| 氰基桥联配合物的溶剂热合成研究进展 |
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| 引用本文： | 袁爱华,楚超霞,周虎,张颖.氰基桥联配合物的溶剂热合成研究进展[J].江苏科技大学学报(社会科学版),2009,23(3):217-224. |
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| 作者姓名： | 袁爱华 楚超霞 周虎 张颖 |
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| 作者单位： | 江苏科技大学,材料科学与工程学院,江苏,镇江,212003
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| 基金项目： | 江苏省高校自然科学基金资助项目 |
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| 摘 要： | 介绍了以MCN（M=Na，K）和K3M’（CN）6]（M’=Fe，Co）为氰基来源的氰基桥联配合物溶剂热合成的研究进展。讨论了影响溶剂热合成氰基桥联合物的主要因素，如：反应条件、有机配体、氰基来源、平衡离子、溶剂种类及摩尔比等．最后指出了目前存在的问题，并对今后的研究趋势进行了展望．
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| 关 键 词： | 氰基桥联 配合物 溶剂热 合成 |
Developments of solvothermal synthesis of cyano-bridged complexes |
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| Yuan Aihua,Chu Chaoxia,Zhou Hu,Zhang Ying.Developments of solvothermal synthesis of cyano-bridged complexes[J].Journal of Jiangsu University of Science and Technology:Natural Science Edition,2009,23(3):217-224. |
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| Authors: | Yuan Aihua Chu Chaoxia Zhou Hu Zhang Ying |
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| Institution: | School of Materials Science and Engineering;Jiangsu University of Science and Technology;Zhenjiang Jiangsu 212003;China |
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| Abstract: | The recent progress of solvothermal synthesis of cyano-bridged complexes based on MCN（M = Na, K） and K3 M＇（ CN）6 ] （M＇ = Fe,Co） as the sources of cyano ligands was introduced in this paper. Then, the main factors influencing the solvothermal synthesis of cyano-bridged complexes were discussed, such as reaction conditions, organic ligands, cyano sources, counter-ions, solvents, molar ratio, and so on. Finally, the main problems at present were pointed, and the development trends were forecasted. |
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| Keywords: | cyano-bridged complexes solvothermal synthesis |
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