柴油/GTL混合燃料特性及对柴油机排放的影响

研究了不同比例的柴油与天然气合成油(GTL)混合燃料的主要理化特性,采用ECER49十三工况法测试了一台增压柴油机燃用各种混合燃料的有害排放。结果显示:随GTL比例的增加,混合燃料的密度、硫和芳烃含量逐渐减小,黏度、十六烷值和低热值逐步增大,以70%馏出率为界,GTL馏程从大于变为小于柴油的馏程;与柴油相比,GTL能降低所有常规排放,且随GTL比例增加,降低趋势愈明显。     

Investigation of soot formation in Diesel-GTL fuel blends under quiescent conditions

In this study, a visual investigation of sprays and flames is performed, and soot formation in Diesel-GTL fuel blends is studied in a specially designed quiescent constant-volume chamber under various ambient gas temperatures and O₂ concentrations. Similar to the case of soot formation during diesel fuel combustion, the sooting zone during the mixing-controlled combustion of Diesel-GTL blends is located in the leading portion of the jet boundaries. Auto-ignition delay and soot concentration decrease with an increase of GTL content in the fuel blend. Soot also decreases with lower O₂ concentration, higher injection pressure, and lower ambient gas temperature. The lack of soot formation at lower O₂ concentrations and lower temperatures suggests that Diesel-GTL fuel blends can be successfully utilized in low-temperature diesel combustion technologies that are currently being developed. Furthermore, this mixing controlled combustion method with Diesel-GTL blends can be used to modulate various engine operation parameters, and therefore to simultaneously reduce the formation of soot and NOx within a wide range of diesel engine loads.     

重型柴油机燃用不同柴油替代燃料的性能研究

对乖型柴油机燃用纯柴油、体积混合比例为1:9的天然气合成油(GTL柴油)与柴油混合燃料(G10)、体积混合比例为1:9的生物柴油与柴油混合燃料(BD10)、纯GTL柴油(G100)及纯牛物柴油(BD100)5种燃料的动力性、经济性及燃烧特性进行了研究.结果表明,BD10、G10与纯柴油有相似的燃烧特性,额定转速F G100的缸内工作压力增大,BD100的缸内工作压力显著降低;G10油耗较之BD10降低2.43%,功率较之BD10平均高2.78%;与燃用纯柴油的油耗相比,G100平均降低2.62%,BD100平均高出13%;除NOx排放外,生物柴油在降低CO、HC、PM的排放上均有所改善.     

柴油机掺烧生物柴油NO_x和Soot排放控制研究

对柴油机燃用生物柴油-0号柴油混合燃料的NO_x和Soot排放特性进行了仿真研究。在柴油机参数不作任何改变的情况下燃用体积分数分别为10%,20%,30%,40%和50%的生物柴油混合燃料,与原机的NO_x和Soot排放特性进行对比。研究表明:随着混合燃料中生物柴油体积分数的增加,柴油机Soot排放降低,NO_x排放增大。EGR的引入使柴油机NO_x排放降低,同时也使Soot排放增加。在1 800r/min中低负荷工况下,大比例生物柴油-0号柴油混合燃料应用于柴油机时,可通过调节EGR率使得柴油机NO_x和Soot排放都控制到与原机相当。     

柴油—生物柴油混合燃料喷雾特性试验研究

采用高分辨率数码照相机对柴油与柴油—生物柴油混合燃料喷雾特性进行了对比研究。结果表明,随着生物柴油掺混比的增大,燃料黏度增大,喷雾锥角变小,Sauter平均直径增大。与MB24相比,柴油的相对尺寸范围和发散边界较大,因此其Sauter平均直径比MB24混合燃料的略大。由于乙醇的稀释作用,改制油MB24的Sauter平均直径最小,雾化质量明显改善。从喷雾液滴尺寸的数目分布可以看出,所有燃料的曲线峰值均位于14μm处,小颗粒液滴较多。随着生物柴油掺混比的增大,曲线峰值下降,下降趋势均匀平缓,说明燃料黏度的增大将使雾化油滴的尺寸分布渐趋均匀。从液滴尺寸的累积体积分布可以看出,随着生物柴油掺混比的增大,达到某一累积体积的油滴直径增大,说明大颗粒油滴增多。     

