Exhaust emissions and its control methods in compression ignition engines: A review

Extensive usage of automobiles has certain disadvantages and one of them is its negative effect on environment. Carbon dioxide (CO₂), carbon monoxide (CO), hydrocarbons (HC), oxides of nitrogen (NO_x), sulphur dioxide (SO₂) and particulate matter (PM) come out as harmful products during incomplete combustion from internal combustion (IC) engines. As these substances affect human health, regulatory bodies impose increasingly stringent restrictions on the level of emissions coming out from IC engines. This trend suggests the urgent need for the investigation of all aspects relevant to emissions. It is required to modify existing engine technologies and to develop a better after-treatment system to achieve the upcoming emission norms. Diesel engines are generally preferred over gasoline engines due to their undisputed benefit of fuel economy and higher torque output. However, diesel engines produce higher emissions, particularly NO_x and PM. Aftertreatment systems are costly and occupy more space, hence, in-cylinder solutions are preferred in reducing emissions. Exhaust gas recirculation (EGR) technology has been utilized previously to reduce NO_x. Though it is quite successful for small engines, problem persists with large bore engines and with high rate of EGR. EGR helps in reducing NO_x, but increases particulate emissions and fuel consumption. Many in-cylinder solutions such as lower compression ratios, modified injection characteristics, improved air intake system etc. are required along with EGR to accomplish the future emission norms. Modern combustion techniques such as low temperature combustion (LTC), homogeneous charge compression ignition (HCCI), premixed charge compression ignition (PCCI) etc. would be helpful for reducing the exhaust emissions and improving the engine performance. However, controlling of autoignition timing and achieving wider operating range are the major challenges with these techniques. A comprehensive review of diesel engine performance and emission characteristics is given in this paper.     

汽车发动机在节能和排放领域的新进展

回顾 内燃机的发展历程，并对为降低内燃机排放而采取各种动力的汽车进行分析，指出燃油汽车仍具有很大的发展前景，论述了汽油机从化油器式直至均燃直喷式的发展历程，并阐述了它们各自的优缺点；指出了柴油机为达到提高功率密度、降低燃油消耗及改善环境的目的应采取的措施。     

Reduction of engine emissions via a real-time engine combustion control with an egr rate estimation model

Vehicle emissions regulations are becoming increasingly severe and remain a principal issue for vehicle manufacturers. Since, WLTP (Worldwide harmonized Light vehicles Test Procedures) and RDE (real driving emission) regulations have been recently introduced, the engine operating conditions have been rapidly changed during the emission tests. Significantly more emissions are emitted during transient operation conditions compared to those at steady state operation conditions. For a diesel engine, combustion control is one of the most effective approaches to reduce engine exhaust emissions, particularly during the transient operation. The concern of this paper is about reducing emissions using a closed loop combustion control system which includes a EGR rate estimation model. The combustion control system calculates the angular position where 50 % of the injected fuel mass is burned (MFB50) using in-cylinder pressure for every cycle. In addition, the fuel injection timing is changed to make current MFB50 follow the target values. The EGR rate can be estimated by using trapped air mass and in-cylinder pressure when the intake valves are closed. When the EGR rate is different from the normal steady conditions, the target of MFB50 and the fuel injection timing are changed. The accuracy of the model is verified through engine tests, as well as the effect of combustion control. The peaks in NO level was decreased during transient conditions after adoption of the EGR model-based closed loop combustion control system.     

Experimental investigation and comparison of nanoparticle emission characteristics in light-duty vehicles for two different fuels

In recent years, particle number emissions rather than particulate mass emissions in automotive engines have become the subject with controversial discussions. Recent results from studies of health effects imply that it is possible that particulate mass does not properly correlate with the variety of health effects attributed to engine exhaust. The concern is now focusing on nano-sized particles emitted from I. C. engines. In this study, particulate mass and particle number concentration emitted from light-duty vehicles were investigated for a better understanding of the characteristics of the engine PM from different types of fuels, such as gasoline and diesel fuel. Engine nano-particle mass and size distributions of four test vehicles were measured by a condensation particle counter system, which is recommended by the particle measurement program in Europe (PMP), at the end of a dilution tunnel along a NEDC test mode on a chassis dynamometer. We found that particle number concentrations of diesel passenger vehicles with DPF system are lower than gasoline passenger vehicles, but PM mass has some similar values. However, in diesel vehicles with DPF system, PM mass and particle number concentrations were greatly influenced by PM regeneration. Particle emissions in light-duty vehicles emitted about 90% at the ECE15 cycle in NEDC test mode, regardless of vehicle fuel type. Particle emissions at the early cold condition of engine were highly emitted in the test mode.     

