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The contribution of road traffic to particulate matter and metals in air pollution in the vicinity of an urban road
Institution:1. Department of Highway Engineering, Faculty of Civil Engineering, University of Zilina, Univerzitna 8215/1, 010 26 Zilina, Slovakia;2. Comenius University in Bratislava, Faculty of Natural Sciences, Institute of Laboratory Research on Geomaterials, Mlynska dolina, 842 15 Bratislava 4, Slovakia;1. Laboratory of Respiration Physiology, Carlos Chagas Filho Institute of Biophysics, Universidade Federal do Rio de Janeiro, São Paulo, Brazil;2. Laboratory of Inflammation, Fundação Oswaldo Cruz, São Paulo, Brazil;3. Laboratory of Inflammation, Institute of Biomedical Sciences, Universidade Federal do Rio de Janeiro, São Paulo, Brazil;4. Laboratory of Experimental Air Pollution, Department of Pathology, School of Medicine, Universidade de São Paulo, São Paulo, Brazil;1. Univ. Grenoble Alpes, CNRS, IRD, G-INP, IGE, F-38000, Grenoble, France;2. ANDRA DRD/GES Observatoire Pérenne de l’Environnement, F-55290, Bure, France;3. Lig’Air, F-45590, Saint-cyr-en-Val, France;4. Atmo Grand Est, F-67300, Schiltigheim, France;5. Atmo AuRA, F-38400, Grenoble, France;6. Atmo Occitanie, F-31770, Colomiers, France;7. Univ. Savoie Mont-Blanc, LCME, F-73000, Chambéry, France;1. Polymer Petroleum and Coal Chemistry Group, Materials Science and Technology Division, CSIR-North East Institute of Science and Technology, Jorhat, 785006, Assam, India;2. Academy of Scientific and Innovative Research, CSIR-NEIST Campus, Jorhat, 785006, India;1. Institute of Earth Sciences, University of Iceland, Iceland;2. Icelandic Meteorological Office, Iceland;3. Environment and Natural Resources, University of Iceland, Iceland;1. Division of Environmental Health and Risk Management, School of Geography, Earth and Environmental Sciences, University of Birmingham, Edgbaston, Birmingham, B15 2TT, United Kingdom;2. School of Earth Sciences and Resources, China University of Geosciences, Xueyuan Road 29, 100083, Beijing, China;3. Ministry of Education Key Laboratory for Earth System Modeling, Department of Earth System Science, Tsinghua University, Beijing, 100084, China;4. School of Light Industry, Beijing Technology and Business University, Beijing, 100048, China;5. SKL-ESPC and BIC-ESAT, College of Environmental Sciences and Engineering Peking University, Beijing, 100871, China;6. State Environmental Protection Key Laboratory of Sources and Control of Air Pollution Complex, Beijing, 100084, China;7. State Key Joint Laboratory of Environment, Simulation and Pollution Control School of Environment, Tsinghua University, Beijing, 100084, China
Abstract:A detailed investigation was conducted to study the sources of particulate matter in the vicinity of an urban road in Žilina. To determine the amount of particulate matter (PM10, PM2.5 and PM1) present in the ambient air, a reference gravimetric method was used. The main objective of this contribution was to identify the sources of these particles by means of statistical methods, specifically principal component analysis (PCA), factor analysis (FA), and absolute principal component scores (APCS), as well as using the presence of 17 metals in the particulate matter (Na, Mg, Al, Ca, V, Cr, Fe, Mn, Ni, Cu, Zn, As, Mo, Sb, Cd, Ba, Pb). To identify the metals in the particulate matter samples and to determine their abundances, spectroscopic methods were used, specifically inductively coupled plasma mass spectrometry (ICP-MS). Each of these metals may come from a specific source, such as the burning of fossil fuels in fossil fuel power plants; local heating of households; the burning of liquefied fossil fuels in the combustion engines of vehicles; the burning of coal and wood; non-combustion related emissions resulting from vehicular traffic; resuspension of traffic-related dust; and industry. Diesel vehicles and non-combustion emissions from road traffic have been identified as two key sources of the particulate matter. The results reveal that non-combustion emissions, which are associated with the elements Na, Fe, Mn, Ni, Zn, Mo, Sb, Cd, and Pb, are the major contributors, followed by combustion emissions from diesel vehicles, which are associated with the elements Mg, Ca, and Ba.
Keywords:Particulate matter (PM)  Sources of PM  Air pollution  Metals  Statistical methods
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