Benthic sediment composition and nutrient cycling in an Intermittently Closed and Open Lake Lagoon

Surfical sediments within Corunna Lake, a moderate size Intermittently Closed and Open Lake Lagoon (ICOLL), were examined for solid phase nutrient concentrations (TN, TP, TOC,) and solute exchange rates between the sediment and water column (O₂, NO₃–N, NH₄–N, FRP, and N₂). The surfical sediments in Corunna Lake contained high concentrations of TN (5 mg/g dry mass), total phosphorus (0.6 mg/g dry mass), and TOC (~ 5% dry mass). The carbon stable isotope ratio (δ¹³C) and TOC:TN ratios (δ¹³C ~ ? 24, TOC:TN ~ 11–14) demonstrated that the composition of the organic matter in the sediment was a mixture derived primarily of degraded planktonic matter. The close association between TP and Fe concentrations highlighted the potential role Fe plays in mediating Filterable Reactive Phosphorus (FRP) concentrations in the water column of Corunna Lake. In situ benthic chamber incubations were used to measure benthic fluxes. Solute exchange rates between the sediment and water column in Corunna Lake were similar to other reported studies (O₂ = ? 469 to ? 1765 µmol m^? 2 h^? 1, NH₄–N = 0.1–63 µmol m^? 2 h^? 1, NO₂/NO₃–N = 0 µmol m^? 2 h^? 1, FRP = ? 4–1.6 µmol m^? 2 h^? 1and N₂ = 12–356 µmol m^? 2 h^? 1). As more carbon was deposited and mineralized the efficiency of the bacterial population to denitrify nitrogen in the sediment decreases. The linkage between land use and benthic biogeochemistry was also explored. A dairy farm exists in the middle catchment of Corunna Lake, and the receiving bay sediment consistently demonstrated the highest oxygen consumption rates in winter and spring (? 1408 µmol m^? 2 h^? 1 in winter, ? 1691 µmol m^? 2 h^? 1 in spring) and lowest denitrification efficiencies during summer (~ 3%). Nitrate/nitrite fluxes were not observed during any of the chamber incubations, with the concentrations of nitrate/nitrite being below detection limits (< 10 μg/L). Seasonal changes influenced the rates of solute exchange between the sediment and water column. Critical measures of solute exchange for NH₄–N and biogenic N₂ indicated that seasonal temperature changes play a significant role in mediating the reaction rates of sedimentary based biogeochemical processes. Measurable FRP fluxes were small but greater in the benthic sediments which received higher carbon inputs. Sediments have a high capacity to adsorb P which is released as sediment oxygen demand increases as a result of increases in labile carbon loads.     

Marine molluscs as biomonitors for heavy metal levels in the Gulf of Suez, Red Sea

Levels of the heavy metals Copper (Cu), Zinc (Zn), Lead (Pb), Cadmium (Cd), Chromium (Cr), Nickel (Ni), Iron (Fe) and Manganese (Mn) were determined in coastal water, sediments and soft tissues of the gastropod limpet, Patella caerulea, and the bivalve, Barbatus barbatus, from seven different stations in the western coast of the Gulf of Suez. The concentrations of heavy metals in water ranged between 3.37–4.78, 18.83–21.46, 2.75–3.17, 0.22–0.27, 0.99–1.21, 2.69–3.65, 3.75–4.56 μg L^− 1 and 23.82–32.78 mg g^− 1 for Cu, Zn, Pb, Cd, Cr, Ni, Mn and Fe, respectively. The corresponding concentration values in the sediments were 8.65–12.16, 51.78–58.06, 36.52–42.15, 3.23–3.98, 9.03–12.75, 34.31–49.63, 3.28–4.56 and 64.20–70.22 μg g^− 1 for Cu, Zn, Pb, Cd, Cr, Ni, Mn and Fe, respectively. The highest accumulated metals were Fe, Zn and Mn in both P. caerulea and B. barbatus, while the lowest one was Cd. The accumulation of metals was more pronounced in P. caerulea than B. barbatus. The highest concentrations of all metals in water, sediments and mollusca were recorded at Adabiya harbour north of the Gulf, while the lowest concentrations were recorded at Gabal El-Zeit and Hurghada. Land based activities and ships awaiting berth are the main source of metal pollution in the northern part of the Gulf.     