基于改善柴油机排放的燃烧过程优化措施

改善柴油机排放的核心是对燃烧过程进行优化,通过改善燃烧过程来降低柴油机排放是当前柴油机研究中的重要课题。本文主要从优化进气系统、优化喷油系统、优化燃烧室结构、燃料的改质及优化润滑系统五个方面进行分析,综合这些相互制约的优化措施优化柴油机的燃烧过程,降低颗粒物质PM和NOx的直接排放。     

Reduction of emissions with propane addition to a diesel engine

Recent studies on dual-fuel combustion in compression-ignition (CI) engines, also known as diesel engines, fall into two categories. In the first category are studies focused on the addition of small amounts of gaseous fuel to CI engines. In these studies, gaseous fuel is regarded as a secondary fuel and diesel fuel is regarded as the main fuel for combustion. The objectives of these studies typically involve reducing particulate matter (PM) emissions by using gaseous fuel as a partial substitution for diesel fuel. However, the addition of gaseous fuel raises the combustion temperature, which increases emissions of nitrogen oxides (NO_x). In the second category are studies focused on reactivity-controlled compression-ignition (RCCI) combustion. RCCI combustion can be implemented by early diesel injection with a large amount of low-reactivity fuel such as gasoline or gaseous fuel. Although RCCI combustion promises lower NO_x and PM emissions and higher thermal efficiency than conventional diesel combustion, it requires a higher intake pressure (usually more than 1.7 bars) to maintain a lean fuel mixture. Therefore, in this study, practical applications of dual-fuel combustion with a low air-fuel ratio (AFR), which implies a low intake pressure, were systemically evaluated using propane in a diesel engine. The characteristics of dualfuel combustion for high and low AFRs were first evaluated. The proportion of propane used for four different operating conditions was then increased to decrease emissions and to identify the optimal condition for dual-fuel combustion. Although the four operating conditions differ, the AFR was maintained at 20 (? approximately equal to 0.72) and the 50% mass fraction burned (MFB 50) was also fixed. The results show that dual-fuel combustion can reduce NO_x and PM emissions in comparison to conventional diesel combustion.     

Review on characterization of nano-particle emissions and PM morphology from internal combustion engines: Part 1

This paper is review of the characterization of exhaust particles from state-of-the-art internal combustion engines. We primarily focus on identifying the physical and chemical properties of nano-particles, i.e., the concentration, size distribution, and particulate matter (PM) morphology. Stringent emissions regulations of the Euro 6 and the LEV III require a substantial reduction in the PM emissions from vehicles, and improvements in human health effects. Advances in powertrains with sophisticated engine control strategies and engine after-treatment technologies have significantly improved PM emission levels, motivating the development of new particle measurement instruments and chemical analysis procedures. In this paper, recent research trends are reviewed for physical and chemical PM characterization methods for gasoline and diesel fueled engines under various vehicle certification cycles and real-world driving conditions. The effects of engine technologies, fuels, and engine lubricant oils on exhaust PM morphology and compositions are also discussed.     

Effect of various LPG supply systems on exhaust particle emission in spark-ignited combustion engine

The particle size distribution and particle number (PN) concentration emitted by internal combustion engine are a subject of significant environmental concern because of their adverse health effects and environmental impact. This subject has recently attracted the attention of the Particle Measurement Programme (PMP). In 2007, the UN-ECE GRPE PMP proposed a new method to measure particle emissions in the diluted exhaust of automotive engines and a regulation limit (<6.0×10¹¹ #/km, number of particles). The specific PN regulation of spark-ignited combustion engine will be regulated starting on September 1, 2014 (EURO 6). In this study, three types of LPG supply systems (a mixer system and a multi-point injection system with gas-phase or liquid-phase LPG fuel) were used for a comparison of the particulate emission characteristics, including the nano-sized particle number density. Each of the three LPG vehicles with various LPG injection systems contained a multi-cylinder engine with same displacement volumes of 2,000 cm³ and a three-way catalytic converter. The test fuel that was used in this study for the spark-ignited combustion engine was n-butane basis LPG fuel, which is primarily used for taxi vehicles in Korea. The characteristics of nano-particle size distribution and number concentration of particle sizes ranging from 20 to 1,000 nm (aerodynamic diameter) that were emitted from the three LPG vehicles with various LPG supply systems were investigated by using a condensation particle counter (CPC), which is recommended by the PMP under both the NEDC and FTP-75 test modes on a chassis dynamometer. The experimental results indicate that the PN emission characteristics that were obtained by the CPC system using the PMP procedure are sufficiently reliable compared to other regulated emissions. Additionally, the sources of PN emissions in ascending order of magnitude are as follows: mixer type, gas-phase LPG injection (LPGi) and liquid-phase LPG injection (LPLi) passenger vehicles. The liquid-phase LPG injection system produced relatively large particle sizes and number concentrations compared to the gaseous system, regardless of the vehicle driving cycle. This phenomenon can be explained by unburned micro-fuel droplets that were generated due to a relatively short homogeneous fuel-air mixture duration in the engine intake manifold. Also the particle number emissions from the LPG vehicle were influenced by the vehicle driving cycle.     

