Modelling nutrient fluxes from sub-arctic basins: Comparison of pristine vs. dammed rivers

The deterministic Riverstrahler model of river functioning is applied for the first time to sub-arctic catchments. Seasonal nutrient (N, P, Si) deliveries to the coastal zone are simulated, and nutrient annual fluxes are established for the nearly pristine river Kalix (hereafter called Kalixälven) and the heavily dammed river Lule, (hereafter called Luleälven) both located in Northern Sweden and draining into the Bothnian Bay, Baltic Sea.For Kalixälven simulations are performed with a runoff calculated from precipitation, evapo-transpiration and temperature data for the period 1990–1999, using a hydrological model calibrated on observed monthly discharges at the river outlet. The same hydrological parameters are used to calculate specific runoff for the Luleälven basin in absence of dam regulation. Reservoir filling and emptying are simulated using a simplified representation of their management rules. Diffuse sources of nutrient are evaluated according to land cover of the catchment. The simulated seasonal trends are within the range of the observed data, in particular for discharge, dissolved silica, total phosphorus, inorganic nitrogen and total organic carbon. Specific runoff is 50% higher in the Luleälven than in the Kalixälven watershed due to higher altitudes and precipitations. Average silica, nitrate and phosphorus concentrations are much lower in Luleälven than in Kalixälven. Comparison of model results for the Luleälven with and without dams shows a reduction of respectively 25% and 30% in silica and phosphorus fluxes delivered at the outlet, while nitrogen delivery is increased by 10% in the dammed vs. undammed river system. The model allows assessing the respective role of reservoir trapping of nutrient in the reservoir through algal uptake and sedimentation, and of changes in the vegetation induced by flooding the valley formerly covered by forests and wetlands.     

The Cost of Nutrient Reduction: A Case Study of Chesapeake Bay

Over $3.5 billion were spent toward nutrient controls in the Chesapeake Bay watershed between 1985 and 1996. These expenditures were based on cost-shares between federal, state, local, and private sources and should be considered conservative. A comparison of point and nonpoint nutrient control expenditures in the Bay basin showed that about 50% of the funds were directed toward agricultural best management practices and 45% were allocated for point source nutrient reductions and combined sewer overflows (20% and 25%, respectively). The remainder was spent on various other estuarine-targeted programs. Maryland was responsible for 79% of the total expenditures, 16% was expended by Virginia, and the remainder was attributable to the District of Columbia and Pennsylvania (4% and 1%, respectively). The most costly basin was the Patuxent (over $125 per kilogram of total nitrogen removed) and the least costly was the Eastern Shore of Virginia, where the cost was just under $21 per kilogram of nitrogen removed. For the control practices examined, the analysis found that nutrient management was the least costly. Animal waste control and low tillage were the second and third most economical nutrient management strategies. Significant reductions were achieved from point sources for both total nitrogen (16%) and total phosphorus (53%) by 1996. Virtually all of the large reduction in point source phosphorus was a result of the phosphorus detergent ban implemented basinwide in the late 1980s. Nonpoint source nutrient reductions were more modest. An approximate 12% reduction in phosphorus was accompanied by an 8% reduction in total nitrogen loadings. Despite these nutrient reductions, no significant improvements in bottom-dissolved oxygen levels were detected along the Bay mainstem during the warmer months, and the mouth of Chesapeake Bay showed marginally significant degradation during the 11-year period. It was determined that dissolved oxygen conditions were influenced more by nitrogen than phosphorus reductions and that nutrient controls aimed at the mid-Bay region had the greatest potential for improving low dissolved oxygen conditions in the Bay's bottom waters.     

PSO-BP神经网络在船舶二级脱硝系统中的应用

随着国际海事组织（IMO）标准Tier III标准的实施，船舶柴油机尾气中的氮氧化物（NOx）的排放受到了更严格的限制。选择性催化还原脱硝技术因其高效、可靠等优势成为船舶柴油机NOx减排的主要选择。本文先根据SCR反应机理在MATLAB中搭建一级SCR脱硝系统和二级SCR脱硝系统模型，通过仿真结果对比，发现加入二级脱硝系统后，脱硝率可以得到提高。鉴于BP网络预测精度较低，本文将粒子群（PSO）算法加入到BP权值训练过程中，利用PSO-BP 神经网络预测 SCR-DeNOX系统出口处NOX浓度。结果表明：PSO-BP 神经网络不但可以预测SCR-DeNOX系统出口处的NOX浓度，而且与传统BP 神经网络相比可以提高预测结果的精度，为有效控制喷氨量、降低氨气逃逸量提供帮助。     