Estimation of air–sea CO2 fluxes in the Bay of Biscay based on empirical relationships and remotely sensed observations

An empirical algorithm has been developed to compute the sea surface CO₂ fugacity (fCO₂^sw) in the Bay of Biscay from remotely sensed sea surface temperature (SST_RS) and chlorophyll a (chl a_RS) retrieved from AVHRR and SeaWiFS sensors, respectively. Underway fCO₂^sw measurements recorded during 2003 were correlated with SST_RS and chl a_RS data yielding a regression error of 0.1 ± 7.5 µatm (mean ± standard deviation). The spatial and temporal variability of air–sea fCO₂ gradient (ΔfCO₂) and air–sea CO₂ flux (FCO₂) was analyzed using remotely sensed images from September 1997 to December 2004. An average FCO₂ of ? 1.9 ± 0.1 mol m^? 2 yr^? 1 characterized the Bay of Biscay as a CO₂ sink that is suffering a significant long-term decrease of 0.08 ± 0.05 mol m^? 2 yr^? 2 in its capacity to store atmospheric CO₂. The main parameter controlling the long-term variability of the CO₂ uptake from the atmosphere was the air–sea CO₂ transfer velocity (57%), followed by the SST_RS (10%) and the chl a_RS (2%).     

Numerical simulation of flow around a smooth circular cylinder at very high Reynolds numbers

High Reynolds number flows (Re = 1 × 10⁶, 2 × 10⁶ and 3.6 × 10⁶, based on the free stream velocity and cylinder diameter) covering the supercritical to upper-transition flow regimes around a two-dimensional (2D) smooth circular cylinder, have been investigated numerically using 2D Unsteady Reynolds-Averaged Navier–Stokes (URANS) equations with a standard high Reynolds number k ? ? turbulence model. The objective of the present study is to evaluate whether the model is applicable for engineering design within these flow regimes. The results are compared with published experimental data and numerical results. Although the k ? ? model is known to yield less accurate predictions of flows with strong anisotropic turbulence, satisfactory results for engineering design purposes are obtained for high Reynolds number flows around a smooth circular cylinder in the supercritical and upper-transition flow regimes, i.e. Re > 10⁶. This is based on the comparison with published experimental data and numerical results.     

Quantifying erosion rates and stability of bottom sediments at mussel aquaculture sites in Prince Edward Island,Canada

Downward fluxes of organic biodeposits under suspended mussel culture cause benthic impacts such as microbial mat production. Quantifying sediment erosion in these coastal ecosystems is important for understanding how fluxes of organic matter and particulates contribute to benthic–pelagic coupling. Critical shear velocity (u?), erosion rates and particle size distributions of resuspended sediment were measured at two sites; an impacted muddy site with extensive mussel culture (site 1), and a coarser sandier site with less mussel influence (site 2), using a new method for assessing sediment erosion at Tracadie Bay, Prince Edward Island in August 2003. Shear forces were generated by vertically oscillating a perforated disc at controlled frequencies. These forces correspond to shear velocity, using a re-designed and calibrated Particle Erosion Simulator. Undisturbed sediment cores obtained by divers and grab (sub-cored using a Plexiglas? cores) were exposed to shear stress to compare differences between collection methods. Microbial mats were present at site 1 which initially biostabilized sediment against erosion due to ‘armoring’ of the sediment, but onset of erosion was abrupt once these mats failed. Erosion sequences at site 2 (without mat cover) were smoother resulting in less material being eroded. Mean mass of material eroded was 47 and 23 g m^? 2 min^? 1 at sites 1 and 2 respectively. Mat area cover and shear velocity was strongly related. Critical shear velocities varied between 1.70 and 1.77 cm s^? 1, with no obvious differences between location or collection method, so sediments from these two contrasting sites had identical mean critical shear velocities. Significant differences existed in the concentrations of chlorophyll a, colloidal and bulk carbohydrates, between mats and bare sediment from site 1. Particle sizes measured by videography of resuspended sediment at different shear velocities ranged from 100 μm (the minimum diameter capable of being detected by the system), to large mat fragments of 1700 μm for both sites. These results provide evidence of the relevance of using a portable erosion device to indicate how sediment erodability is affected by mussel–microbial relationships.     

