基于O3H2O2处理船舶压载水过程中形成溴酸盐的研究

船舶压载水异地排放是造成外来生物入侵的主要途径之一,为此需对船舶压载水进行处理,但在杀灭有害生物的同时也产生了致癌性有毒化学副产物。本研究主要研究O₃/H₂O₂处理船舶压载水过程中溴酸盐的生成,并考察了温度、pH、溴离子浓度、H₂O₂/O₃摩尔比对其生成过程的影响。结果表明,溴酸盐含量随温度升高而降低,随溴离子含量的增加而升高,随pH增加而增加,H₂O₂/O₃摩尔比存在一个最佳范围(0.5~1)。从工程实际出发,建议处理后的船舶压载水采用中和处理手段以降低对海洋环境的负面影响。     

不同含水量液舱在弹体撞击下的动态响应特性

为了明确液舱在平头弹体侵彻下的变形毁伤特点,利用100%含水量液舱的高速侵彻实验,结合数值仿真方法,分析了平头弹作用下液舱含水量对舱壁动态响应的影响规律。结果表明：在相同含水量条件下,弹体初速度越高,弹体在水中的速度衰减越快,耗散的动能越多;同时弹体速度的衰减也随液舱含水量的增加而增大。弹体动能的耗散使得舱内形成空泡,且空泡尺寸随弹体速度的增加而增大。液舱壁由于空泡的作用产生了外凸变形,且其变形量随弹体速度及含水量的增加而增大;当液舱部分含水时,舱壁出现非对称变形,液面下的舱壁的最大变形量与满舱时近似相等。     

基于固有变形的船用钢薄板对接焊失稳变形的数值分析

在船用钢薄板的焊接过程中,不但会产生常见的焊接变形,也有可能产生焊接失稳变形。本文以焊缝的固有变形为依据,阐明船用钢薄板对接焊失稳变形产生的内在机理;同时,以固有变形为输入参数,通过弹性有限元分析的数值模拟,预测出可能产生的失稳变形模态和变形值;最终,通过四种不同的工艺方法(激光焊、瞬态热拉伸、随焊激冷和间断焊等),来减小固有变形的数值,并控制薄板对接焊接头可能产生的失稳变形。     

SmAl0.95M0.05O3-δ(M=Ni,Mg,Zn)钙钛矿氧化物的合成和电性能研究

为了提高SmAlO3体系的导电能力,采用低价的Ni2+,Mg2+,Zn2+分别对其B位离子进行了部分替代,在高温固相反应下合成了具有正交钙钛矿结构的混合导体SmAl0.95M0.05O3-δ(M=Ni,Mg,Zn),并利用XRD和直流四引线法对样品的结构以及电导率与温度和氧分压的关系进行了表征.电导率测量结果表明,掺杂显著提高了样品的电导率,比未掺杂的SmAlO3的电导率增加了3～4个数量级,在所有掺杂样品中,SmAl0.95Zn0.05O3-δ的电导率最高,800℃时为3.5×10-1 S/m,活化能最小为0.43 eV.从电导率随氧分压的变化关系分析可知,在高氧分压环境下,SmAl0.95Zn0.05O3-δ是一个氧离子和电子空穴的混合导体,但以离子导电为主,由于P型电导具有随温度下降而减弱的特征,故使其氧离子迁移数随温度下降而逐渐增大.     

浅谈500m^3／h铰吸式挖泥船总体设计

本概述了非自航、全液压、整体式的500m^3/h铰吸式挖泥船的总体设计思想。     

22 000m3液化气船整船和舱段三维有限元强度分析

对22 000m     

纳米Al2O3复合镀铁层的结构与性能

为提高船机零部件的耐磨性,减少零部件的磨损,通过在电镀液中添加Al2O3纳米颗粒的方法,制备出含有Al2O3纳米颗粒的复合镀铁层。对制备出的镀层进行硬度、表面形貌、元素成分和摩擦磨损性能分析。结果表明：Al2O3纳米颗粒成功进入了镀层,含有Al2O3颗粒的复合镀层相对普通镀铁层有明显提高；含有40g/L Al2O3的复合镀层的摩擦系数相对普通镀层下降了25%,磨损量也大幅下降；经过摩擦磨损后复合镀层的表面状态良好。     