Simulated responses of the Gulf of Mexico hypoxia to variations in climate and anthropogenic nutrient loading

A mathematical model was used to simulate monthly responses of the Gulf of Mexico hypoxia to variations in climate and anthropogenic nutrient loading over a 45-year period. We examined six hypothetical future scenarios that are based on observed and projected changes in the Mississippi River discharge, Mississippi River nitrate concentrations, and ambient water temperatures. In particular, we investigated the implications of a 30% decrease in the Mississippi River nitrogen flux, which was recently proposed by the Mississippi River Watershed/Gulf of Mexico Hypoxia Task Force as a measure to reduce the size of the hypoxic zone. Model simulations suggest that the frequency of hypoxia in the northern Gulf of Mexico is highly sensitive to variations in riverine nitrate flux, but also to variations in freshwater discharge and ambient water temperatures. A 30% decrease in the Mississippi River nitrate flux, for example, would reduce the frequency of hypoxia by 37%. Nevertheless, a 20% increase the Mississippi River discharge, which may occur under some climate change scenarios, would produce an increase in the frequency of hypoxia of the same magnitude. Thus, if the potential climatic variations are taken into account, a 30% decrease in the nitrogen flux of the Mississippi River may not be sufficient to accomplish the proposed hypoxia management goal.     

Alterations in nutrient limitations — Scenarios of a changing Baltic Sea

Previous trend studies have shown increasing nitrogen and phosphorus as well as decreasing silica concentrations in the water mass of the Baltic Sea. This has had an impact on the amount of primary production, but also on the quality and succession of plankton species. Present study examines the spatial and temporal patterns of potential nutrient limitations in the Baltic Sea for the time period 1970–2000. Generally, low concentrations of DSi can limit the diatom blooms and such conditions are found in the Gulf of Riga and Gulf of Finland during spring and summer. Nutrient ratios, DSi:DIN, DSi:DIP and DIN:DIP, are often used to determine which nutrient may limit the primary production. Annual long-term temporal trends of silica to inorganic nitrogen and phosphorus respectively show consistent decreasing patterns. The largest slopes are detected during spring and summer for DSi:DIN and during spring for DSi:DIP ratios. For the DIN:DIP ratio significant slopes are only found in a few locations despite increasing levels for both nutrients, displaying a large variation in trends. In the open Baltic Proper the present trends are positive during winter and negative during spring and autumn. Gulf of Finland and Gulf of Riga are areas where both DSi:DIP and DSi:DIN ratios are found close to the Redfield ratios for diatoms. Together with the evaluated trends these suggest that the Gulfs may become silica limited in a relatively near future. These findings give some implications on the development and impact of changing nutrient concentrations.     

A box model approach for a long-term assessment of estuarine eutrophication, Szczecin Lagoon, southern Baltic

We develop a layered “box model” to evaluate the major effects of estuarine eutrophication of the Szczecin lagoon which can be compared with integrating measures (chlorophyll a (Chl a), sediment burial, sediment oxygen consumption (SOC), input and output of total nutrient loads) and use it to hindcast the period 1950–1996 (the years when major increase in nutrient discharges by the Oder River took place). The following state variables are used to describe the cycling of the limiting nutrients (nitrogen and phosphorus): phytoplankton (Phy), labile and refractory detritus (D_N, D_Nref, D_P, D_Pref), dissolved inorganic nitrogen (DIN), dissolved inorganic phosphorus (DIP), and oxygen (O₂). The three layers of the model include two water layers and one sediment layer. Decrease of the carrying capacity with respect to the increased supply of organic matter of the system with advancing eutrophication over the period studied is parameterized by an exponential decrease of the sediment nitrogen fluxes with increasing burial, simulating changing properties from moderate to high accumulating sediments. The seasonal variation as well as the order of magnitude of nutrient concentrations and phytoplankton stocks in the water column remains in agreement with recent observations. Calculated annual mean values of nutrient burial of 193 mmol N m⁻² a⁻¹ and 23 mmol P m⁻² a⁻¹ are supported by observed values from geological sediment records. Estimated DIN remineralization in the sediments between 100 and 550 mmol N m⁻² a⁻¹ corresponds to SOC measurements. Simulated DIP release up to 60 mmol P m⁻² a⁻¹ corresponds to recent measurements. The conceptual framework presented here can be used for a sequential box model approach connecting small estuaries like the Szczecin lagoon and the open sea, and might also be connected with river box models.     