Intra-annual variability of distribution patterns and fluxes of dissolved trace metals in a subtropical estuary (Danshuei River,Taiwan)

Water samples were collected along salinity gradients and dissolved trace metal (Cd, Cu, Ni, Pb, and Zn) concentrations were determined in a macro-tidal, mountainous estuary (Danshuei River Estuary) in northern Taiwan. Bi-monthly surveys were conducted between March 2001 and June 2002, during both wet and dry seasons. This study investigated intra-annual variability, fluxes, and the extent of addition or removal of dissolved trace metals in the estuary, which is characterized by the fluctuation of redox interface according to river flow conditions. In sub-oxic and anoxic waters, the presence of reduced sulfur species led to the formation of metal-sulfide minerals that sequester metals out of the water column. Therefore, trace metal fluxes and removal/addition rates are seasonally variable, largely by the extent of estuarine hypoxia. In the 9 sampling expeditions over the 16-month period, fluxes of dissolved trace metals out of the Danshuei River Estuary were estimated as follows: Cd, ? 0.33–4.46 mol/day; Cu, ? 48–1112 mol/day; Ni, 1836–6586 mol/day; Pb, 2.47–11.59 mol/day; and Zn, 361–2656 mol/day. For elements such as Cd and Cu, the removal in the Danshuei River Estuary during dry seasons was so dramatic that there were net fluxes from the coast to the estuary (negative fluxes). Ni behaved near conservatively in this estuary, thus its river endmember concentrations directly determined Ni fluxes out of the estuary. Removal of Pb was effectively enhanced by the presence of higher suspended particulate matter concentrations in the upper estuary and the formation of Fe- and Mn-oxides and oxyhydroxides that precipitate out of the water column in mid-estuary, which generally leaves low effective river endmember Pb concentrations, thus low fluxes out of the estuary.     

Density-dependent effects on seston dynamics and rates of filtering and biodeposition of the suspension-cultured scallop Chlamys farreri in a eutrophic bay (northern China): An experimental study in semi-in situ flow-through systems

Effects of stocking density on seston dynamics and filtering and biodeposition by the suspension-cultured Zhikong scallop Chlamys farreri Jones et Preston in a eutrophic bay (Sishili Bay, northern China), were determined in a 3-month semi-field experiment with continuous flow-through seawater from the bay. Results showed that the presence of the scallops could strongly decrease seston and chlorophyll a concentrations in the water column. Moreover, in a limited water column, increasing scallop density could cause seston depletion due to scallop's filtering and biodeposition process, and impair scallop growth. Both filtration rate and biodeposition rate of C. farreri showed significant negative correlation with their density and positive relationship with seston concentration. Calculation predicts that the daily removal of suspended matter from water column by the scallops in Sishili Bay ecosystem can be as high as 45% of the total suspended matter; and the daily production of biodeposits by the scallops in early summer in farming zone may amount to 7.78 g m^− 2, with daily C, N and P biodeposition rates of 3.06 × 10^− 1, 3.86 × 10^− 2 and 9.80 × 10^− 3 g m^− 2, respectively. The filtering and biodeposition by suspension-cultured scallops could substantially enhance the deposition of total suspended particulate material, suppress accumulation of particulate organic matter in water column, and increase the flux of C, N and P to benthos, strongly enhancing pelagic–benthic coupling. It was suggested that the filtering-biodeposition process by intensively suspension-cultured bivalve filter-feeders could exert strong top-down control on phytoplankton biomass and other suspended particulate material in coastal ecosystems. This study also indicated that commercially suspension-cultured bivalves may simultaneously and potentially aid in mitigating eutrophication pressures on coastal ecosystems subject to anthropogenic N and P loadings, serving as a eutrophic-environment bioremediator. The ecological services (e.g. filtering capacity, top-down control, and benthic–pelagic coupling) functioned by extractive bivalve aquaculture should be emphasized in coastal ecosystems.     