Operating strategy for gasoline/diesel dual-fuel premixed compression ignition in a light-duty diesel engine

Environmental problems have become a major issue for diesel engine development. Although emission aftertreatment systems such as DPFs (diesel particulate filters), LNTs (lean NOx traps) and SCR (selective catalytic reduction) have been used in diesel vehicles, the manufacturing cost increase caused by this equipment can be hard to be control. Thus, it is better for engine emissions to be reduced by improving the combustion system. A dual-fuel combustion concept is a recommended method to improve a combustion system and effectively reduce emissions. Low reactivity fuel including gasoline and natural gas, which was supplied to the intake port by the FPI (port fuel injector), improved the premixed air-fuel mixture conditions before ignition. Additionally, a small amount of high reactivity fuel, in this case diesel, was injected into the cylinder directly as an ignition source. This dual-fuel combustion promises lower levels of NOx (nitrogen oxide) and PM (particulate matter) emissions due to the elimination of local rich regions in the cylinder. However, it is challenging to control the dual-fuel combustion because the combustion stability and efficiency deteriorate due to the lack of ignition source and reactivity. Thus, it is important to establish an appropriate dual-fuel operating strategy to achieve stable, high efficiency and low emission operation. As a result of this research, a detailed operating method of dual-fuel PCI (premixed compression ignition) was introduced in detail at a low speed and low load condition by using a single cylinder diesel engine. Engine operating parameters including the gasoline ratio, a diesel injection strategy consisting of multiple injectors and timing, the EGR (exhaust gas recirculation) rate and the intake pressure were controlled to satisfy the low ISNOx (indicated specific NOx) and PM emissions levels (0.21 g/kWh and 0.1 FSN, 0.040 g/kWh, respectively) as per the EURO-6 regulation without any after-treatment systems. The results emphasized that a well-constructed dual-fuel PCI operating strategy showed low NOx and PM emissions and high GIE (gross indicated fuel conversion efficiency) with excellent combustion stability.     

Efficiency and ecological characteristics of a VCR diesel engine

Compression ratio (CR) is a design parameter with highest influence on efficiency, emission and engine characteristics. In conventional internal combustion (IC) engines, the compression ratio is fixed and their performance is, therefore, a compromise between conflicting requirements. One fundamental problem is that drive units in the vehicles must successfully operate at variable speed and loads and in different ambient conditions. If a diesel engine has a fixed CR, a minimal value must be chosen that can achieve a reliable self-ignition when starting the engine in cold start conditions. In diesel engines, variable compression ratio (VCR) provides control of peak cylinder pressure, improves cold start ability and low load operation, enabling the multi-fuel capability, increase of fuel economy and reduction of emissions. By application of VCR and other mechanisms, the optimal regime fields are extended to the prime requirements: consumption, power, emission, noise, etc., and/or the possibility of the engine to operate with different fuels is extended. An experimental Diesel engine has been developed at the Faculty of Engineering, University of Kragujevac. The changes of CR are realized by changing the piston chamber diameter. Detailed engine tests were performed at the Laboratory for IC engines. Special attention has been given to decrease of fuel consumption and exhaust emissions. An optimal field of CR variation has been determined depending on the given objectives: minimal fuel consumption, minimal nitric oxides, and particulate matter emissions, etc.     