Budget calculations of nitrogen, phosphorus and BOD5 passing through the Oder estuary

The Oder River estuary is a large and complex system composed of lagoons, lakes and river branches in which numerous biogeochemical processes lead to modification of loads of dissolved/suspended material brought in with the riverine waters. Budget calculations show that on an annual basis, 71–88% of total nitrogen, 73–89% of total phosphorus and 72–101% of BOD₅ inflowing to the estuary are exported to the Baltic Sea. Among the inorganic nutrient species, nitrates exhibit the highest net transformation rate into organically bound forms (over 60%). The transformation could have been equally high or even higher in the case of ammonia and phosphates but these processes may have been compensated by intensive mineralization. The mechanisms responsible for the nutrient transformation patterns, as well as their net effect on the annual loads delivered into the Baltic Sea, are discussed in the paper. Phosphorus seemed to play a limiting role in phytoplankton production in the estuary in spring, while nitrogen did the same in summer.     

Environmental changes and the responses of the ecosystems of the Yellow Sea during 1976–2000

The changes in the environmental features of the Yellow Sea during the last 25 years of the 20th century were studied using a set of seasonally monitored data along a transect (at 36°N) maintained by the State Oceanic Administration of China. The data included the ocean temperature (T), salinity (S) and biogenic elements, such as dissolved oxygen (DO), phosphorus (PO₄-P), silicon (SiO₃-Si) and dissolved inorganic nitrogen (DIN).The seasonal (summer and winter) values and the annual mean of these elements showed significant changes during the monitored period. Time series of T, S, DIN and N:P ratios exhibited positive trends, while those of DO, P and Si exhibited negative trends. During this period, the annual mean of T and DIN in the Yellow Sea increased by 1.7 °C and 2.95 μmol L⁻¹, respectively, while those of DO, P and Si decreased by 59.1, 0.1 and 3.93 μmol L⁻¹, respectively. In the 1980s, particularly in between 1985 and 1989, concentrations of P and Si dropped to near the ecological threshold for growth of diatoms. The N:P ratio increased from 4 in 1984 to over 16 in 2000. The climate trend coefficients, R_xt, for these time series are all above 0.43 with significance levels of 95%, except for salinity. The increases in T were consistent with the recent climate warming in northern China and the adjacent seas, i.e. the Bohai Sea and the East China Sea. The reduction of DO was probably attributable to the increase in T and decrease in primary production in these regions. The positive trend of DIN was mainly attributable to precipitation and partly to Changjiang River discharge. The negative concentration trends of P and Si were due to the decreases in their concentrations in seawater that flowed to the Yellow Sea from the Bohai Sea. As a result, N:P ratios greatly increased in the seawater of the Yellow Sea.Moreover, some important responses of the Yellow Sea ecosystems to the changes in physical variables and chemical biogenic elements were obviously displayed. These responses include strengthening nutrient limitation, decreasing chlorophyll a, primary production and phytoplankton abundance, succession of dominant phytoplankton species from diatoms to non-diatoms, changes in fish community structure and species diversity.     

Phytoplanktonic nutrient utilisation and nutrient signature in the Southern Ocean

The separation in Southern Ocean provinces of silicate excess at nitrate exhaustion and of nitrate excess at silicate exhaustion was already introduced by Kamykowski and Zentara (Kamykowski, D., Zentara, S.J., 1985. Nitrate and silicic acid in the world ocean: patterns and processes. Mar. Ecol. Prog. Ser. 26, 47–59; and Kamykowski, D., Zentara, S.J., 1989. Circumpolar plant nutrient covariation in the Southern Ocean: patterns and processes. Mar. Ecol. Prog. Ser. 58, 101–111) and our investigations of the silicate to nitrate uptake ratios confirm the earlier distinction. Oligotrophic antarctic waters mainly exhibit proportionally higher silicate removal what induces a potential for nitrate excess. The nitrogen uptake regime of such areas is characterised by low absolute as well as specific nitrate uptake rates throughout. Maximal values did not exceed 0.15 μM d⁻¹ and 0.005 h⁻¹, respectively. Corresponding f-ratios ranged from 0.39 to 0.86. This scenario contrasts strikingly to the more fertile ice edge areas. They showed a drastic but short vernal increase in nitrate uptake. Absolute uptake rates reached a maximum value of 2.18 μM d⁻¹ whereas the maximal specific uptake rate was 0.063 h⁻¹. In addition to an optimal physical environment for bloom development, accumulation of ammonium stimulated nitrate uptake in a direct or indirect way. Since ammonium build-up in surface waters traces enhanced remineralisation, release of other essential compounds during degradation of organic matter might have been the main trigger. This peak nitrate utilisation during early spring led to the observed potential for silicate excess. With increasing seasonal maturity the nitrate uptake became inhibited by the presence of enhanced ammonium availability (up to 8% of the inorganic nitrogen pool), however, and after a short period of intensive nitrate consumption the uptake rates drop to very low levels, which are comparable to the ones observed in the area of nitrate excess at silicate exhaustion.     