Mass and heat transports in the NE Barents Sea: Observations and models

The strait between Novaya Zemlya and Frans Josef Land, here called the Barents Sea Exit (BSX) is investigated using data obtained from a current-meter array deployed in 1991–1992, and two numerical models (ROMS and NAME). Combining the observations and models the net volume flux towards the Arctic Ocean was estimated to 2.0 ± 0.6 Sv (1 Sv = 10⁶ m³s^? 1). The observations indicate that about half of this transport consists of dense, Cold Bottom Water, which may penetrate to great depths and contribute to the thermohaline circulation. Both models give quite similar net transport, seasonal variations and spatial current structures, and the discrepancies from the observations were related to the coarse representation of the bottom topography in the models. Also the models indicate that actual deployment did not capture the main in- and outflows through the BSX. A snapshot of the hydrographic structure (CTD section) indicates that both models are good at reproducing the salinity. Nevertheless, they react differently to atmospheric cooling, although the same meteorological forcing was applied. This may be due to the different parameterisation of sea ice and that tides were included in only one of the models (ROMS). Proxies for the heat transport are found to be small at the BSX, and it can not be ruled out that the Barents Sea is a heat sink rather than a heat source for the Arctic Ocean.     

Geochemical controls on distributions and speciation of As and Hg in sediments along the Gaoping (Kaoping) Estuary–Canyon system off southwestern Taiwan

Surface and box-cored sediments were collected along the Gaoping (formerly spelled Kaoping) Estuary–Canyon system and analyzed for As and Hg contents and speciation, ²¹⁰Pb-based sedimentation rates and various geochemical parameters to elucidate the mechanisms that control natural and anthropogenic inputs of As and Hg from the Gaoping (Kaoping) River (KPR). The contents of As and Hg in surface sediments ranged from 1.84 to 20.7 mg kg^− 1 and from 0.07 to 2.15 mg kg^− 1, respectively, in the estuary and canyon. The concentrations generally decreased from the lower river toward the mixing boundary and then increased toward the estuarine mouth, followed by a slight variation in the canyon. Both As and Hg concentrations correlated strongly with clay, total organic carbon (TOC), Al, Fe and Mn contents in estuarine sediments but not necessary the same cases for canyon surface sediments. The factor analysis of surface sediments shows that the first two factors, which account for 75.6% of the variance, may represent major roles of carriers (clay, Al and Fe–Mn oxides) and TOC in controlling As and Hg distributions, respectively. Accordingly, the spatial patterns of the enrichments of As (1.9–16.2) and Hg (1.8–30.8) with reference to the crust levels follow the individual element's distribution patterns, likely because of deposition variability following inputs from the river. The contents of mobile As and Hg correlated substantially with the contents of both metals that were extracted with 0.1 M HCl. In addition to the major pool in the residual fraction (65–87%), As was relatively abundant in Fe–Mn oxides/hydroxides, whereas Hg was abundant in the organic/sulfide fraction. The deposition and accumulation rates of As and Hg in the canyon clearly decreased as the depth of water increased. The depth distributions of both metals are likely controlled primarily by TOC and Fe–Mn oxides associated factors followed by a contribution from anthropogenic pollution. The metal pollution appears to have increased substantially around 1970, following the economic boom in Taiwan, suggesting that modern sediments in the Gaoping (Kaoping) Canyon were derived from the Gaoping (Kaoping) River (KPR).     

Modelling the ecosystem dynamics of the Barents Sea including the marginal ice zone: II. Carbon flux and interannual variability

An upgraded and revised physically–biologically coupled, nested 3D model with 4 km grid size is applied to investigate the seasonal carbon flux and its interannual variability. The model is validated using field data from the years for which the carbon flux was modelled, focussing on its precision in space and time, the adequacy of the validation data, suspended biomass and vertical export. The model appears to reproduce the space and time (± 1 week and 10 nautical miles) distribution of suspended biomass well, but it underestimates vertical export of carbon at depth. The modelled primary production ranges from 79 to 118 g C m^− 2 year^− 1 (average 93 g C m^− 2 year^− 1) between 4 different years with higher variability in the ice-covered Arctic (± 26%) than in the Atlantic (± 7%) section. Meteorological forcing has a strong impact on the vertical stratification of the regions dominated by Atlantic water and this results in significant differences in seasonal variability in primary production. The spatially integrated primary production in the Barents Sea is 42–49% greater during warm years than the production during the coolest and most ice-covered year.     

