在不同水质地区实地进行海洋生物膜对SS UNS S32760不锈钢腐蚀行为研究（英文）

In the presence of biofilms, stainless steels(SS) exhibits an increase in corrosion potential, called ennoblement. In the present study, the corrosion potential(Ecorr) behavior of the duplex SS UNS S32760 was recorded simultaneously with the in situ marine biofilm formation in two areas at Arraial do Cabo,Southeastern Brazil. The biofilm at Forno Harbor(an anthropogenically disturbed area) was characterized by higher relative abundances of Bacteria at day 2, followed by diatoms(especially Navicula sp.) on day 10 and dinoflagellates on day 18,whereas no clear trend was recorded at Cabo Frio Island(an undisturbed area). The ennoblement of Ecorr values was site-dependent. In a complementary laboratory assay, biofilms were removed and the Ecorr values registered in sterile conditions for the subsequent 10 days and corroborated in situ results. Understanding biofilms and SS interactions has important implications for materials science and engineering decisions as well as helping to fill in important gaps in this knowledge.     

Galvanic corrosion behaviour of aluminium 3004 and copper in tropical marine atmosphere

The galvanic corrosion behaviour of aluminium 3004 and copper with different area ratios were studied in the tropical marine atmosphere at Tuticorin harbour over a period of 426 days. The area ratios OfAAI： Acu, studied were l：l, 1：2, l：4, 1：8, 2：1, 4：1 ＆ 8：1. The galvanic corrosion behaviour of metals was studied in terms of relative increase in the corrosion rate of aluminium due to galvanic coupling with copper, relative decrease in the corrosion rate of copper due to galvanic coupling with aluminium, and the susceptibility of aluminium to pitting owing to galvanic coupling with copper, The galvanic potential and galvanic current of the system were monitored. Pits of different dimensions ranging from mild etchings to perforations were experienced on the borders and the surfaces of the interface of aluminium in contact with copper. The weathering parameters and the environmental pollutants which have a major role in influencing the galvanic corrosion of metals were also monitored. The corrosion products resulting from galvanic corrosion were analysed using XRD and the pitting on aluminium resulting from galvanic corrosion has been highlighted in terms of pit depth, size and density of pit, using a high resolution microscope.     

Analysis of corrosion risk due to chloride diffusion for concrete structures in marine environment

The chloride-induced steel corrosion is one of the main causes of deterioration for reinforced concrete structures exposed to marine environments. The chloride ingress into reinforced concrete structures is even more complex since it depends on random parameters linked to transport and chemical properties of materials, which results in variability of corrosion initiation. This variation raises the need of statistical approaches to evaluate the risk of corrosion initiation due to chloride ingress. To address this issue, we use sensitivity analysis to identify the influence of input parameters on critical length of time before corrosion initiation predicted by our chloride diffusion model. Exceedance probabilities of corrosion initiation time given that input parameters exceed certain thresholds were also calculated. Results showed that the corrosion initiation time was most sensitive to: chloride effective diffusion coefficient D_e in concrete, that is a parameter controllable by relevant stakeholders; surface chloride concentration C_s, a non-controllable parameter depending on surrounding conditions. Reducing the chloride diffusion coefficient enables us to postpone the maintenance of structures. However, the interaction between controllable parameters and non-controllable surrounding conditions was revealed influential on the reliability of results. For instance, the probability that corrosion initiation time exceeds 15 years given an effective diffusion coefficient (D_e) equal to 0.1 × 10⁻¹² m²⋅s-1 can vary from 19 to 41% according to stochastic variations of chloride concentrations (C_s) values. Postponing the corrosion initiation time was combined with a decreasing probability of its occurrence.     