Effect of seaweed proliferation on benthic habitat quality assessed by Sediment Profile Imaging

Changes in sediment quality, with special reference to benthic habitat conditions resulting from macroalgae overgrowth, were studied in the Venice Lagoon, Italy. Data were collected biweekly in spring and summer from 1993 to 1998 and from 2001 to 2002, as part of the macroalgae growth control strategies managed by the Venice Water Authority-Consorzio Venezia Nuova. Benthic habitat conditions were studied by means of Sediment Profile Imaging, which allowed the collection of several variables: aRPD (apparent redox potential discontinuity), prism penetration depth, presence of anoxia on the surface of the sediment, presence of reduced gas bubbles, stage of benthic colonization. All these variables led to the calculation of an environmental index (Organism–Sediment Index, OSI), which was then related to physical variables and macroalgae abundance. Until 1996, the overall benthic habitat of the Venice Lagoon showed almost stressed conditions; from 1997, the seaweed biomass rapidly declined and the OSI increased significantly. The OSI seemed to be affected by seaweed biomass, sediment compactness and water depth. Macroalgae biomass greater than 4.5 kg/m² led to the complete disappearance of stage III of benthic colonization; values as low as 0.70 kg m² already had a severe impact on recolonization. SPI attributes indicated the main mechanisms that could have contributed to the benthic quality: seaweed proliferation is often followed by rapid decay of macroalgae biomass, especially when present in large amounts. The decrease in seaweed biomass often results in oxygen depletion in the water column and thus in the sediment, preventing complete benthic colonization. This research confirms the importance of in situ rapid reconnaissance surveys to assess the impact of eutrophication on the benthic habitat.     

Nutrient biogeochemical cycles in the Gulf of Riga: scaling up field studies with a mathematical model

A box model has been implemented to understand the large-scale biogeochemical cycles of nitrogen, phosphorus, and silicon in the Gulf of Riga. The large data sets collected within the international Gulf of Riga Project in 1993/1995 were used to validate the model. The comparison to data was useful in scaling up to the gulf-wide level and scrutinizing the conclusions based on short-term field surveys and experimental studies. The simulations indicate that the limiting role was passing from silicon to phosphorus to nitrogen over the seasons of organic production. However, on an annual scale, nutrient limitation was close to the “Redfield equilibrium”. Mass balance considerations, based on modeled coupled fluxes, disagree with the conclusions on low sediment denitrification and high phosphorus retention in the pelagic system, which were derived from isolated measurements.Nutrient budgets constructed with the model revealed the high buffer capacity of the Gulf of Riga. The nutrient residence times span a range from 6 years for N to 70 years for Si. The buffering arises from intensive internal recycling in the water body and by the bottom sediments. The budgets indicate that the Gulf retains about two-thirds of external nitrogen and silicon inputs, while phosphorus retention is only 10%.A slow response to external perturbations is demonstrated with numerical experiments run for 15 years under 50% reductions of terrestrial nutrient inputs. These experiments imply that the most effective is the N+P reduction scenario, which resulted in a 20% decrease of primary production after 12 years. A reduction of P resulted in only a 6% decrease of primary production; however, it yielded an 80% drop in the amount of nitrogen fixation.     