Development and lipid storage in Calanus euxinus from the Black and Marmara seas: Variabilities due to habitat conditions

Oil sac volume, gonad size and moulting patterns were investigated in the copepod Calanus euxinus inhabiting deep and shallow zones of the Black Sea and penetrating into the Marmara Sea. In summer the C. euxinus population in deep layers of the Black Sea was dominated by pre-diapause and diapausing postmoult copepodite stage V (CV) with small sexually undifferentiated gonads and mean lipid content of 14.1 ± 6.0% of body volume. The lipid content of deep-living females was 7.2 ± 4.2% of body volume. At the same time, intermoult and premoult CV with enlarged gonads and low lipid content (7.7 ± 5.1% of body volume) and females with oil sac volume of 1.4 ± 1.0% were found at shallow stations. Premoult CV with oil volume of 0.6 ± 0.8% and mature females with little visual evidence of substantial lipid storage dominated in the Marmara Sea. The differences in moulting patterns and oil sac volumes of C. euxinus from deep zones and shallow regions suggest that vertical migrations to the oxygen minimum zone (OMZ) are necessary for formation of large lipid reserves providing high reproductive potential of this species. On the basis of an energy balance model it was shown that under low phytoplankton concentration of about 30 μg C l^− 1 preadults and adults migrating to the OMZ could accumulate lipids (up to 5% of body energy content daily), in contrast to copepods constrained to shallow oxic water columns of the Black Sea and from the Marmara Sea.     

Phytoplankton dynamics related to water mass properties in the Gulf of Gabes: Ecological implications

The spatial distribution of chlorophylls and carotenoids was recorded throughout the Gulf of Gabes (South Ionian Sea) in March 2007, and was related to patterns of the physical structure and the nutrient concentrations.Two distinct water masses were identified based on the temperature and salinity (T–S) analysis: a cool and less salty Modified Atlantic Water (MAW) and a saltier Mediterranean Mixed Water (MMW). There was no significant difference in the mean nitrogen and phosphate concentrations between MMW and MAW, although the silica values were significantly higher in MAW. The Integrated chlorophyll a mean value was about 4 mg m^? 2, with a maximum of 13 mg m^? 2 at MAW stations.Higher Chlorophyll a records in typical MAW stations were mainly due to chlorophytes, which contributed up to 58% of the pigments concentrations in the MAW and about 46% in the MMW. The contribution of chlorophytes to total Chlorophyll a was found to be relatively stable throughout the water column. The contribution of diatoms, which were twofold higher in the MMW than in the MAW, did not exceed 17% of chlorophyll a and was mainly due to subsurface maxima. The chlorophytes, pelagophytes, prymnesiophytes and cryptophytes all together accounted for more than 77% of total chlorophyll a in the MAW and about 67% in the MMW.There were statistically significant differences between MMW and MAW in the pigment contribution of cyanobacteria and pelagophytes. These two taxa accounted for 13% and 24% of chlorophyll a respectively in the MAW and MMW indicating that these differences concerned phytoplankton classes at relatively low contributions to total chlorophyll a.     

Predicting the chloride penetration of fly ash concrete in seawater

In this study, a model for predicting chloride penetration in fly ash concrete under long-term exposure in a marine environment is developed. The empirical model was based on 2-, 3-, 4-, and 5-year investigation of concretes in a marine site. Regression analysis of the data was carried out by applying Fick's second law of diffusion to generate an empirical formula for predicting chloride concentration in concrete. The model uses the water to binder (W/B) ratio, fly ash content, distance from the concrete surface, and exposure time. Model validation revealed that the predicted chloride concentration levels were within a ±25% error margin (R² = 0.91 ? 0.99) in the samples used to develop the model. The model was also verified using data from previous laboratory and field studies. Most predicted chloride concentration levels were within a ±30% margin of error from field samples. The model also predicted the strong effect of fly ash and W/B ratio on reducing chloride diffusion in concrete. Results clearly indicated that a high volume fly ash replacement (up to 50% by weight of binder) and a low W/B ratio will yield good chloride resistance in concrete under long-term exposure in a marine environment.     