Gas transfer velocities of CO2 and CH4 in a tropical reservoir and its river downstream

We have measured simultaneously the methane (CH₄) and carbon dioxide (CO₂) surface concentrations and water–air fluxes by floating chambers (FC) in the Petit-Saut Reservoir (French Guiana) and its tidal river (Sinnamary River) downstream of the dam, during the two field experiments in wet (May 2003) and dry season (December 2003). The eddy covariance (EC) technique was also used for CO₂ fluxes on the lake. The comparison of fluxes obtained by FC and EC showed little discrepancies mainly due to differences in measurements durations which resulted in different average wind speeds. When comparing the gas transfer velocity (k₆₀₀) for a given wind speed, both methods gave similar results. On the lake and excluding rainy events, we obtained an exponential relationship between k₆₀₀ and U₁₀, with a significant intercept at 1.7 cm h^− 1, probably due to thermal effects. Gas transfer velocity was also positively related to rainfall rates reaching 26.5 cm h⁻¹ for a rainfall rate of 36 mm h^− 1. During a 24-h experiment in dry season, rainfall accounted for as much as 25% of the k₆₀₀. In the river downstream of the dam, k₆₀₀ values were 3 to 4 times higher than on the lake, and followed a linear relationship with U₁₀.     

Seasonal study of dissolved CH4, CO2 and N2O in a shallow tidal system of the bay of Cádiz (SW Spain)

During 2004, 10 samplings were performed in order to measure dissolved methane (CH₄), carbon dioxide (CO₂) and nitrous oxide (N₂O) in the surface waters of Río San Pedro, a tidal creek in the salt marsh area of the Bay of Cádiz (SW Spain). The inner partvs of the creek is affected by the inputs coming from an intensive fish farm and the drainage of an extensive salt marsh area.Dissolved CH₄, CO₂ and N₂O concentrations ranged from 11 to 88 nM, 36 to 108 μM and 14 to 50 nM, respectively. Surface waters were in all cases oversaturated with respect to the atmosphere, reaching values of up to 5000% for CH₄, 1240% for CO₂ and 840% for N₂O. Dissolved CH₄, CO₂ and N₂O showed a significant tidal and seasonal variability. Over a tidal cycle, concentrations were always highest during low tide, which points to the influence of the inputs from the fish farm effluent and the drainage of the adjacent salt marsh area, as well as in situ production within the system. Dissolved CH₄, CO₂ and N₂O seasonal patterns were similar and showed maximum concentrations in summer conditions. Using four different parameterizations to calculate the gas transfer coefficients [Liss, P.S. and Merlivat, L., 1986. Air-sea exchange rates: introduction and synthesis. In P. Buat-Ménard (Ed.), The Role of Air-Sea Exchanges in Geochemical Cycling. Reidel, Dordrecht, The Netherlands, p. 113–127.; Clark, J.F., Schlosser, P., Simpson, H.J., Stute, M., Wanninkhof, R., and Ho, D.T., 1995. Relationship between gas transfer velocities and wind speeds in the tidal Hudson River determined by the dual tracer technique. In: B. Jähne and E. Monahan (Eds.), Air-Water Gas Transfer: AEON Verlag and Studio, Hanau, Germany, pp. 785–800.; Carini, S., Weston, N., Hopkinson, G., Tucker, J., Giblin, A. and Vallino, J., 1996. Gas exchanges rates in the Parker River estuary, Massachusetts. Biol. Bull., 191: 333–334.; Kremer, J.N., Reischauer, A. and D'Avanzo, C., 2003. Estuary-specific variation in the air-water gas exchange coefficient for oxygen. Estuaries, 26: 829–836.], the averaged air–water fluxes of CH₄, CO₂ and N₂O from the creek to the atmosphere ranged between 34 and 150 μmol CH₄ m^− 2 day^− 1, 73 and 177 mmol CO₂ m^− 2 day^− 1 and 24 and 62 μmol N₂O m⁻² day⁻¹, respectively.     

