重型汽车铝水箱的防腐蚀成膜研究 |
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引用本文: | 王庆国,白培谦.重型汽车铝水箱的防腐蚀成膜研究[J].汽车实用技术,2012(7):38-41. |
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作者姓名: | 王庆国 白培谦 |
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作者单位: | 陕西重型汽车集团有限公司,陕西西安,710200 |
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摘 要: | 本文调查分析了陕汽重卡铝水箱腐蚀渗漏情况,通过实验分析了铝合金在不同缓蚀剂、促进剂、pH值等条件下的成膜情况,以及各种膜在盐雾、盐水浸泡等条件下的腐蚀实验。结果表明:在酸性溶液中,钼酸纳对铝有着良好的缓蚀作用,其缓蚀机理主要是酸根离子会吸附在铝的表面,阻止了铝的溶解,起到保护的作用。另外钼酸盐是弱氧化剂,在酸溶液中被铝还原,生成深蓝色的钼蓝,钼蓝也会吸附到铝的表面,从而抑制阳极反应1];其防腐效果明显,给铝水箱漏水防治提供了可行方案。
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关 键 词: | 汽车 铝水箱 防腐 钼酸钠 成膜 |
Heavy-duty automotive aluminum tank anti-corrosion film |
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Authors: | Wang Qingguo Bai Peiqian |
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Institution: | (Shaanxi Heavy Duty Automobile Co.,Ltd,Shaanxi Xi’an 710200) |
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Abstract: | This paper investigates and analyzes the Shaanxi Auto heavy track aluminum tank corrosion leakage, through the experimental analysis of aluminum alloy corrosion inhibitor in different,to promote the film-forming agent,pH,and other conditions,as well as a variety of membranes in the salt spray,salt watercorrosion test under the soaking conditions.The results showed that:in acidic solution,molybdate is satisfied that good inhibition of aluminum corrosion inhibition mechanism of the radical ion adsorbed on the surface of the aluminum to prevent the dissolution of the aluminum,play a protective role.In addition, molybdate weak oxidants,aluminum reduction in acid solution,to generate dark blue molybdenum blue, molybdenum blue also adsorbed onto the aluminum surface,thus inhibiting the anodic reaction1];its anti-corrosion effect,the aluminum tank leaking prevention and treatment provides a viable solution. |
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Keywords: | automobile aluminum tank corrosion: sodium molybdate: Fdm |
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