An analysis of the characteristics of chlorophyll in the Sulu Sea

The seasonal and spatial variations of chlorophyll concentrations, Sea Surface Temperature (SST), wind fields and wind-induced Ekman pumping in the Sulu Sea are investigated using a set of new remote sensing measurements from October 1997 to December 2004. The results show the seasonality of chlorophyll, wind fields and SST and reveal the phytoplankton blooming events in the Sulu Sea basin during the northeast monsoon season. In summer, chlorophyll concentrations were relatively low (< 0.2 mg/m³) and distributed uniformly throughout the basin with a narrow belt of high chlorophyll concentrations along the coastal waters, particularly the coasts of Borneo and of the Sulu Archipelago. In winter, chlorophyll concentrations increased (> 0.2 mg/m³) throughout the entire basin, and phytoplankton bloomed southward to the central basin, while chlorophyll concentrations reached high levels (1 mg/m³) in the center of the blooms. One peak was observed during the northeast monsoon season each year. SSTs have significant negative correlations with chlorophyll concentrations; i.e., high and uniformly distributed in summer but lower with an obvious tongue of cold waters southward to the central basin in winter. The seasonal variation of chlorophyll concentrations and SST distribution were associated with the seasonally reversing monsoon. The winter phytoplankton blooming and the tongue of the cold waters were correlated to the vertical upwelling cold and nutrient-rich waters drawn by the northeast wind, with the center of the blooms and the location of cold tongues coinciding with the maximum of the wind speeds and the Ekman pumping velocities.     

CO2 air–sea disequilibrium and preformed alkalinity in the Pacific and Indian oceans calculated from subsurface layer data

This work estimates new regionalized empirical parameterizations for preformed alkalinity (A_T^o) and the CO₂ air–sea disequilibrium (?C_dis). Both are key terms for the computation of anthropogenic CO₂ in the back-calculation methods. Data from the subsurface layer (75–180 m depth range) covering an area from North to South and from 19°E to 67.5°W (Pacific and Indian oceans) were taken from GLODAP (The Global Ocean Data Analysis Project) database. The subsurface layer is proved as a reliable reference for representing the main characteristics of the different water masses of the oceans. Besides, handing data from the two ocean basins altogether makes the new parameterizations of A_T^o and ?C_dis to be more globally consistent. Nevertheless, each ocean basin, at least in some regions, has different oceanographic characteristics based on its proper dynamical processes and water masses formation. In order to maintain each ocean basin ‘identity’ the whole domain was divided in six different regions (two of them sharing waters from Pacific and Indian oceans) and parameterizations in each region for both terms were obtained. Previously, data were transformed into a grid of 4°lat. × 5°lon. and the results obtained from the parameterizations were visualized and compare with pCO₂ climatologies. From the comparisons with previous ?C_dis estimations good results are obtained showing the reliability and robustness of the new regionalized empiric parameterizations.     

Residual stress distributions in ship hull specimens

This paper provides an in-depth study of residual stress distributions found in stiffened steel plate structures, such as those typically used in ship hulls. The effect of stiffener spacing on the distribution of residual stress components was studied. The welding heat input was also varied between high and moderate to study the effect of heat input level on residual stress distributions. Four specimens, resembling typical stiffened steel plate structures used in ship hulls were built and tested. Steel plates of 9.5 mm thickness were stiffened by welding L127 × 76 × 9.5 steel angles. The test was completed using the neutron diffraction method. The three normal components of residual stress were obtained in this study. It was found that a lower heat input results in higher tensile residual stress and that there exists a critical stiffener spacing somewhere beyond 250 mm that creates a maximum tensile residual stress value near the welded connection.     