Hydrodynamic performance of multiple-row slotted breakwaters

This study examines the hydrodynamic performance of multiple-row vertical slotted breakwaters. We developed a mathematical model based on an eigenfunction expansion method and a least squares technique for Stokes second-order waves. The numerical results obtained for limiting cases of double-row and triple-row walls are in good agreement with results of previous studies and experimental results. Comparisons with experimental measurements of the reflection, transmission, and dissipation coefficients (C _R , C _T , and C _E ) for double-row walls show that the proposed mathematical model adequately reproduces most of the important features. We found that for double-row walls, the C _R increases with increasing wave number, kd, and with a decreasing permeable wall part, dm. The C _T follows the opposite trend. The C _E slowly increases with an increasing kd for lower kd values, reaches a maximum, and then decreases again. In addition, an increasing porosity of dm would significantly decrease the C _R , while increasing the C _T . At lower values of kd, a decreasing porosity increases the C _E , but for high values of kd, a decreasing porosity reduces the C _E . The numerical results indicate that, for triple-row walls, the effect of the arrangement of the chamber widths on hydrodynamic characteristics is not significant, except when kd<0.5. Double-row slotted breakwaters may exhibit a good wave-absorbing performance at kd>0.5, where by the horizontal wave force may be smaller than that of a single wall. On the other hand, the difference between double-row and triple-row vertical slotted breakwaters is marginal.     

Benthic megafauna communities under the influence of the South Atlantic Central Water intrusion onto the Brazilian SE shelf: A comparison between an upwelling and a non-upwelling ecosystem

The structure and dynamics of the benthic invertebrate megafauna of the Southeastern Brazilian shelf were studied over a 2-year period. Two regions presenting different oceanographic conditions, Ubatuba-SP and Cabo Frio-RJ were compared in terms of biomass, density of organisms and species richness. Two to three 30-min tows were undertaken at each of the stations, located at 40 and 100 m isobath, in a normal transect offshore of both regions. Faunal distributional patterns correlated with water mass dynamics, depth and sediment parameters. In the Cabo Frio region, subjected to a Ekman-driven seasonal coastal upwelling, the impact of the South Atlantic Central Water (SACW) on the inner shelf leads to a change in the benthic communities, with a high dominance of top carnivores such as the crab Portunus spinicarpus and the sea-star Astropecten brasiliensis, which accounted for the larger part of the total biomass. Distinct species associations were found in each of the two regions and the total biomass at Cabo Frio inner shelf was almost twice that of Ubatuba during the 2002 summer, when a marked upwelling was verified. The relationship between megabenthic biomass and input of organic matter to the sea floor during upwelling events is discussed.     

Effect of pH on mechanical,physical and tribological properties of electroless Ni-P-Al<Subscript>2</Subscript>O<Subscript>3</Subscript> composite deposits for marine applications

Successful co-deposition of fine particulate matter within an Electroless Nickel-Phosphorous (ENi-P) matrix is dependent on various factors like bath composition, particle compatibility with metallic matrix, bath reactivity (pH), particle size and their distribution. ENi-P deposits incorporating Al₂O₃/Alumina in a disperse phase have varied effects on properties and attributes like surface roughness (Ra), microhardness, wear resistance, corrosion resistance and surface morphology of the deposits obtained. This paper experimentally investigates the effect of alumina (1.55 g/L) on Ra, microhardness, surface morphology, deposition rate, wettability, wear resistance and corrosion resistance of ENi-P-Al₂O₃ composite deposits on mild steel substrates at bath pH 5, 7 and 9. Study reveals that optimum deposit parameters and deposition rates are achieved with bath pH. However, not much study has been undertaken concerning composite deposits obtained from higher bath pH or basic bath. This is attributable to the fact that at higher bath pH or alkaline baths, the bath gets unstable and eventually degrades or decomposes, thereby resulting in sub optimal or poor deposition. Hence, experimental investigations carried out by preparing suitable baths, operating under optimum conditions, and enabling successful composite deposition in acidic and alkaline baths have revealed that there is a significant improvement in the above mentioned properties of the as-deposited composite deposits, as the pH is increased from pH 5 to pH 9. This aspect can therefore be advantageously utilized for preparing various marine components like fasteners, nuts, bolts, washers, pipes, cables, components having relative motion etc.     