浅水湖泊平面二维水质模型研究

磷氮元素在水体中迁移对湖泊富营养化研究具有重要性。采用有限元伽辽金加权余量法建立了简单的二维水质模型,并计算了在风场作用下的苏州市澄湖丰水期和枯水期的氮磷的分布以及输移。计算中引入了可由实测资料率定的可为正负的综合衰减参数,综合考虑了氮磷元素的沉降速率和释放速率,这样减少了水质多参数难确定的困难。计算的结果表明,流态与实际情况吻合较好,氮磷元素的浓度计算值与实测值相差不大。     

An eddy-permitting, coupled ecosystem-circulation model of the Arabian Sea: comparison with observations

A nitrogen-based, pelagic ecosystem model has been coupled with an eddy-permitting ocean general circulation model of the Arabian Sea, and the results are compared with observations. The seasonal variability simulated by the model is in good agreement with observations: during the southwest monsoon season, phytoplankton increases in the western Arabian Sea due to upwelling along the coast; during the northeast monsoon season, phytoplankton abundance is large in the northern Arabian Sea because of the enhanced nitrate entrained by relatively deep vertical mixing. Two major differences are, however, found in the basin-wide comparison between model results and observations: an unrealistic nitrate maximum in the subsurface layer of the northern Arabian Sea and too low primary production in oligotrophic regimes. The former may be attributed to the lack of denitrification in the model. Possible causes for the latter include the present model's underestimation of fast nutrient recycling, the neglect of carbon fixation decoupled from nitrogen uptake and of nitrogen fixation, and inadequate nitrate entrainment by mixed layer deepening. The rate at which simulated nitrate increases in the northern Arabian Sea is 11–24 TgN/year, and should correspond to the denitrification rate integrated over the northern Arabian Sea assuming that the loss of nitrogen through denitrification is balanced by advective input. The model does not reproduce the observed phytoplankton bloom in the late southwest monsoon season. Possible causes are that the mixed layer may be too shallow in summer and that the horizontal transport of nitrate from the coast of Oman may be too weak. Sensitivity experiments demonstrate a strong dependence of the simulated primary productivity on the vertical mixing scheme and on the inclusion of a fast recycling loop in the ecosystem model.     

Ecological modeling as a tool for coastal zone management in Dokai Bay, Japan

An ecological numerical model has been developed for coastal zone management in Dokai Bay, Japan. The numerical model experiment reproduces the occurrence of red tides and oxygen-deficiency in Dokai Bay during summer. Moreover, the model experiments forecast that when the phosphorus or nitrogen load from land will be cut by 90% or 95%, respectively, red tides and oxygen-deficiency will not occur in Dokai Bay. If the sewage facility is not sufficient to cut the nutrients load to the necessary degree, it is necessary to consider other countermeasures such as cultivating bivalves in order to decrease the nutrients in the bay.     

A finite element model for the Venice Lagoon. Development, set up, calibration and validation

The development, calibration and validation of a two-dimensional finite element model for the Venice Lagoon is described. The model uses a staggered grid for the spatial integration of the water levels and velocities. A semi-implicit numerical time stepping scheme is implemented, which guarantees unconditional stability for the gravity wave propagation. Because of the shallow depths in the lagoon, the model deals also with areas where flooding and drying occur.A first calibration of the model has been performed against harmonic constants of 12 tide gauges located in the lagoon. After this calibration, model output shows a good agreement with a set of water level data referring to a period of calm winds and to another data set of water level data measured in 38 stations during a period of strong winds.Meteorological data and river discharges are used to set up a 1-year long simulation that models the salinity and temperature fields. The temperature time evolution is well simulated. Comparison of model output to salinity data is not straightforward, since input data for the main rivers that discharge freshwater into the lagoon is not available for the year of reference. However, yearly averages of observed values of salinity are in a reasonable agreement with results of a climatological simulation.The presented model shows good propagation of the tidal wave and stability characteristics. It is the first step for a comprehensive model of the Venice Lagoon that deals not only with hydrodynamic variables, but also with sediment transport and ecological processes.     