Rigid moorings in shallow water: A wave power application. Part I: Experimental verification of methods

Experimental work carried out at 1:60 scale in a wave flume assessed the pitch motion and anchor loading of 3 articulated tower installations in 50 m water depth while being exposed to north Atlantic storms with H_s of 15.2 m and T_p of 18.4 s. The three installations differ only in that their mass and buoyancy characteristics provide a natural period in pitch at equilibrium of 13 s, 20 s and 34 s respectively. It is verified that the dominant behaviour can be simulated by a relatively simple mathematical model, allowing the critical parameters of peak anchor loads and pitch angles to be calculated and extrapolated to full scale. It is demonstrated from the experimental and simulation results that the mass characteristics of a non surface piercing tower can be used to offset some of the challenges of moving to shallow water. If done correctly, it is possible to keep horizontal anchor loads under control and reduce vortex-induced transverse loading at the expense of increased pitch motions. Overall, the use of articulated tower installations in water depths of 50 m would appear to be technically feasible, even in exposed areas. The limitations on the size of such structures and the consequences of the resulting pitch accelerations and induced anchor loads are the subject of further study. It is proposed that the model verified herein can be used to further assess their potential at delivering viable wave power position mooring systems.     

Primary productivity and export fluxes on the Canadian shelf of the Beaufort Sea: A modelling study

We present a coupled sea ice–ocean-biological (including ice algae) model in the Arctic Ocean. The 1D model was developed and implemented on the Canadian Beaufort Sea shelf to examine the importance of different physical processes in controlling the timing and magnitude of primary production and biogenic particle export over an annual cycle (1987). Our results show that the snow and sea ice cover melt and/or break-up controls the timing of the phytoplankton bloom but primary producers (ice algae and phytoplankton) on the outer shelf are essentially nutrient limited. The total annual primary production (22.7 to 27.7 g-C m^? 2) is thus controlled by nutrient “pre-conditioning” in the previous fall and winter and by the depth of wind mixing that is controlled in part by the supply of fresh water at the end of spring (ice melt or runoff). The spring bloom represents about 40% of the total annual primary production and occurs in a period of the year when sampling is often lacking. Time interpolation of observed values to obtain total annual primary production, as done in many studies, was shown to lead to an underestimation of the actual production. Our simulated ratios of export to primary production vary between 0.42 and 0.44.     

Monitoring trace elements (Al, As, Cr, Cu, Fe, Mn, Ni and Zn) in deep and surface waters of the estuary of the Nerbioi-Ibaizabal River (Bay of Biscay, Basque Country)

Deep water samples (in contact with the sediment) were collected at eight different points of the estuary of the Nerbioi-Ibaizabal River (Bay of Biscay, Basque Country), both at low and high tides, during four sampling campaigns (May, September and December 2005 and March 2006). Superficial water was also sampled in March 2006. Temperature, pH, redox potential, dissolved oxygen and electrical conductivity corresponding to each sample were measured in situ at each sampling point using a multiparametric probe. The physico-chemical parameters found are typical of highly stratified estuaries, with an acceptable oxygenation level. After filtering and acidifying the samples, they were analysed by inductively coupled plasma/mass spectrometry (ICP/MS) to simultaneously determine the total concentration of Al, As, Cr, Cu, Fe, Mn, Ni and Zn. Concentrations in the μg kg^− 1 level were found in all cases (c_Cr and c_Ni, 1–10; c_Al, c_As and c_Zn, 10–50; c_Cu and c_Mn, 10–100 and c_Fe, 100–400 μg kg^− 1). A probable net input of Al, Cr, Mn and Zn via the main (Nerbioi-Ibaizabal) and some of the tributary rivers (Galindo, Asua and Gobela) was identified. Evidence of a common source of Al and Zn to the estuary was found. Correlation analysis of data revealed connections between variables (concentration of Cu, Fe and As with salinity, as well as c_Al with c_Zn, c_Cu with c_Fe, c_As with c_Fe, and c_As with c_Cu). Principal Component Analysis (PCA) of data allowed the samples to be grouped according to sampling campaign, with two principal components accounting for 62% of the total variance. In addition, plots of element concentration against salinity suggested a conservative behaviour for As, Cu and Fe and a non-conservative one for Cr. Not clear mixing behaviour was observed for the rest of elements.