Monitoring trace elements (Al, As, Cr, Cu, Fe, Mn, Ni and Zn) in deep and surface waters of the estuary of the Nerbioi-Ibaizabal River (Bay of Biscay, Basque Country)

Deep water samples (in contact with the sediment) were collected at eight different points of the estuary of the Nerbioi-Ibaizabal River (Bay of Biscay, Basque Country), both at low and high tides, during four sampling campaigns (May, September and December 2005 and March 2006). Superficial water was also sampled in March 2006. Temperature, pH, redox potential, dissolved oxygen and electrical conductivity corresponding to each sample were measured in situ at each sampling point using a multiparametric probe. The physico-chemical parameters found are typical of highly stratified estuaries, with an acceptable oxygenation level. After filtering and acidifying the samples, they were analysed by inductively coupled plasma/mass spectrometry (ICP/MS) to simultaneously determine the total concentration of Al, As, Cr, Cu, Fe, Mn, Ni and Zn. Concentrations in the μg kg^− 1 level were found in all cases (c_Cr and c_Ni, 1–10; c_Al, c_As and c_Zn, 10–50; c_Cu and c_Mn, 10–100 and c_Fe, 100–400 μg kg^− 1). A probable net input of Al, Cr, Mn and Zn via the main (Nerbioi-Ibaizabal) and some of the tributary rivers (Galindo, Asua and Gobela) was identified. Evidence of a common source of Al and Zn to the estuary was found. Correlation analysis of data revealed connections between variables (concentration of Cu, Fe and As with salinity, as well as c_Al with c_Zn, c_Cu with c_Fe, c_As with c_Fe, and c_As with c_Cu). Principal Component Analysis (PCA) of data allowed the samples to be grouped according to sampling campaign, with two principal components accounting for 62% of the total variance. In addition, plots of element concentration against salinity suggested a conservative behaviour for As, Cu and Fe and a non-conservative one for Cr. Not clear mixing behaviour was observed for the rest of elements.     

Transit costs and cost efficiency: Bootstrapping non-parametric frontiers

This paper explores a selection of recently proposed bootstrapping techniques to estimate non-parametric convex (DEA) cost frontiers and efficiency scores for transit firms. Using a sample of Norwegian bus operators, the key results can be summarized as follows: (i) the bias implied by uncorrected cost efficiency measures is numerically important (close to 25%), (ii) the bootstrapped-based test rejects the constant returns to scale hypothesis, and (iii) explaining patterns of efficiency scores using a two-stage bootstrapping approach detects only one significant covariate, in contrast to earlier results highlighting, e.g., the positive impact of high-powered contract types. Finally, comparing the average inefficiency obtained for the Norwegian data set with an analogous estimate for a smaller French sample illustrates how the estimated differences in average efficiency almost disappear once sample size differences are accounted for.     

About attitudes and perceptions: finding the proper way to consider latent variables in discrete choice models

We provide an in-depth theoretical discussion about the differences between individual-specific latent constructs (representing attitudes, for example, but also other characteristics such as values or personality traits) and alternative-specific latent constructs (that may represent perceptions) affecting the choice-making process of individuals; we also carry out an empirical exercise to analyze their effects. This discussion is of importance, as the majority of papers considering attitudinal latent variables just take these as attributes affecting directly the utility of a certain alternative, while systematic taste variations are rarely considered and perceptions are mostly ignored. The results of our case study show that perceptions may indeed affect the decision making process and that they are able to capture a significant part of the variability that is normally explained by alternative specific constants. Furthermore, our results indicate that attitudes may be a reason for systematic taste variations, and that a proper categorization of latent variables, in accordance with underlying theory, may outperform the customary assumption of linearity.     

Multi-agent simulation of adoption of alternative fuels

We have formalized and parameterized a model for the production of six transport fuels and six fuels blends from six feedstocks through 13 different production chains, and their adoption of by 11 distinct subpopulations of motorists. The motorists are represented by agents that use heuristics to choose a fuel on the basis of three attributes and a social feedback loop. Adoption of specific fuels is mostly driven by price differences, but other factors play a role if prices are similar. The results are not always intuitive and do not always show up immediately. We find that sustained combinations of interventions are required to bring about a transition away from petrol or diesel. Adoption of alternative fuels was most often confined to niche markets with a share of 5% or lower. Only in a single case was a complete fuel transition observed.     