Reaction characteristics of the diesel oxidation catalyst of particulate matters from the diffusion flame of a oiler burner

The objective of this experimental study is to investigate the characteristics of the size distribution and the number concentration of PM (particulate matters) emitted from the diffusion flame of a boiler burner, which has the same type of combustion as a diesel engine. This study is performed to investigate the emission characteristics of nanoparticles generated from diffusion combustion in diesel fuel, and it considered fuel factors and the reaction characteristics of the nanoparticles on the DOC (Diesel oxidation catalyst). The factors examined in this experiment included the sulfur content in the fuel, the blend of the diesel fuel containing biodiesel and bio-ethanol, and the concentration of engine oil (0.1% and 1.0%) blended with diesel fuel. The particle size distribution of the nanoparticles exhausted from the boiler burner was measured by an SMPS (scanning mobility particle sizer). The number concentration of PM that were smaller than 70 nm in diameter greatly increased in the rear of the DOC when fuel containing 250 ppm of sulfur was used. The experiment also suggested that the particle number concentration in both the front and rear of the DOC was lower when ULSD (ultra low sulfur diesel) fuel blended with biodiesel and bio-ethanol, which are oxygenated fuels, was used than when only ULSD fuel was used. The higher the content of engine oil in the fuel, the higher the particle number concentration was in the front and rear of the catalyst. When the first dilution air temperature is increased from 30°C to 180°C, the nanoparticle number concentration dramatically dropped in the rear of the catalyst when fuel containing 250 ppm of sulfur was used, while the particle size distribution remained almost the same when the fuel with engine oil was used.     

Study of diesel spray combustion and ignition using high-pressure fuel injection and a micro-hole nozzle with a rapid compression machine: improvement of combustion using low cetane number fuel

This study aimed to reduce NO_x and soot by creating a more homogeneous lean fuel distribution in a diesel spray using high-pressure fuel injection and a micro-hole nozzle. This injection system shortened the ignition delay, but a homogeneous lean fuel distribution in the diesel spray was not achieved. Using a lower cetane number fuel, the resulting longer ignition delay made a uniform, lean fuel distribution in the diesel spray possible with this injection system. Ignition and combustion were analyzed by the combustion chamber pressure history, and flame temperatures and KL values were analyzed by the two-color method.     

二甲醚／柴油混合燃料在压燃式发动机上的应用

为探索二甲醚/柴油混合燃料作为柴油机替代燃料的应用性能,对D20二甲醚/柴油混合燃料的喷雾特性进行了试验研究;同时,开展了直喷式柴油机燃用二甲醚/柴油混合燃料动力性能、经济性能及排放性能研究。结果表明:在同样的环境背压下,D20混合燃料的油束与柴油相比较,贯穿度有所缩短,喷雾锥角有所增大;柴油机燃用二甲醚/柴油混合燃料时,通过适当调整循环油量,发动机的动力性可以超过原柴油机,最低当量比油耗下降4.5%,烟度指标下降70%以上,NOx排放降低30%~50%;二甲醚/柴油混合燃料是一种能实现高比功率、低排放的石油替代燃料。     

柴油/乙醇混合燃料的性质及对发动机性能的影响

研究了不同掺混比例的柴油/乙醇(C2H5OH)混合燃料的相溶问题,分析了柴油/C2H5OH混合燃料对发动机动力性和经济性的影响,并结合13工况下试验结果分析了混合燃料对发动机HC和微粒(PM)排放的影响。实验结果表明,助溶剂可有效解决柴油的相溶问题,燃料较低的十六烷值是造成小负荷下HC和PM中可溶性有机物(SOF)排放恶化的主要因素。     

GTL燃料发动机的性能及排放特性

进行了柴油机燃用柴油、天然气制油GTL燃料及GTL-柴油混合燃料(GTL燃料体积分数分别为10％和20％)的外特性、负荷特性和ESC十三工况试验,研究了柴油机燃用GTL燃料的动力性、经济性和排放特性.试验结果表明:与燃用柴油相比,随着GTL燃料比例的增大,柴油机排放逐渐降低.燃用GTL燃料时的外特性功率和扭矩与柴油相当...     