Determination of anthropogenic CO2 in the North Atlantic Ocean using water mass ages and CO2 equilibrium chemistry

A new method to calculate the anthropogenic CO₂ (ΔDIC_ant) within the water column of the North Atlantic Ocean is presented. The method exploits the equilibrium chemistry of the carbonate system with reference to temperature, salinity and the partial pressure of atmospheric CO₂ (pCO_2,atm). ΔDIC_ant is calculated with reference to the ventilation ages of water masses derived from tracer data and to the time history of pCO_2,atm. The method is applied to data recorded during the WOCE program on the WHP A1/E transect in the North Atlantic Ocean, where we characterise six key water masses by their relationships of dissolved inorganic carbon (DIC) and apparent oxygen utilisation (AOU). The error in determining ΔDIC_ant is reduced significantly by minimising the number of values referred to, especially by avoiding any use of remineralisation ratios of particulate organic matter. The distribution of ΔDIC_ant shows highest values of up to 45 μmol kg⁻¹ in the surface waters falling to 28–33 μmol kg⁻¹ in the Irminger Sea west of the Mid-Atlantic Ridge. The eastern basin is imprinted by older water masses revealing decreasing values down to 10 μmol kg⁻¹ ΔDIC_ant in the Antarctic Bottom Water. These findings indicate the penetration of the whole water column of the North Atlantic Ocean by anthropogenic CO₂.     

船舶尾管假轴制造及安装工艺研究

船舶艉轴管采用分体式结构型式时,用常规方法安装难以保证安装的精度。本文介绍一种新的安装工艺方法,通过采用其他材料代替尾轴和尾轴承进行全真模拟安装,可以显著提高安装的精度,且安装过程便捷、可靠、安全,具有较好的推广价值。     

Atmospheric CO2 measurements and error analysis on seasonal air–sea CO2 fluxes in the Bay of Biscay

Atmospheric molar fraction of CO₂ (xCO₂^atm) measurements obtained on board of ships of opportunity are used to parameterize the seasonal cycle of atmospheric xCO₂ (xCO₂^atm) in three regions of the eastern North Atlantic (Galician and French offshore and Bay of Biscay). Three selection criteria are established to eliminate spurious values and identify xCO₂^atm data representative of atmospheric background values. The filtered data set is fitted to seasonal curve, consisting of an annual trend plus a seasonal cycle. Although the fitted curves are consistent with the seasonal evolution of xCO₂^atm data series from land meteorological stations, only ship-board measurements can report the presence of winter xCO₂^atm minimum on Bay of Biscay. Weekly air–sea CO₂ flux differences (mmol C·m^− 2 day^− 1) produced by the several options of xCO₂^atm usually used (ship-board measurements, data from land meteorological stations and annually averaged values) were calculated in Bay of Biscay throughout 2003. Flux error using fitted seasonal curve relative to on board measurements was minimal, whereas land stations and annual means yielded random (− 0.2 ± 0.3 mmol C·m^− 2·day^− 1) and systematic (− 0.1 ± 0.4 mmol C·m^− 2 day^− 1), respectively. The effect of different available sources of sea level pressure, wind speed and transfer velocity were also evaluated. Wind speed and transfer velocity parameters are found as the most critical choice in the estimate of CO₂ fluxes reaching a flux uncertainty of 7 mmol C·m^− 2·day^− 1 during springtime. The atmospheric pressure shows a notable relative effect during summertime although its influence is quantitatively slight on annual scale (0.3 ± 0.2 mmol C·m^− 2·day^− 1). All results confirms the role of the Bay of Biscay as CO₂ sink for the 2003 with an annual mean CO₂ flux around − 5 ± 5 mmol C m^− 2 day^− 1.     

金纳米棒比色检测亚铁离子

实现亚铁离子的简单高效检测,在生化传感领域具有至关重要的作用。本文中,基于芬顿试剂(亚铁离子和过氧化氢的混合物)对金纳米棒的选择性氧化,实现了对亚铁离子的比色检测。伴随芬顿试剂的引入,金纳米棒溶胶颜色由红色逐渐演变为棕色、绿色、蓝色、紫色,乃至粉红色。基于此规律,实现了对亚铁离子的可视化检测。本文提出了一种相对Hg^(2+), Mg^(2+), Cu^(2+), Fe^(3+), Sn^(2+), Co^(2+), Cd^(2+), Cr^(3+), Zn^(2+), Ba^(2+), Ni^+等离子具有良好选择性的亚铁离子检测方法。     