纳米MoS2颗粒对海洋平台铝合金钻探管表面微弧氧化膜的性能影响

为了使海洋平台铝合金钻探管具有优异的耐腐蚀性能,试验采用微弧氧化技术,在海洋平台钻探管用2A12铝合金表面制备氧化铝陶瓷膜。本试验研究了纳米颗粒添加量对微弧氧化膜的微观形貌、组织结构和耐腐蚀性的影响。试验得出：MoS₂纳米颗粒添加量对微弧氧化膜的制备影响较大,随着MoS₂纳米颗粒添加量的增加,微弧氧化膜的厚度有增大的趋势,孔径先增大后减小,膜表面越来越致密光滑;随着MoS₂纳米颗粒添加量的增加,微弧氧化膜的耐腐蚀性能提高,当MoS₂纳米颗粒添加量由0.5g/L增加到2g/L时,腐蚀速率由0.00032g.(dm₂)_-1.h_-1降低至0.00024g.(dm₂)_-1.h_-1。     

Experimental study on the wave-induced dynamic response and hydrodynamic characteristics of a submerged floating tunnel with elastically truncated boundary condition

Hydrodynamic load and motion response are the first considerations in the structural design of a submerged floating tunnel (SFT). Currently, most of the relevant studies have been based on a two-dimensional model test with a fixed or fully free boundary condition, which inhibits a deep investigation of the hydrodynamic characteristics with an elastic constraint. As a result, a series of difficulties exist in the structural design and analysis of an SFT. In this study, an SFT model with a one-degree-of-freedom vertical elastically truncated boundary condition was established to investigate the motion response and hydrodynamic characteristics of the tube under the wave action. The effect of several typical hydrodynamic parameters, such as the buoyancy-weight ratio, γ, the relative frequency, f/f_N, the Keulegan–Carpenter (KC) number, the reduced velocity, U_r, the Reynolds number, Re, and the generalized Ursell_s number, on the motion characteristics of the tube, were selectively analyzed, and the reverse feedback mechanism from the tube's motion response to the hydrodynamic loads was confirmed. Finally, the critical hydrodynamic parameters corresponding to the maximum motion response at different values of γ were obtained, and a formula for calculating the hydrodynamic load parameters of the SFT in the motion state was established. The main conclusions of this study are as follows: (i) Under the wave action, the motion of the SFT shows an apparent nonlinearity, which is mainly caused by the intensive interaction between the tube and its surrounding water particles, as well as the nonlinearity of the wave. (ii) The relative displacement of the tube first increases and then decreases with increasing values of f/f_N, U_r, KC number, Re, and the generalized Ursell_s number. (iii) γ is inversely proportional to the maximum relative displacement of the tube and the wave force on the tube in its motion direction. (iv) Under the motion boundary condition (as opposed to the fixed boundary condition), the peak frequency of the wave force on the SFT in its motion direction decreases and approaches the natural vibration frequency of the tube, whereas the wave force perpendicular to the motion direction increases. When the incident wave frequency is close to the natural vibration frequency of the tube, the tube resonates easily, leading to an increased wave force in the motion direction. (v) If the velocity in the Morison equation is substituted by the water particle velocity measured when the tube is at its equilibrium position, the inertia coefficient in the motion direction of the tube is linearly related to its displacement, whereas that in the direction perpendicular to the motion direction is logarithmically related to its displacement.     