Effects of gasoline, diesel, LPG, and low-carbon fuels and various certification modes on nanoparticle emission characteristics in light-duty vehicles

This study was focused on experimental comparisons of the effects of various vehicle certification modes on particle emission characteristics of light-duty vehicles with gasoline, diesel, LPG, and low-carbon fuels such as bio-diesel, bioethanol, and compressed natural gas, respectively. The particulate matter from various fueled vehicles was analyzed with the golden particle measurement system recommended by the particle measurement programme, which consists of CVS, a particle number counter, and particle number diluters. To verify particle number and size distribution characteristics, various vehicle emission certification modes such as NEDC, FTP-75, and HWFET were compared to evaluate particle formation with both CPC and DMS500. The formation of particles was highly dependent on vehicle speed and load conditions for each mode. In particular, the particle numbers of conventional fuels and low-carbon fuels sharply increased during cold start, fast transient acceleration, and high-load operation phases of the vehicle emission tests. A diesel vehicle fitted with a particulate filter showed substantial reduction of particulate matter with a number concentration equivalent to gasoline and LPG fuel. Moreover, bio-fuels and natural gas have the potential to reduce the particulate emissions with the help of clean combustion and low-carbon fuel quality compared to non-DPF diesel-fueled vehicles.     

Emissions simulation in a 7000 kg-grade diesel hybrid electric vehicle

Hybrids combine a combustion engine with an electric motor and battery. The two technologies can be combined to reduce fuel consumption and exhaust emissions. This paper presents the concept of hybrid electric vehicles (HEVs) applied to truck or van vehicles with diesel engines. The simulation results from the advanced vehicle simulator (ADVISOR) demonstrate that the required power may be properly shared between the internal combustion engine and electric motor. The simulation can also be used to prove that the technique is useful for improvements in driving performance; additionally, the technique is suitable for hybrid electric vehicles, allowing for good fuel economy and low emissions performance.     

浅谈柴油机满足国IV两条技术路线

近年来,随着人们对环境保护的日趋重视,世界各国对内燃机废气排放的要求变得越来越严格,轻型柴油车开始实施国Iv标准。目前由于机内排放控制并不能完全起到净化效果,因此对已排出燃烧室但尚未排到大气中的废气进行处理,采取机外控制技术显得很有必要。PM和NOx是柴油机主要排放污染物,如何同时降低这两种尾气组成,达到国Ⅳ排放水平,是当今世界柴油机技术的难点和研究热点。本文介绍目前国内满足柴油机国IV排放标准的SCR和EGRDPF／DOC两种主流技术路线。通过对比分析两种系统的原理和优缺点得出适合国内发展的路线,并浅谈未来柴油机排放控制的发展方向。     

单缸直喷柴油机涡流室燃烧系统外部增压的实验研究

为满足非道路用柴油机的排放法规,从改善柴油机缸内混合气形成质量出发,提出了直喷式柴油机涡流室燃烧系统;设计了柴油机外部增压系统,进行了新型燃烧系统在外部增压下性能的实验研究。结果表明,外部增压能降低柴油机的油耗和排放;增压压力为0.15MPa时,柴油机油耗率最低。增压压力为0.18MPa时,使用4×0.36×140°喷油嘴在供油提前角为8°CA、90%负荷下,NOx排放量仅为常压下的25%。     

车用柴油机冷EGR系统的试验研究

冷EGR技术不仅可以有效降低NOx排放，而且有助于减少因柴油机采用EGR引起的微粒排放量的增加。本文进行了车用柴油机冷EGR系统的试验，研究了冷EGR对柴油机排放性能的影响。并且，对冷EGR和喷油延迟这两种降低柴油机NOx排放措施进行比较。     

Investigation of particle emission characteristics from a diesel engine with a diesel particulate filter for alternative fuels

Particle number measurement is a new approach to determine emission, which may be more accurate at very low emission levels than when using gravimetric measurements. An experimental study was performed to investigate the effect of fuel properties on the performance, combustion process, regulated gaseous emissions and particle number emissions of a diesel engine with an uncatalyzed diesel particulate filter (DPF). The effect of the filter on the particle size distribution was reported. The DPF number-based filtration efficiency in terms of number efficiency and fractional efficiency for petroleum diesel fuel and two alternative fuels, BTL and GTL, were analyzed. For nearly all test modes, the filter had a higher number efficiency for diesel than for BTL and GTL. The DPF fractional efficiency showed it was highly dependent on fuel type and varied widely at each size range. For diesel, the filter fractional efficiency was sufficiently high and behaved as predicted by filtration theory. For BTL and GTL, the fractional performance of the filter decreased when unexpectedly low efficiencies within the nuclei mode were exhibited. This research will be helpful in understanding DPF number-based filtration performance for alternative fuels and will provide information for the development of particulate emission control technology.     

