Predictive Model for Corrosion Rate of Oil Tubes in CO2／He S Coexistent Environment Part Ⅰ： Building of Model

Based on an analysis of the existing models of CO2 corrosion in literatures and the autoclave simulative experiments, a predictive model of corrosion rate (γcorr ) in CO2/H2S corrosion for oil tubes has been established, in which γcorr is expressed as a function of pH, temperature (T) , pressure of CO2 ( Pco2 ) and pressure of H2S (PH2S). The model has been verified by experimental data obtained on N80 steel. The improved features of the predictive model include the following aspects: ( 1 ) The influence of temperarare on the protectiveness of corrosion film is taken into consideration for establishment of predictive model of the γcorr in CO2/H2S corrosion. The Equations of scale temperature and scale factor are put forward, and they fit the experimental result very well. (2)The linear relationship still exists between In γcorr and In Pco2 in CO2/H2S corrosion ( as same as that in CO2 corrosion). Therefore,a correction factor as a function of PH2s has been introduced into the predictive model in CO2/H2 S corrosion. ( 3 ) The model is compatible with the main existing models.     

注汽管道承压能力评估和实物试验验证

基于失效评估图技术对某注汽管道进行了承压能力评价,给出了管线在不同腐蚀壁厚情况下的极限承压能力和极限裂纹尺寸。并利用实物爆破试验验证了评价方法的安全性和有效性,通过对爆破断口进行宏观和微观分析,发现管段的开裂属于脆性开裂。     

腐蚀管道剩余寿命预测方法

基于可靠性理论,提出了一种预测管道腐蚀剩余寿命的新方法,即管道腐蚀可靠性寿命预测方法。该方法包括建立腐蚀管道的失效状态函数、腐蚀速率等变量的概率分布模型、管道失效概率和可靠度随时间的变化规律;然后根据管道所处地区级别和风险等级给定目标可靠度,确定管道的腐蚀剩余寿命。运用此方法预测了新疆采油一厂红浅注汽管道的腐蚀剩余寿命,为该管道腐蚀检测周期的确定提供了科学依据。     

Predictive Model for Corrosion Rate of Oil Tubes in CO_2/H_2S Coexistent Environment Part Ⅰ: Building of Model

Introduction　　Sincethecorrosionofoiltubesinbrinesolutionscontainingcarbondioxide (CO2 )andhydrogensulfide(H2 S)gasesisasevereprobleminengineering ,itisveryurgenttobuildapredictivemodelofthecorrosionrate(rcorr)foroiltubesinCO2 /H2 Scoexistentenvironment …