URANS simulations of catamaran interference in shallow water

This paper investigates the interference effects of wave systems on a multi-hull vessel in shallow water. A numerical analysis is made using the URANS code CFDSHIP-Iowa V.4 on the DELFT Catamaran model 372. The test matrix for numerical computations includes two separation distances (s = 0.17; 0.23) and the depth values of h/T = 8.2, 2.5 and 2, at several speeds ranging within Fr _H = 0.775–1.739. Numerical results are compared with the experimental data of the Bulgarian Ship Hydrodynamic Center, and verification and validation for resistance, sinkage and trim are also performed. Results show that, at critical speed (Fr _H ≈ 1), the presence of a finite depth significantly affects the catamaran total resistance, which, in shallower water, increases considerably with respect to deep water. At low h/T, small effects of the water depth on resistance occur at subcritical and supercritical speeds. The interference effects seem to be more relevant in shallow, rather than in deep water, with maximum IF values registered at critical speeds (Fr _H ≈ 1). Similarly to deep water, the lower the separation distance the greater the interference value. Moreover, in shallow water some negative interference is observed at Fr > 0.5. Wave patterns and wave profiles are analyzed and a comparison is made between several configurations of catamaran and a mono-hull vessel, in order to analyze how water depth and separation distance determine resistance and interference. Finally, a vortex instability study is also included.     

Effect of non-symmetrical corrosion imperfection on the collapse pressure of subsea pipelines

The effects of non-symmetrical corrosion defects (about the major or minor axis of the ellipse) on the collapse modes and collapse pressures of subsea pipelines are studied using the Finite Element (FE) method. The corrosion defects are represented by a groove of a given length, width, and depth which is created by the “element death” technology. Parametric studies are conducted and the influences of corrosion location angle, length, width, and depth on the collapse pressure are discussed. Several significant and interesting results are achieved: (1) The collapse modes are mainly affected by the corrosion location angle, width, and depth; (2) The collapse pressure of a pipe may increase as the corrosion length, width, or depth increases when the corrosion location angle is small; (3) The longer the corrosion length, the larger the effect of corrosion location angle on the collapse pressure; (4) For collapses controlled by corrosion defect (0.3≤h/t ≤ 0.7), the relationship between the collapse pressure and corrosion location angle follows a simple cosine function. For collapses controlled by the ovality (h/t < 0.3), the relationship can be expressed by the combination of straight-line and cosine function.     

Prediction of wave parameters by using fuzzy inference system and the parametric models along the south coasts of the Black Sea

Forecasting of sea-state characteristics has a great importance in coastal and ocean engineering studies. Therefore, the purpose of this study was to investigate performances of Adaptive-Network-Based Fuzzy Inference System (ANFIS) and several parametric methods in the Black Sea. For this purpose, different fuzzy models with different input combinations were developed for two different wind data sources (TSMS and ECMWF) at two offshore buoy stations. It also aimed to apply several approaches to event-based data sets for wave predictions. Generally, in literature the tendency is to use time series data for wave predictions. In this kind of prediction approach, lagged time series data are taken as inputs and current or future variables are taken as output. In this study, event-based data for each independent storm were extracted from time series data. Simultaneous or concurrent data of wind speed, blowing duration, fetch length and wave characteristics were detected for each single storm. These event data were then used to set up models. The hindcast results were validated with significant wave height and mean wave period data recorded in Hopa and Sinop buoy stations. The performance of developed fuzzy models were also compared with that of four different parametric methods (Wilson, SPM, Jonswap, and CEM methods) applied for two wind data sources at both buoy stations. Finally, it was determined that in the prediction of both wave parameters (H _s and T _z) the ANFIS models (R = 0.66, squared correlation coefficient, and MAE = 0.37 m, mean absolute error, for the best model in prediction of H _s) were more accurate than the parametric methods (R = 0.63 and MAE = 0.75 m for the best model in prediction of H _s).     

Lateral response of monopile reinforced by cement-improved soil in clay to monotonic and cyclic loadings: Laboratory model test and theoretical investigation

A systematic study was performed in laboratory model tests to assess the response of cement-improved reinforced monopiles to lateral monotonic and cyclic loading in clay. The overall load‒deflection behavior and profile of the bending moment was fully studied in monotonic tests, in addition to the p-y curves of the reinforced and unreinforced piles. Cyclic loading tests were carried out at different cyclic magnitude values and load ratios, and the cement-improved soil reinforcement range was also varied. This study provides several insights into the ongoing development of the deflection, unloading stiffness and bending moment of cement-improved soil reinforced piles as cycling progresses, which can provide empirical design recommendations for cement-improved soil reinforced monopiles subjected to lateral cyclic loading. Based on the typical p-y curve models of pile in soft clay and stiff clay, by considering the proportion of soil resistance shared by cement-improved soil and soft clay around a pile under lateral load, the modification factors of two parameters p_u and y₅₀ are derived, and then a modified p-y curve model of cement-improved soil reinforced piles in soft clay is established.     