Effects of the fuel injection ratio on the emission and combustion performances of the partially premixed charge compression ignition combustion engine applied with the split injection method

Currently, due to the severity of world-wide air pollution by substances emitted from vehicles, emission control is being enforced more strictly, and it is expected that the regulation requirements for emission will become even more severe. A new concept combustion technology that can reduce the Nitrogen oxides (NOx) and PM in relation to combustion is urgently required. As a core combustion technology among new combustion technologies for the next generation engine, the homogenous charge compression ignition (HCCI) is expanding its application range by adopting a multiple combustion mode, a catalyst, direct fuel injection and partially premixed charge compression ignition combustion using the split injection method. This paper used a split injection method in order to apply the partially premixed charge compression ignition combustion method without significantly altering engine specifications of the multiple combustion mode and practicality by referring to the results of studies on the HCCI engine. Furthermore, the effects of the ratio of the fuel injection amount on split injection are investigated. From the test results, the adequate combination of the ratio of the fuel injection amount for the split injection method has some benefit on exhaust and fuel economy performance in a naturally aspirated single cylinder diesel engine.     

Influence of oxygenate content on particulate matter emission in gasoline direct injection engine

The relationship between the oxygen content in gasoline and the particulate emission (particle number and weight) was investigated. In order to study the influence of the engine configuration on the particulate emission, four vehicles were tested in which the following systems were installed: Vehicle 1 was equipped with direct injection system which uses central mounted outwardly opening injectors. Vehicle 2 and 3 used direct injection with a side mounted multihole injectors and Vehicle 4 had port fuel injection system. Methyl tert-butyl ether (MTBE) was used as the oxygen booster. The oxygen content in the gasoline was varied from 1 to 3 wt%, which corresponds with an MTBE dosage from 3.55% to 16.11%. This study used fuel that contained the same octane number with a 2% oxygen content without oxygen components, and it was used as the reference fuel in order to distinguish the effect of the oxygen content increases and the octane boosts that result from the MTBE. All vehicle tests were performed on a roller type chassis dynamometer using the New European Driving Cycle (NEDC) and Federal Test Procedure-75 (FTP-75) cycle. The experiment results demonstrate that the oxygen content increases in the gasoline reduced the particulate emission in vehicles with direct injection engines. An equivalent phenomenon was observed in a vehicle with a port fuel injection engine, but its absolute particle number was much smaller than that of the gasoline direct injection engine. The amount of reduction of the particle number in the start (cold) phase of the test cycle was significant compared with the later (hot) phase engine operation. However, particulates were emitted even though the engine was fully warmed up, especially when the engine was highly loaded. Other factors such as fuel economy or other exhaust emissions were not significantly affected by the oxygen content.     

Effect of a 2-stage injection strategy on the combustion and flame characteristics in a PCCI engine

Recently, to reduce environmental pollution and the waste of limited energy resources, there is an increasing requirement for higher engine efficiency and lower levels of harmful emissions. A premixed charge compression ignition (PCCI) engine, which uses a 2-stage type injection, has drawn attention because this combustion system can simultaneously reduce the amount of NOx and PM exhausted from diesel engines. It is well known that the fuel injection timing and the spray angle in a PCCI engine affect the mixture formation and the combustion. To acquire two optimal injection timings, the combustion and emission characteristics of the PCCI engine were analyzed with various injection conditions. The flame visualization was performed to validate the result obtained from the engine test. This study reveals that the optimum injection timings are BTDC 60° for the first injection and ATDC 5° for the second injection. In addition, the injection ratio of 3 to 7 showed the best NOx and PM emission results.     

基于传统动力源的重型商用车减碳技术

在全球能源危机和温室效应加剧的大环境下，中国向世界承诺减碳目标：2030年前力争实现碳达峰，2060年前力争实现碳中和。作为节能减排的重点，重型商用车的减碳成效是“双碳”征程中的关键。重点介绍基于传统动力源的重型商用车减碳技术，包括内燃机燃烧、低摩擦、智能变速、轻量化、混合动力等技术在内的动力总成领域，以及包括天然气、含氧燃料、氢氨燃料在内的先进燃料领域。通过不同领域的技术发展以及优势互补，更加高效、低碳、清洁的内燃机仍将在重型商用车领域持续发挥重要作用。