F-T柴油与正丁醇混合燃料的燃烧和排放特性研究

F-T柴油具有十六烷值高、几乎不含硫和芳香烃的特点,正丁醇是能量密度较高的可再生的生物质燃料。在增压中冷4缸柴油机上对比研究了0号柴油、F-T柴油和F-T柴油-正丁醇混合燃料的燃烧、排放特性。结果表明:与柴油相比,掺混丁醇后缸内压力峰值、压力升高率降低;燃用F-T柴油-正丁醇混合燃料可同时降低炭烟和NO_x排放,随着正丁醇掺混比例的提高炭烟排放显著降低,F-T柴油掺混20%正丁醇的炭烟排放降幅高达67.8%,NO_x排放降幅达20.9%。     

GTL柴油作为柴油机清洁代用燃料可行性分析

综述了GTL柴油的特性及其对排放的影响,并就GTL柴油和常规柴油在柴油机中的燃烧和排放特性进行了比较。同时指出GTL柴油在发动机中应用时的润滑性和对橡胶的适应性等方面存在的问题,并探讨了解决途径。     

喷油策略对柴油机燃烧噪声及排放影响的模拟研究

进行了通过优化高压共轨系统燃油喷射策略来改善缸内燃烧排放性能的研究,基于AVL Fire软件,针对1015柴油机开展了不同燃油喷射策略下的喷雾燃烧和排放的数值模拟,建立了数学模型并验证了模型的可靠性,分析了一次预喷的预喷时刻、预喷量、主喷提前角对燃烧噪声及排放的影响,揭示了各参数对燃烧噪声和NOx及炭烟生成的影响机理,为进一步优化预喷方案提供了理论依据。     

Experimental investigation of B20 combustion and emissions under various intake conditions for low-temperature combustion

Recently, biodiesel has emerged as an alternative fuel for achieving low-temperature combustion (LTC). Several articles in the literature have showed that oxygenated biofuels, including biodiesel, can improve combustion stability under high exhaust gas recirculation (EGR) operation, which is considered to be necessary for the removal of nitric oxides (NOx). The objective of this study was to investigate the performance and emissions of 20% biodiesel blended diesel fuel (B20) at various intake pressures and oxygen concentration levels to characterize the fuel for LTC application. The experimental investigation of B20 was carried out using a single-cylinder engine (SCE) at 1400 rpm and 50% load condition. A set of critical flow orifices with synthetic EGR was employed to simulate various intake pressures and EGR levels. The behavior of the B20 was first characterized under various intake conditions. The results showed that with high oxygen intake, B20 exhibited combustion and emission levels that were very similar to conventional diesel. However, B20 reduced combustion deterioration while exhibiting lower carbon monoxide (CO) and hydrocarbon (HC) emissions than diesel under low oxygen intake conditions.     

发动机燃用水乳化柴油的研究进展

综述了柴油机燃用水乳化柴油的燃烧与喷雾特性、动力性与经济性及排放特性,对比分析了发动机燃用水乳化柴油与普通柴油在性能上的差异及其原因,总结了水乳化柴油在柴油机上的应用优化方法。结果表明:与柴油相比,乳化柴油着火滞燃期延迟,燃烧持续期缩短,喷雾贯穿距变长或相差不大,火焰升起高度增加;燃用乳化柴油时动力性下降,但有效热效率较柴油升高;乳化柴油可以明显降低NOx和炭烟排放,但多数工况下HC和CO排放有所升高,低转速和中低负荷工况下尤为明显;燃用乳化柴油时颗粒物数量浓度增加,体积浓度减小,且对于醛类和噪声排放并没有改善作用;添加合适添加剂或结合发动机技术协同作用,可以针对性地改善乳化柴油的燃烧过程,进一步起到节能减排的效果。基于燃料稳定性与燃料理化特性综合优化目标的燃料设计,以及适用于乳化柴油的高压共轨柴油机燃烧组织参数优化是未来的研究方向。     

发动机燃用生物柴油对NO_x排放影响的试验研究

在一台涡轮增压直喷式柴油机上分别燃用生物柴油、掺混油和石化柴油进行试验,对滞燃期、燃烧始点、燃烧压力、燃烧温度、预混燃烧放热规律和扩散燃烧放热规律等燃烧参数对NOx排放的影响进行了研究。结果表明,随着燃料中生物柴油含量的增加,发动机滞燃期缩短,燃烧始点提前,最高燃烧压力增加,最高燃烧温度上升,预混燃烧累积放热率减小,扩散燃烧累积放热率增大;燃烧参数的变化是造成NOx排放升高的主要原因。     