The coastal edge of the Northeast Water polynya in spring 1993

Multidisciplinary, marine ecological observations were conducted at the shallow water edge of the Northeast Water in June, 1993. Although variable in size and shape, a small polynya was constantly present at Eskimonaes, at the fast-ice edge of Ingolfsfjord. A shallow stratified layer developed at the water sufface at negative water and air temperatures—an effect of sea ice melting in cold water early in the season. Nutrients were recorded in considerable quantities, although by mid July NO₃ had become depleted. The chlorophyll and phytoplankton maxima at 8–12 m depth had peak values of 2 mg chl a m⁻³, typical for Arctic algal blooms. The phytoplankton included over 90 species and was dominated by the Fragillariopsis group. Zooplankton was poor in biomass and density, but over 23 taxa were found, with the copepods Oithona similis and Pseudocalanus acuspes being numerically dominant. Sedimentation was approximately 0.2 g dry weight m⁻² d⁻¹ and suspended matter concentrations ranged from 4 to 19 mg l⁻¹. The benthos was represented by hard bottom forms only, with a surprisingly dense cover of macrophytes. Juvenile sea urchins (Strongylocentrotus droebachiensis), brittle stars (Ophiocten sericeum) and amphipods were dominant. Higher trophic levels were represented by benthic feeders, such as eiders and walruses. The area observed was more similar to high Arctic fjord ecosystems than to the offshore central Northeast Water polynya.     

Hydrothermally degraded carbon fiber / epoxy plates subjected to underwater explosive loading in a fully submerged environment

An experimental and computational investigation was conducted to evaluate the underwater blast response of fully submerged carbon fiber composite plates after prolonged exposure to saline water. The material was a biaxial carbon fiber/epoxy composite with a [±45°] fiber orientation layup. The plates were placed in a saline water bath with a temperature of 65 °C for 35 and 70 days, which simulates approximately 10 and 20 years of operating conditions in accordance to Fick's law of diffusion coupled with Arrhenius's Equation and a reference ocean temperature of 17 °C. Underwater blast experiments were performed in a 2.1 m diameter pressure vessel. The composite plates were placed in the center of the vessel while fully submerged in water, and an RP-85 explosive was detonated at a standoff distance of 102 mm from the center of the plate. Two cases of fluid hydrostatic gage pressures were investigated: 0 MPa, and 3.45 MPa. Two high speed cameras were utilized for three-dimensional Digital Image Correlation, which provided full-field displacements and velocities of the composite plates during underwater blast loading. A third high speed camera captured the behavior of the explosive gas bubble. Moreover, the pressure fields generated by the explosive detonation and resulting gas bubble were recorded with tourmaline pressure transducers. A water diffusion study was completed which showed that the diffusion of water into the composites reached a point of complete saturation after 35 days of exposure. Quasi-static material characterization tests were performed before and after prolonged exposure to saline water. The properties obtained from quasi-static testing also served as material inputs for the numerical models. The quasi-static test results showed that the tensile modulus E_1,2 does not change with exposure to saline water, whereas the in-plane shear modulus G₁₂ decreases with saline water exposure. During blast loading, for the case of 0 MPa hydrostatic gage pressure, the gas bubble interacts with the composite plate substantially. In such an event, the out of plane displacement increased for saline water exposed plates when compared to virgin structures. For the case of 3.45 MPa hydrostatic gage pressure, the gas bubble does not visibly interact with the composite plate. In this case, the out of plane displacement for specimens exposed to saline water was similar to the virgin specimen. A fully coupled Eulerian–Lagrangian fluid structure interaction simulation was performed by using the DYSMAS code. The numerical simulations showed that the displacement of fully submerged composite plates is driven by the displacement of fluid, as well as the size of the gas bubble formed by the explosive rather than the peak pressure generated by the explosive. The numerical simulations were in agreement with the experimental findings in terms of pressure history and plate deformation.     