Annual uptake of atmospheric CO2 by the Weddell Sea derived from a surface layer balance, including estimations of entrainment and new production

Data from two cruises, one in April/May 1996 and one in December/January 1993, covering the same wide area in the offshore Weddell Sea, were used to derive the annual extent of entrainment and the capacity of the biological pump. The former property was obtained with the help of dissolved oxygen data, whereas the latter was approximated with nutrients. Especially the data from April/May, representing the initial state of the winter surface layer, were crucial to assess the annual extent of these processes. The results were applied to our carbon dioxide data. The annual increase of the Total CO₂ (TCO₂) concentration in the surface layer due to vertical transport amounts to 16.3 μmol kg⁻¹. An entrainment rate of deep water in the surface layer amounting to 35±10 m yr⁻¹ was deduced. The compensating, biologically mediated TCO₂ reduction was calculated to be larger than the TCO₂ increase due to vertical transport. Since the balance of these two processes determines whether the Weddell Sea is a source or a sink of CO₂, this indicates that the Weddell Sea, albeit upwelling area, is definitely a sink for atmospheric CO₂ on an annual basis. This conclusion is further supported by contemplations that the biological drawdown of CO₂ in the Weddell Sea as a whole is probably underestimated by our calculations. The new production for the Weddell Sea on a per unit area basis was found to be much higher than that for the Antarctic Ocean, when the latter value is being obtained by traditional biological methods. On the other hand, the CO₂ uptake by the Weddell Sea on a per unit area basis is somewhat smaller than the CO₂ uptake by the world ocean.     

柴油机绿色设计与制造技术

从绿色设计的要求出发 ,分析探讨了与柴油机绿色设计与制造有关的几个问题 ,介绍了降低柴油机环境污染提高其环境友好度的各种措施及方法     

非饱和土体气态水迁移引起的含水量变化方程

基于现有土力学理论及流体力学理论 ,结合非饱和土气态水迁移特征 ,得到了根据土体基质吸力和温度确定土孔隙饱和蒸气压力的表述关系式 ,推导得到非饱和土体中气态水迁移引起含水量变化的非稳态方程 ,方程揭示了气态水迁移的动力是温度梯度和含水量梯度 ,气态水迁移现象是温度不均匀分布和含水量不均匀分布单独或共同作用的表现形式 ,方程表述了实验揭示的现象。最后应用含水量变化方程对实验结果进行了计算分析 ,验证了该方程的合理性     

Short trips: An opportunity for reducing mobile-source emissions?

This paper examines how conversion of automobile trips of less than 3 miles to other transportation modes reduces emissions. Short trips contribute disproportionately to emissions because of cold starts. An analysis is conducted of short-trip behavior across the US using the 1995 Nationwide Personal Transportation Survey. The data is used to develop likely scenarios of mode conversions for short trips, which are then applied to estimate emission savings using MOBILE6 cold start and running emission factors for volatile organic compounds, nitrogen oxides, carbon monoxide, and carbon dioxide. The results suggest that reducing short auto trips would modestly reduce mobile source air pollution, but emission reductions are high compared to most federally-funded surface transportation interventions aimed at improving air quality. Enhanced the community pedestrian environment to encourage short trip mode conversion also produces co-benefits such as increased physical activity and subsequent reductions in chronic diseases.     

Residence time,exposure time and connectivity in the Scheldt Estuary

Residence times and exposure times are computed for 13 boxes in the Scheldt Estuary, using the high-resolution tracer-transport model SLIM. The concepts are clearly defined and related to how they should be computed. First, the timescale values are compared with results published previously that were obtained with a simple box model, and an unexpected difference is revealed. This may suggest that a high-resolution model is necessary, even for the computation of such integrated quantities as residence or exposure times. Secondly, the newly computed residence times are compared to the exposures times to illustrate their intrinsic differences. From this difference, it is possible to propose a return coefficient, expressing the fraction of the exposure time that is due to “returning water”, i.e. water which has already left the estuary at least once. Finally, the estuarine exposure times are decomposed into the different box exposure times, resulting in a connectivity matrix. This matrix expresses how much time is spent in each of the estuarine subdomains during the water parcels' journey through the estuary.     

Impact of biometric and anthropometric characteristics of passengers on aircraft safety and performance

Demand for commercial air travel has been increasing over the years and recent forecasts indicate similar future trends. New aircraft with enhanced design features are being built and entering the airline service globally. These enhancements aim to ensure continued safety, efficiency, performance and prolonged life serviceability. However, these new enhancements often neglect the impact of the changing anthropometric characteristics of the passenger. Past studies have identified increasing trends in the average weight, height and other anthropometrical and biometrical measures of people at a global scale. However, many are limited to only exploring the ramifications primarily from the perspective of passenger experience. This paper highlights the importance of considering passengers’ anthropometric characteristics from a holistic perspective and identifies gaps for future research.