pH variability and CO2 induced acidification in the North Sea

A coupled carbonate system–marine ecosystem–hydrodynamic model is used to simulate the temporal and spatial variability in pH across the southern North Sea as it relates to the environmental and biological processes affecting CO₂, namely, photosynthesis and respiration, riverine boundary conditions and atmospheric CO₂ concentrations. Annual pH ranges are found to vary from < 0.2 in areas of low biological activity to > 1.0 in areas influenced by riverine signals, consistent with observations and previous studies. It is shown that benthic, as well as pelagic, activity is an important factor in this variability. The acidification of the region due to increased fluxes of atmospheric CO₂ into the marine system is calculated and shown to exceed, on average, 0.1 pH units over the next 50 years and result in a total acidification of 0.5 pH units below pre-industrial levels at atmospheric CO₂ concentrations of 1000 ppm. The potential for measurable changes in biogeochemistry are demonstrated by simulating the observed inhibition of pelagic nitrification with decreasing pH. However, we conclude that there is a lack of knowledge of how acidification might affect the complex interaction of processes that govern marine biogeochemical cycles and a consequent need for further research and observations.     

37500方LEG运输船螺旋桨毂帽鳍设计研究

毂帽鳍是一种通过回收螺旋桨毂涡旋转能量来达到节能效果的船舶桨后节能装置。本文针对我公司承建的37500方LEG运输船,运用CFD软件对粘性流场中毂帽鳍的敞水性能进行了计算研究,着重考察了毂帽鳍的根部螺距角、错位角、直径比及纵向位置等因素对效率的影响,通过多方案优选设计了适用于该船的毂帽鳍方案,并对该方案进行了模型试验验证。结果表明：在螺旋桨工作点时,螺旋桨效率提高了1.26%。考虑到模型试验的尺度效应,在实船应用时其节能效果将更加显著。     

潜艇舱室固态胺CO2清除技术的动力学分析

分析了潜艇舱室固态胺CO2吸附及水蒸气再生的反应机理,指出了CO2水合反应和水合CO2分解反应分别为吸附与再生过程的慢反应.在实际工况下,固态胺吸附CO2的速率受传质控制,水蒸气再生过程很快,其速率不是主要关注的问题.基于双膜理论及双电层理论,分析讨论了固态胺吸附传质过程,推导出了CO2总的传质速率方程,给出了影响速率的2个可调因素--温度及固态胺的含水量.     

8m3抓斗挖泥船挖泥系统设计

介绍由国内新开发设计、结合引进国外先进技术和关键技术设备开发的大型抓斗挖泥船挖泥性能,涉及抓斗机的性能参数、抓斗机及抓斗的结构特点、传动装置型式、安全保护及报警装置、自动化作业监视装置等内容。     

350m^3／h分体绞吸式挖泥船的船型介绍

就350m^3/h绞吸式挖泥船设计中主尺度的确定,总布置,结构设计特点及主要设备的选取情况作了简要介绍。     

内河船舶和国内海船CO2系统的异同分析

针对船舶现场检验中发现的固定式灭火系统的CO₂系统以及瓶头阀及其相关组件的各种缺陷,主要阐述内河船舶CO₂系统和国内海船CO₂系统的异同、瓶头阀的结构、释放总管的安装要求、泄放总管的安装要求、控制管路的安装要求,这也是验船师现场检验的难点,以期相关人员在遇到问题时了解如何处理。     

Quasi-two-dimensional flow on the polar β-plane: Laboratory experiments

Geophysical turbulence is strongly affected by the variation of the Coriolis parameter with latitude. This variation results in the so-called β-effect, which forces energy from small-scales to be transferred preferentially into zonal motions. This effect results in the formation of narrow jet-like zonal flows that dominate the dynamics and act as transport barriers. Here, laboratory experiments are used to reproduce this effect in decaying turbulent flows. An electromagnetic cell is used to generate an initial field of vorticity in a rotating tank. Under conditions of quasi-geostrophic flow, the β-effect is produced by depth variation of the flow instead of variation of the Coriolis parameter. The effects of changing the container geometry and the overall fluid depth on the production of jets are investigated. The results suggest that this laboratory configuration can be used to model jet formation in the oceans and that increasing fluid depth is a practical way to decrease viscous effects.