Estimation of air–sea CO2 fluxes in the Bay of Biscay based on empirical relationships and remotely sensed observations

An empirical algorithm has been developed to compute the sea surface CO₂ fugacity (fCO₂^sw) in the Bay of Biscay from remotely sensed sea surface temperature (SST_RS) and chlorophyll a (chl a_RS) retrieved from AVHRR and SeaWiFS sensors, respectively. Underway fCO₂^sw measurements recorded during 2003 were correlated with SST_RS and chl a_RS data yielding a regression error of 0.1 ± 7.5 µatm (mean ± standard deviation). The spatial and temporal variability of air–sea fCO₂ gradient (ΔfCO₂) and air–sea CO₂ flux (FCO₂) was analyzed using remotely sensed images from September 1997 to December 2004. An average FCO₂ of ? 1.9 ± 0.1 mol m^? 2 yr^? 1 characterized the Bay of Biscay as a CO₂ sink that is suffering a significant long-term decrease of 0.08 ± 0.05 mol m^? 2 yr^? 2 in its capacity to store atmospheric CO₂. The main parameter controlling the long-term variability of the CO₂ uptake from the atmosphere was the air–sea CO₂ transfer velocity (57%), followed by the SST_RS (10%) and the chl a_RS (2%).     

On the numerical accuracy of the wave load distribution on a ship advancing in short and steep waves

Defining numerical uncertainty is an important part of the practical application of a numerical method. In the case of a ship advancing in short and steep waves, little knowledge exists on the solution behaviour as a function of discretisation resolution. This paper studies an interface-capturing (VOF) solution for a passenger ship advancing in steep (kA = 0.24) and short waves (L _w /L _pp = 0.16). The focus is to estimate quantitative uncertainties for the longitudinal distributions of the first–third harmonic wave loads in the ship bow area. These estimates are derived from the results of three systematically refined discretisation resolutions. The obtained uncertainty distributions reveal that even the uncertainty of the first harmonic wave load varies significantly along the ship bow area. It is shown that the largest local uncertainties of the first harmonic wave load relate to the differences in the local details of the propagating and deforming encountered waves along the hull. This paper also discusses the challenges that were encountered in the quantification of the uncertainties for this complex flow case.     

Phytoplankton dynamics related to water mass properties in the Gulf of Gabes: Ecological implications

The spatial distribution of chlorophylls and carotenoids was recorded throughout the Gulf of Gabes (South Ionian Sea) in March 2007, and was related to patterns of the physical structure and the nutrient concentrations.Two distinct water masses were identified based on the temperature and salinity (T–S) analysis: a cool and less salty Modified Atlantic Water (MAW) and a saltier Mediterranean Mixed Water (MMW). There was no significant difference in the mean nitrogen and phosphate concentrations between MMW and MAW, although the silica values were significantly higher in MAW. The Integrated chlorophyll a mean value was about 4 mg m^? 2, with a maximum of 13 mg m^? 2 at MAW stations.Higher Chlorophyll a records in typical MAW stations were mainly due to chlorophytes, which contributed up to 58% of the pigments concentrations in the MAW and about 46% in the MMW. The contribution of chlorophytes to total Chlorophyll a was found to be relatively stable throughout the water column. The contribution of diatoms, which were twofold higher in the MMW than in the MAW, did not exceed 17% of chlorophyll a and was mainly due to subsurface maxima. The chlorophytes, pelagophytes, prymnesiophytes and cryptophytes all together accounted for more than 77% of total chlorophyll a in the MAW and about 67% in the MMW.There were statistically significant differences between MMW and MAW in the pigment contribution of cyanobacteria and pelagophytes. These two taxa accounted for 13% and 24% of chlorophyll a respectively in the MAW and MMW indicating that these differences concerned phytoplankton classes at relatively low contributions to total chlorophyll a.     

