Biogeochemistry of sulfur in a sediment core from the west-central Baltic Sea: Evidence from stable isotopes and pyrite textures

The biogeochemistry of the sulfur cycle in a ca. 5-m-long sediment core from the eastern slope (221 m water depth) of the Landsort Deep in the west-central Baltic Sea was investigated by analyzing the solid phase records of sulfur isotopes and pyrite textures, besides selected main and minor elements. The sediments were deposited during post-glacial history of the Baltic Sea when the basin experienced alteration of brackish (Yoldia Sea, Littorina Sea) and freshwater (Baltic Ice Lake, Ancylus Lake) conditions. The stable isotopic composition of total sulfur was analyzed as a function of depth. In selected samples pyrite (FeS₂), greigite (Fe₃S₄), and barite (BaSO₄) fractions were separated for isotope analyses. Pyrite textures were analyzed by SEM and optical microscopy.Microbial reactions associated with the oxidation of organic matter resulted in assemblages of authigenic sulfide minerals which for the post-Ancylus Lake brackish water environment are dominated by pyrite and for freshwater environments by Fe-monosulfides. The sulfur isotopic composition of the brackish water Littorina Sea sediments (δ³⁴S between −40 and −27‰ vs. V-CDT) is believed to be determined by cellular sulfate reduction rates and reactions involving intermediate sulfur species. The availability of reactive iron and decomposable organic matter as well as sedimentation rate and the chemocline position are important variables upon the δ³⁴S values of sulfides in brackish water environment. The syn-depositional abundance of sulfur and organic matter, and transport of dissolved sulfur species vs. rates of microbial reactions determine δ³⁴S in the freshwater sediments. The upper part of the Ancylus Lake sediments is sulfidized by downward diffusing H₂S and/or sulfate from overlying brackish water sediments. Minor concretionary barite formation in the freshwater sediments is most likely due to the reaction of pore water sulfate diffusing downward from brackish water sediments with barium desorbed from freshwater sediments. The size distribution of pyrite framboids in the brackish sediments indicates that the formation mainly occurred from anoxic pore waters, although some pyrite formation in an anoxic water column cannot be excluded.     

An Assessment of Integrated Coastal Management Governance and Implementation Using the DPSIR Framework: KwaZulu-Natal,South Africa

Coastal areas are under increasing pressure driven by demands for coastal space, primarily though population growth, in migration and the need for space for socioeconomic activities. The pressures and associated changes to the coastal environment need to be managed to ensure long-term sustainability. South Africa has enacted an Integrated Coastal Management Act (ICM Act) to facilitate dedicated management of its coastal environment. The implementation has been met with a number of challenges, primarily relating to financial and human capacity constraints, particularly at the local government level. Given that the ICM Act devolves powers to local government, it is imperative that implementation challenges be addressed. This paper focuses on KwaZulu-Natal, one of four South African coastal regions, which is a renowned tourist destination and home to 11.1 million people (Statistics South Africa 2015 Statistics South Africa. 2015. Mid-Year Population Estimates. Statistical release P0302. Pretoria, South Africa: Statistics South Africa. [Google Scholar]). This paper considers the state of coastal management, as well as implementation challenges being experienced at a local governance level, and highlights ways to address these. Data were acquired through questionnaire surveys and semistructured interviews. The Drivers-Pressures-State-Impact-Response (DPSIR) framework was used to identify relevant ICM issues and concerns and develop potential actions for improving the implementation of coastal management activities and the ICM Act. In the assessment of the ICM governance and implementation to date, a key concern identified was a general lack of coastal management knowledge among officials. It was specifically identified that knowledgeable management and capacity-building required championing from the provincial government in order to more efficiently and effectively implement the objectives of the ICM Act through an improved understanding of the coastal environment, its functioning and management.     

A conflict model and interactive simulator (FASTCARS) for predicting enroute driver behavior in response to real-time traffic condition information

This paper proposes a theoretical methodology and practical data collection approach for modeling enroute driver behavioral choice under Advanced Traveler Information Systems (ATIS). The theoretical framework is based on conflict assessment and resolution theories popularized in psychology and applied to models of individual consumer behavior. It is posed that enroute assessment and adjustment is a reactionary process influenced by increased conflict arousal and motivation to change. When conflict rises to a level at which conflict exceeds a personal threshold of tolerance, drivers are likely to alter enroute behavior to alleviate conflict through either route diversion of goal revision. Assessment and response to conflict arousal directly relate to the driver's abilities to perceive and predict network conditions in conjunction with familiarity of network configurations and accessible alternate routes.Data collection is accomplished through FASTCARS (Freeway andArterialStreetTrafficConflictArousal andResolutionSimulator), in interactive microcomputer-based driving simulator. Limited real-world implementation of ATIS has made it difficult to study or predict individual driver reaction to these technologies. It is contended here that in-laboratory experimentation with interactive route choice simulators can substitute for the lack of real-world applications and provide an alternate approach to data collection and driver behavior analysis. This paper will explain how FASTCARS is useful for collecting data and testing theories of driver behavior.     