Nutrient status of the Northeast Water Polynya

The nutrient distribution in the Northeast Water Polynya (NEW) was investigated intensively between the end of May and the beginning of August 1993 during the R/V Polarstern cruise ARK IX. The major characteristics were low initial nitrate concentrations (ca. 4 μM) in the surface mixed layer of the East Greenland Shelf Water, accompanied by high silicate values (ca. 10–14 μM). These concentrations were not reduced by phytoplankton growth. Silicate was rather homogeneously distributed in the entire water column, whereas nitrate increased continuously with depth to about 13 μM. Phosphate concentrations were about 1.1 μM and had a similar distribution to that of silicate. During the course of the summer, nutrients became depleted, and nitrate was exhausted in large parts of the NEW. Silicate was reduced to values of less than 2 μM at some stations which implies that diatom growth continued despite nitrate depletion, ammonium serving as a nitrogen source. The polynya is fertilised by water with the initial nutrient concentrations downstream of the Norske Øer Ice Shelf. This process continuously supplies nutrients to the surface throughout the year and these are transported northward by the anticyclonic surface circulation following the topography of the trough system. The northern boundary of this tongue of relatively nutrient-rich water is controlled by the uptake of nutrients by phytoplankton in summer. Its extemsion is variable due to interactions between biological processes, circulation and ice cover. In the Ob Bank region the nutrient distribution can be altered by the inflow of Polar Water from the north when strong northerly winds prevail as happened during the first part of the study.     

空气净化器对甲醛、苯和氨气的净化效果研究

对几种类型的空气净化器进行性能测试,并以洁净空气量CADR、净化效率Y等指标表示净化器的净化效果.通过对比分析发现,实验室组装的净化器样机净化性能突出,对常见装修污染物甲醛、苯和氨气的净化效率分别达到50%,53%和42%,且处理低浓度污染气体的性能明显优于其他几种样机.     

山区河流航道整治施工对水生态环境的影响

山区河流航道整治一般采取筑坝、疏浚、炸礁、护岸等工程，在施工中不可避免对现状水生态环境造成扰动。以岷江下游航道整治一期工程为例，通过对代表性河段施工前后的水质、浮游生物、底栖动物、鱼类等种类和资源量开展现场监测，研究发现：施工前后水体化学需氧量、五日生化需氧量、氨氮、总磷、石油类、悬浮物的浓度有所升高，但均未超过相关标准限定值；藻类、水生维管束植物、浮游动物、底栖动物、鱼类等施工前后无明显减少。因此通过合理的时间、空间的施工避让，航道整治施工对山区河流水生态环境的影响较小。     

Air pollution impact of maritime shipping operations in the port of Houston

Abstract

Major air pollutants from maritime shipping operations are sulfur oxides, nitrogen oxides, and particulate matter emissions from combustion of fuel oil during cruise, berth, and start‐up modes. Sulfur oxides emissions are substantial from steamships burning high‐sulfur residual fuel oil, where shipping contributes 66 percent of the total sulfur dioxide emissions from transportation sources, and almost 3 percent of the total for Harris county, Texas. Nitrogen oxides emissions are significant during cruise conditions for both steamships and motor ships, while particulate emissions are substantial during start‐up and tube cleaning.

Significant marine air pollutant emission sources are found in busy harbor areas such as the Houston Ship Channel. Offshore terminals for unloading large tankers may result in emissions of 10 to 20 tons of sulfur oxides daily per ship, and 3 to 5 tons of nitrogen oxides daily per ship during pumping operations. Trace‐metal constituents present in the oil may catalyze sulfur dioxide and nitrogen dioxide oxidation to their respective sulfate and nitrate aerosols in the humid Texas Gulf Coast atmospheres to aggravate photochemical air pollution problems once the air masses reach industrial and populated urban areas on land. Onshore sulfur dioxide and particulate‐matter emission controls may be necessary for some large ships in port to minimize potential impact on coastal zone air quality.     

The trophic state of the Baltic Sea a century ago: a model simulation study

We apply a 3-D circulation model with a biogeochemical module (ERGOM) for the simulation of trophic conditions in the Baltic Sea a century ago. One aim is to provide reference or background data for nitrogen, phosphorus and chlorophyll, which is required for the implementation of the European Water Framework Directive (WFD). We assume that the situation a century ago serves this purpose well. Model input for this long-term simulation study are the regionally differentiated riverine and atmospheric nutrient loads to the Baltic Sea, which were compiled and calculated for a situation 100 years ago on the basis of various literature sources. For the mixed surface layer of the open Baltic Sea, we suggest maximum winter concentrations for dissolved phosphorus (dissolved inorganic nitrogen) of 0.23–0.35 (2.7–3.7) mmol/m³. Maximum chlorophyll-a concentrations are between 1.8 and 2.4 mg/m³. The concentrations of all parameters for different coastal waters vary in a wide range, depending on exposure to nutrient sources. Our nutrient concentrations for the situation a century ago are close to early measured data (1950–1960) and suggest that this data is suitable as reference data, as well.