Local joint flexibility of tubular X-joints stiffened with external ring or external plates

In the present paper, the Local Joint Flexibility (LJF) of the ring-stiffened X-joints and plate-stiffened X-joints under compressive load is investigated. In the first phase, a finite element (FE) model was generated and verified with the results of available experimental tests and equations. In the next phase, a set number of 234 FE models were created to evaluate the role of the external ring size (β_r and τ_r), the external plate size (β_p and τ_p), and the connection geometry (γ, τ, and β) on the LJF factor (f_LJF). In these FE models, the weld connecting the chord and brace members was generated. The results indicated that the f_LJF of a plate stiffened joint can be down to 76% of the f_LJF of the corresponding un-stiffened joint. Also, the effect of the ring size on the f_LJF was more than the effect of the plate size on the f_LJF, because of the stiffener position. Despite the notable effect of the ring and the plate on the f_LJF, there is not any study or formula on tubular connections stiffened with ring or plate. Therefore, the FE results were used to propose two parametric formulas for determining the f_LJF in X-joints with external ring or external plate under brace compressive load. Moreover, the derived formulas were checked based on the UK DoE acceptance criteria.     

Carbonate chemistry dynamics and carbon dioxide fluxes across the atmosphere–ice–water interfaces in the Arctic Ocean: Pacific sector of the Arctic

Climatic changes in the Northern Hemisphere have led to remarkable environmental changes in the Arctic Ocean, which is surrounded by permafrost. These changes include significant shrinking of sea-ice cover in summer, increased time between sea-ice break-up and freeze-up, and Arctic surface water freshening and warming associated with melting sea-ice, thawing permafrost, and increased runoff. These changes are commonly attributed to the greenhouse effect resulting from increased atmospheric carbon dioxide (CO₂) concentration and other non-CO₂ radiatively active gases (methane, nitrous oxide). The greenhouse effect should be most pronounced in the Arctic where the largest air CO₂ concentrations and winter–summer variations in the world for a clean background environment were detected. However, the air–land–shelf interaction in the Arctic has a substantial impact on the composition of the overlying atmosphere; as the permafrost thaws, a significant amount of old terrestrial carbon becomes available for biogeochemical cycling and oxidation to CO₂. The Arctic Ocean's role in determining regional CO₂ balance has been ignored, because of its small size (only  4% of the world ocean area) and because its continuous sea-ice cover is considered to impede gaseous exchange with the atmosphere so efficiently that no global climate models include CO₂ exchange over sea-ice. In this paper we show that: (1) the Arctic shelf seas (the Laptev and East-Siberian seas) may become a strong source of atmospheric CO₂ because of oxidation of bio-available eroded terrestrial carbon and river transport; (2) the Chukchi Sea shelf exhibits the strong uptake of atmospheric CO₂; (3) the sea-ice melt ponds and open brine channels form an important spring/summer air CO₂ sink that also must be included in any Arctic regional CO₂ budget. Both the direction and amount of CO₂ transfer between air and sea during open water season may be different from transfer during freezing and thawing, or during winter when CO₂ accumulates beneath Arctic sea-ice; (4) direct measurements beneath the sea ice gave two initial results. First, a drastic pCO₂ decrease from 410 μatm to 288 μatm, which was recorded in February–March beneath the fast ice near Barrow using the SAMI-CO₂ sensor, may reflect increased photosynthetic activity beneath sea-ice just after polar sunrise. Second, new measurements made in summer 2005 beneath the sea ice in the Central Basin show relatively high values of pCO₂ ranging between 425 μatm and 475 μatm, values, which are larger than the mean atmospheric value in the Arctic in summertime. The sources of those high values are supposed to be: high rates of bacterial respiration, import of the Upper Halocline Water (UHW) from the Chukchi Sea (CS) where values of pCO₂ range between 400 and 600 μatm, a contribution from the Lena river plume, or any combination of these sources.