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针对海洋工程装备产品的腐蚀评价需求及当前试验方法适用性差的弊端,提出一种适用于海洋工程装备异种材料电偶腐蚀兼容性评价方法,设计并制作一套海水环境下电偶腐蚀敏感性测试装置,在静态和动态2种全浸海水环境下对8种电偶对进行了电偶腐蚀兼容性评价试验。结果表明:相比实海挂片试验方法和薄液膜下电偶腐蚀试验,静态/动态海水全浸电偶腐蚀敏感性试验装置更适用于海洋工程装备异种材料电偶腐蚀兼容性的评价;由于偶对回路中阴阳极金属极化率的影响,电偶腐蚀电流密度与试验条件关联性远强于腐蚀电位差,电偶腐蚀电流密度更适宜作为海洋工程装备异种材料电偶腐蚀兼容性的评价判据。 相似文献
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舰船海水管路系统电偶腐蚀控制技术 总被引:1,自引:0,他引:1
进入新世纪以来,舰船海水管路系统材料逐步发展为以铜镍合金为主干材料,铸造青铜合金为配套材料的材料体系,同时钛及镍基合金的比例持续升高。这些高电位金属一方面大幅提升了海水管路的耐海水腐蚀性能,尤其是耐冲刷腐蚀性能,另一方面也提高了钛、镍基合金管路与低电位的铜合金管路及附件连接时的电偶腐蚀风险。为应对钛及镍基合金应用带来的上述风险,美国等国外海军通过长期试验研究,对于舰船海水管路系统电偶腐蚀控制系列技术进行了充分评估和考核验证。本文论述国外海军舰船海水管路系统电偶腐蚀控制技术研究的重点方向以及相关考核试验结论,为我国同领域的技术发展提供参考借鉴。 相似文献
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介绍了电解水制氢装置核心部件电解槽的主极板发生腐蚀的现象,研究并分析了极板腐蚀发生的原因,笔者认为主极板腐蚀的机理属于电偶腐蚀 孔蚀,碱液中有害离子是导致腐蚀发生的必要条件。针对主极板腐蚀发生的情况,提出了解决措施。 相似文献
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一船舶电化学腐蚀的种类金属表面与离子导电的电解质溶液发生电化学作用产生的破坏,称为电化学腐蚀。船上的电化学腐蚀一般为局部腐蚀,常见的腐蚀主要有以下几种:(1)电偶腐蚀船上零件只要能构成异金属接触电池,就会发生电偶腐蚀。这种腐蚀较为普遍,例如离心泵的叶轮与泵轴,冷凝器的碳钢壳体与黄铜管子等构成的腐蚀,即为电偶腐蚀。(2)氧浓差腐蚀金属零件与含氧量不同的溶液接触,就会形成氧浓差电池。溶液含氧浓度越高,电极的电位就越高,成为阴极,与含氧浓度低的溶液接触的电极成为阳极,阳极被腐蚀。例如柴油机气缸套与气缸体下部密封圈处的缝… 相似文献
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船舶海水管系管材腐蚀及防腐技术探讨 总被引:8,自引:0,他引:8
文章主要探讨了船舶海水管系腐蚀的机理和原因,并对一些常用管材的抗腐蚀性能及应用场合作了介绍,对船舶海水管系设计中使用的防腐蚀措施作了较系统的介绍. 相似文献
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《船舶与海洋工程学报》2017,(2)
HE15 is a heat treatable high strength alloy with excellent machinability find wide applications in aerospace and defence industries. In view of their excellent mechanical properties, workability, machinability, heat treatment characteristics and good resistance to general and stress corrosion cracking, MDN138 MDN250 have been widely used in petrochemical, nuclear and aerospace industries. The galvanic corrosion behaviour of the metal combinations HE15/MDN138 and HE15/MDN250, with 1:1 area ratio, has been studied in natural seawater using the open well facility of CECRI's Offshore Platform at Tuticorin for a year. The open circuit potentials of MDN138, MDN250 and HE15 of the individual metal, the galvanic potential and galvanic current of the couples HE15/MDN138 and HE15/MDN250 were periodically monitored throughout the study period. The calcareous deposits on MDN138 and MDN250 in galvanic contact with HE15 were analyzed using XRD. The electrochemical behaviors of MDN138, MDN250 and HE15 in seawater have been studied using an electrochemical work station. The surface characteristics of MDN138 and MDN250 in galvanic contact with HE15 have been examined with scanning electron microscope. The results of the study reveal that HE15 offered required amount of protection to MDN138 MDN250. 相似文献
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HE15 is a heat treatable high strength alloy with excellent machinability find wide applications in aerospace and defence industries. In view of their excellent mechanical properties, workability, machinability, heat treatment characteristics and good resistance to general and stress corrosion cracking, MDN138 & MDN250 have been widely used in petrochemical, nuclear and aerospace industries. The galvanic corrosion behaviour of the metal combinations HE15 /MDN138 and HE15 /MDN250, with 1:1 area ratio, has been studied in natural seawater using the open well facility of CECRI’s Offshore Platform at Tuticorin for a year. The open circuit potentials of MDN138, MDN250 and HE15 of the individual metal, the galvanic potential and galvanic current of the couples HE15 /MDN138 and HE15 /MDN250 were periodically monitored throughout the study period. The calcareous deposits on MDN138 and MDN250 in galvanic contact with HE15 were analyzed using XRD. The electrochemical behaviors of MDN138, MDN250 and HE15 in seawater have been studied using an electrochemical work station. The surface characteristics of MDN138 and MDN250 in galvanic contact with HE15 have been examined with scanning electron microscope. The results of the study reveal that HE15 offered required amount of protection to MDN138 & MDN250. 相似文献
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The galvanic corrosion behavior of the metal combinations 15 CDV6/MDN138 and 15 CDV6/MDN250, with 1:1 area ratio, has been studied in natural seawater using the open well facility of CECRI's Offshore Platform at Tuticorin for a year. The open circuit potentials of MDN138, MDN250, and 15 CDV6 of the individual metal, the galvanic potential and galvanic current of the couples 15 CDV6/MDN138 and 15 CDV6/MDN250, were periodically monitored throughout the study period. The calcareous deposits on MDN138 and MDN250 in galvanic contact with 15 CDV6 were analyzed using XRD. The electrochemical behavior of MDN138, MDN250, and 15 CDV6 in seawater was studied using an electrochemical work station. The surface characteristics of MDN138 and MDN250 in galvanic contact with 15 CDV6 have been examined with a scanning electron microscope. The results of the study reveal that the galvanic protection offered by15 CDV6 to MDN250 and MDN138 in natural seawater amounts to 93% and 98%, respectively, implying that the galvanic protection offered by 15 CDV6 is continuous and effective, which has been further evinced from the adherent nature of the calcareous deposit film comprising compounds such as CaCO_3(calcite, aragonite, and vaterite), MgCO_3(magnesite),Mg(OH)_2(brucite), and MgO(brucite). 相似文献
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全钛冷凝器主循环水系统的电偶腐蚀及其防护 总被引:1,自引:0,他引:1
现代舰船主循环水系统多采用全钛冷凝器,但采用全钛冷凝器对冷却系统中其它结构材料将产生电偶腐蚀作用,本文通过电偶腐蚀试验和系统腐蚀试验,查明了这种影响,并提出了防止钛合金对其它电位较负荷材料产生电腐蚀作用的措施。 相似文献