Transport policy in Eastern Europe a case study of Hungary

This paper analyses the development of transport policy making in Eastern Europe over the last forty years and describes the role of the CMEA in determining national developments in Poland, Romania, East Germany, Czechoslovakia, Hungary and Bulgaria. The USSR, Albania and Yugoslavia are excluded. The planning system as operated in the Eastern Block, is described, followed by a particular case study of Hungarian policy making with respect to the transport sector. Specific tansport issues relating to Hungary are outlined before conclusions are drawn in terms of future developments in relation with the European Community.     

Forecasting tanker freight rate using neural networks

Improvement in forecasting accuracy is a difficult task but critical for business success. This paper investigates the potential of neural networks for short- to long-term prediction of monthly tanker freight rates. Procedures are outlined for the development of the neural networks. The problem of under-training and over-training is addressed by controlling the number of iterations during the training process of neural networks. A comparative study of predictive performance between neural networks and ARMA time series models is conducted. Our evience shows that neural networks can significantly outperform time series models, especially for longer-term forecasting.     

Positional change in the Polish liner shipping market: a framework approach

This paper examines the changing position of Polish Ocean Lines (POL) container shipping activities in the North Atlantic, in the light of social, political and economic changes occurring in Poland. An analysis is made of alternative ways of assessing company position—ranging from the qualitative to the quantitative—and that of a qualitative framework approach is selected. Application of this framework using POL as a case study provides an indication of positional change between 1988 and 1993 reflecting the period of major change in Eastern Europe.     

Analyzing the preference for non-exclusive forms of telecommuting: Modeling and policy implications

This study examines three models of the individual's preference for home- and center-based telecommuting. Issues concerning the estimation of discrete models when the alternatives are non-exclusive are discussed. Two binary logit models are presented, one on the preference to telecommute from a center versus not telecommuting from a center (adjusted ² = 0.24), and the other on the preference to telecommute from a center over telecommuting from home (adjusted ² = 0.64). A nested logit model is also estimated on the following four alternatives: preferring not to telecommute, preferring either form of telecommuting, preferring to telecommute from home, and preferring to telecommute from a center (adjusted ² = 0.35).The results of the models illustrated the importance of attitudinal measures in measuring an individual's preference to telecommute. Oblique factor scores representing workplace interaction, stress, workaholism, internal control, and commute stress were statistically significant in some or all of the models. Other explanatory variables which were found to be consistently significant were education, job suitability, and age. Most respondents preferred either to telecommute from home or were indifferent between either form of telecommuting, which raises the question as to whether there really is a sizeable market niche to be filled by telecommuting centers, and hence whether they may make a significant contribution to transportation demand reduction.     

The convergence of diagonalization algorithms for asymmetric network equilibrium problems

We provide a sufficient condition for the convergence of diagonalization algorithms for equilibrium traffic assignment problems with asymmetric Jacobian matrix B(v) of the link user cost mapping s(v) of the flow v. When

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, where D(v^*) > 0 is the diagonal of B(v^*) and v^* is the equilibrium flow, we demonstrate a local convergence theorem for nonlinear cost functions. The implication of this result for practical applications of the model are outlined.     

A parking model hierarchy

The last decade has seen considerable developments in computer assisted design procedures which enable planners to investigate the impacts of changes in the transport system. These developments have become more available to analysts through the introduction of microcomputers and computer graphics. Unfortunately, the impacts of parking on the transport have not been incorporated explicitly in many of these models since their prime concern is the movement of traffic. Parking system design and policy analysis can, however, benefit greatly from these developments in computer technology and availability. The design of parking systems can be improved and the investigation of policy impacts can be trialed or refined prior to their introduction using microcomputer packages. This paper outlines some developments in these areas. More specifically, it outlines a hierarchy or microcomputer models and information systems that can investigate parking policy and study the level of service provided by parking systems.