| 有机锂皂石的膨胀性能影响规律的研究 |
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| 引用本文： | 聂建华,王俊,戴春桃,郑大锋,李平辉.有机锂皂石的膨胀性能影响规律的研究[J].华东交通大学学报,2011(6):63-67. |
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| 作者姓名： | 聂建华 王俊 戴春桃 郑大锋 李平辉 |
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| 作者单位： | 中山职业技术学院;华南理工大学化学与化工学院 |
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| 摘 要： | 从锂皂石原矿中提纯出精矿,经不同浓度的稀盐酸处理得到层电荷数逐渐降低的锂皂石样品,然后对其进行钠化,再与十六烷基三甲基溴化铵(CTAB)反应从而制得有机锂皂石.有机锂皂石在硝基苯中的黏度和红外光谱分析表明当盐酸浓度为0.2 moL· L-1时,锂皂石的层状结构几乎保持不变,此时层电荷数降低到了黏度最大的临界点.有机化最...
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| 关 键 词： | 锂皂石 层电荷数 膨胀 有机改性 |
A Research on the Swelling Property of Hydrophobic Hectorite |
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| Nie Jianhua,Wang Jun,Dai Chuntaoi,Zheng Dafeng,Li Pinghui.A Research on the Swelling Property of Hydrophobic Hectorite[J].Journal of East China Jiaotong University,2011(6):63-67. |
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| Authors: | Nie Jianhua Wang Jun Dai Chuntaoi Zheng Dafeng Li Pinghui |
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| Institution: | 1(1.Zhongshan Polytechnic,Zhongshan 528404,China;2.School of Chemistry and Chemical Engineering,South China University of Technology,Guangzhou 510640,China) |
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| Abstract: | The hectorite is extracted from a raw ore, and then is treated in dilute hydrochloric acid of different concentrations to prepare a series of samples with sequentially reduced layer charge which is treated with sodiurn salt and is modified by cetyltrimethylammonium bromide （CTAB） subsequently. The viscosity of hydrophobic hectorite on nitrobenzene and FT-IR spectroscopy indicate that when the concentration of hydrochloric acid is 0.2 moL/L, the layer structure of hectorite almost keeps intact, and its layer charge decreases to a critical point in which the viscosity of the corresponding hydrophobic hectorite on nitrobenzene reaches its peak. The optimum process conditions of organic modification are as follows： the dosage of CTAB is 1.4CEC, the reaction temperature is 80℃and the reaction time is 12 hours. |
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| Keywords: | hectorite layer charge swell organic modification |
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