Impact of Visible-Solar-Light-Driven photocatalytic pavement on air quality improvement

Photocatalytic pavement has attracted significant interest in the past decades by both the academia and industry for its ability of spontaneous cleaning of air pollutants, such as motor vehicle exhaust gas. Titanium dioxide (TiO₂) is used as the photocatalyst that is mixed into pavement materials or coated on the pavement to remove motor vehicle exhaust gases, e.g., carbon monoxide (CO), nitrogen oxides (NO_x), under the irradiation of the solar light. However, the pure TiO₂ additive only absorbs the light within the ultraviolet region due to its large bandgap. One approach to increase the ability of TiO₂ to the utilization of the full spectrum of the solar light is doping TiO₂. Therefore, this visible-solar-light-driven photocatalytic pavement embedded with doped-TiO₂ will exhibits a better cleaning efficiency of exhaust gas. This work conducted computational simulations of the cleaning efficiency on reducing exhaust gas NO₂ by photocatalytic pavement with doped-TiO₂, and its subsequent influence on the air quality in the surrounding environment. A three-dimensional model was developed for a section of pavement and its vicinal region. Effects of weather conditions, doped-TiO₂ coverages, road widths and traffic flow conditions on the removal of NO₂ and its influence to the adjacent environment were studied. Results indicate that visible-solar-light-driven photocatalytic pavement with doped-TiO₂ features a significantly higher removal efficiency of exhaust gas compared with the normal photocatalytic pavement. Moreover, the doped-TiO₂ embedded pavement is effective to remove NO₂ with different traffic densities and wind conditions, and consequently improve the air quality of the surrounding environment.