Morphology and oxidation kinetics of CI engine’s biodiesel particulate matters on cordierite Diesel Particulate Filters using TGA

The impact of small compression ignition (CI) engine operation conditions and fuel properties on diesel and biodiesel particulate matters (PMs) quantity using opacity smoke meter is investigated. The biodiesel engine’s PMs are around a half of diesel engine PMs under the same engine operation conditions. Morphology of both engine’s PMs are also studied using a Scanning Electron Microscopy (SEM), Transmission Electron Microscopy (TEM) and image processing method. The average primary nanoparticle sizes of diesel and biodiesel engine’s PMs are approximately 34 nm and 32 nm, respectively. The result shows that engine operation condition and fuel property are strongly impact on the quantity and size distribution of primary nanoparticles emission. PM oxidation kinetics on conventional cordierite Diesel Particulate Filters (DPFs) powders by Thermo-gravimetric analysis (TGA) is also successfully studied. The calculated apparent activation energies of biodiesel engine’s PM oxidation on conventional cordierite DPFs powders are lower than that of diesel engine’s PM and carbon black because of unburned oxygenated molecule. The calculated apparent activation energy of biodiesel engine’s PM and diesel engine’s PM oxidize on conventional cordierite DPFs powders with pure air are in the range of 109 ~ 131 kJ/mole and 117 ~ 130 kJ/mole, respectively. It might be expected that smaller primary nanoparticle size of biodiesel engine’s PMs and bio-oxygenate unburned hydrocarbon can promote more PM oxidation rate during vehicle’s DPF regeneration process.     

EGR回路喷甲醇在柴油机上的应用研究

在YC6A220C柴油机上进行了进气道喷甲醇结合EGR的试验研究,在保持原柴油机动力性基本不变的基础上,研究了在不同负荷下,选用不同的EGR率和不同甲醇消耗率对原机的动力性、经济性、NOx和炭烟排放的影响。研究结果表明:单纯地使用EGR对于降低NOx效果比较明显,但是难以同时降低炭烟的排放,尤其当EGR率超过30%时,随着EGR率或者负荷的增加炭烟也急剧增加。向回路喷入适量甲醇后,不但可以保证NOx排放减少,而且炭烟排放也可以大幅度降低。在1 500r/min(最大扭矩转速)下,在EGR率为20%~35%,甲醇消耗率为50~70g/(kW·h)范围内,可以同时降低NOx和炭烟排放。发动机的动力性和燃油消耗略有降低,排放水平均低于燃用0号柴油。     

甲醇—柴油混合燃料在共轨发动机上的燃烧和排放特性研究

在1台电控高压共轨增压发动机上,不改变原机结构,采用甲醇—柴油混合燃烧的方式,进行燃烧排放特性分析。结果表明:在相同转速下,发动机的当量燃油消耗率随负荷的增加而降低;随着甲醇含量增加,发动机的最高燃烧压力、最高燃烧放热率和最高燃烧温度都逐渐升高;中低负荷时,发动机的CO和HC排放随着负荷的升高而减小,燃用混合燃料时较燃用柴油略有升高,且甲醇含量越高升高越多;燃用混合燃料时发动机的NO_x和炭烟排放较燃用柴油时有所降低,且随着负荷的升高而增大。     

高压共轨柴油机燃烧与排放模型的研究

利用高速闪光摄影技术,对高压喷射喷雾体空间发展规律进行了试验分析,提出了一个计算高压喷射喷雾体发展的数学公式;在正确描述高压燃油喷雾的基础上,建立了一个能预测高压共轨柴油机性能和排放的准维燃烧模型,此模型改进了燃油喷射模型及碳烟的生成与氧化模型,考虑到燃烧区的区间传热和缸内工质的对流辐射传热,对一台高压共轨柴油机进行了仿真计算。计算与试验结果对比分析表明,改进后的燃烧与排放模型能较好地反映缸内各区的燃烧与排放情况。