Trace element levels in some commercially valuable fish species from coastal waters of Mediterranean Sea, Egypt

Concentrations of 5 trace elements (Cd, Pb, Cu, Cr, Zn) were determined in muscle of fishes collected from two coastal areas of the Egyptian coast of the Mediterranean Sea west of Alexandria (El-Mex Bay and Eastern Harbour). Sardinella aurita, Alepes djedaba, Siganus luridus, Siganus rivulatus, Sphyraena chrysotoenia, and Scomberomorus commerson were collected from El-Mex Bay. While Boops boops, Lithognathus mormyrus, Sparisoma cretense, Serranus cabrilla and Synodus saurus were collected from the E.H. In all fishes zinc was highest (up to 57 mg/kg) followed by Cr, Cu, Pb and Cd. The concentrations of several metals in fishes were significantly different among the species in each area. For all trace element examined, the concentrations decreased significantly with body weight of some fishes. In contrast, a positive correlation with body weight was found especially for Zn and Cu concentrations in 5 fish species and for Pb in 4 fish species. The concentrations of Cd, Pb and Zn were higher in fishes from El-Mex Bay (3.76, 6.49 and 57.21 mg/kg) than those from Eastern Harbour, whereas the opposite trend was observed for Cu and Cr, revealing the direct sources of trace metal pollution present in El-Mex coastal area. Levels of Cr surpassed the Maximum Permissible Concentration in most fish tissues, followed by Pb and Cd in some species. Cu and Zn presented concentrations below the maximum permissible levels in fish tissues.     

Statistical comparison of trace metal concentrations in wild mussels (Mytilus galloprovincialis) in selected sites of Galicia and Gulf of Biscay (Spain)

Concentrations of five trace metals (Cd, Hg, Pb, Cu and Zn) in wild mussels (Mytilus galloprovincialis) from the Galician and Gulf of Biscay areas in Spain were monitored from 2000 to 2004. A pool of mussel soft tissue was prepared using 50 or more individuals representing the available size range (35–60 mm) present at the sampling points (A Coruña, Pontevedra and Vigo–Galicia, NW of Spain—and Avilés, Bilbao and Santander–Gulf of Biscay). Metals were analysed by atomic absorption spectrometry, AAS, (flame–AAS: Cu and Zn; graphite furnace–AAS: Cd and Pb; flow injection-cold vapour–AAS: total Hg). Quality of the chemical analyses was assessed by participation in periodic QUASIMEME intercalibration exercises carried out from 2000 to 2004, while the present study was developed . Univariate statistical studies, Anova (Analysis of the Variance) and Principal Component Analysis (autoscaled data, Varimax rotation) were carried out. Differences between the two areas as well as certain temporal trends were found and, in general, the Gulf of Biscay samples showed higher metallic contents, mainly close to Avilés, where iron and steel factories thrown residues for years into a nearby coastal area.     

Trace metals in water, sediments and marine organisms from the northern part of the Gulf of Suez, Red Sea

Concentrations of Cd, Pb, Cu and Zn were determined in water, sediments, gastropod (Bulla umpulla) and green algae (Ulva lactuca) collected from five stations in the western side of the northern part of the Gulf of Suez during the period February 1993–January 1994. Sediments recorded the highest concentrations of Cd (2.26–4.40 μg/g) and Pb (13.90–28.34 μg/g), While the highest concentrations of the essential metals Cu and Zn were found in B. umpulla (28.19–72.04 and 60.24–108.74 μg/g, respectively). Water and sediments showed similar spatial distribution patterns for the highest mean values of the different metals. Highest values of the studied metals were found at stations influenced by various pollution sources such as harbours, and sewage and industrial drains. In contrast, the lowest concentrations were observed faraway from any pollution source. Calculations of concentration factors (C.F.) for gastropod and algae showed highest C.F. of Cd (4312.5–8705.9) and Pb (2103.3–8317.9) in algae, and highest C.F. of Cu (5288.9–42376.5) and Zn (3686.7–9631.5) in gastropod.     

A numerical transport model for predicting the distributions of Cd, Cu, Ni, Pb and Zn in the southern North Sea: the sensitivity of model results to the uncertainties in the magnitudes of metal inputs

A new transport model for metals (named NOSTRADAMUS) has been developed to predict concentrations and distributions of Cd, Cu, Ni, Pb and Zn in the southern North Sea. NOSTRADAMUS is comprised of components for water, inorganic and organic suspended particulate matter transport; a primary production module contributes to the latter component. Metal exchange between dissolved (water) and total suspended particulate matter (inorganic + organic) phases is driven by distribution coefficients. Transport is based on an existent 2-D vertically integrated model, incorporating a 35 × 35 km grid. NOSTRADAMUS is largely driven by data obtained during the Natural Environment Research Council North Sea Project (NERC NSP). The sensitivity of model predictions to uncertainties in the magnitudes of metal inputs has been tested. Results are reported for a winter period (January 1989) when plankton production was low. Simulated ranges in concentrations in regions influenced by the largest inflows, i.e. the NE English coast and the Southern Bight, are similar to the ranges in the errors of the concentrations estimated at the northern and southern open sea boundaries of the model. Inclusion of uncertainties with respect to atmospheric (up to ± 54%) and riverine (± 30%) inputs makes little difference to the calculated concentrations of both dissolved and particulate fractions within the southern North Sea. When all the errors associated with the inputs are included there is good agreement between computed and observed concentrations, and that for dissolved and particulate Cd, Cu and Zn, and dissolved Ni and Pb, many of the observations fall within, or are close to, the range of values generated by the model. For particulate Pb, model simulations predict concentrations of the right order, but do not reproduce the large scatter in actual concentrations, with simulated concentrations showing a bias towards lower values compared to those observed. A factor which could have contributed to observed concentrations, and which is not included in the model, is considered to be a substantial benthic input of dissolved lead during this winter period, coupled to a rapid and extensive scavenging of the dissolved lead to particles. Significant reductions in riverine and aeolian inputs of total Cd and Cu of 70% and 50%, respectively, consistent with aims of North Sea Conferences, are predicted to lead to minor decreases (~ 10%) in water column concentrations of dissolved and particulate Cd and Cu, except near river sources, where maximum reductions of ~ 30–40% may occur.     

Marine molluscs as biomonitors for heavy metal levels in the Gulf of Suez, Red Sea

Levels of the heavy metals Copper (Cu), Zinc (Zn), Lead (Pb), Cadmium (Cd), Chromium (Cr), Nickel (Ni), Iron (Fe) and Manganese (Mn) were determined in coastal water, sediments and soft tissues of the gastropod limpet, Patella caerulea, and the bivalve, Barbatus barbatus, from seven different stations in the western coast of the Gulf of Suez. The concentrations of heavy metals in water ranged between 3.37–4.78, 18.83–21.46, 2.75–3.17, 0.22–0.27, 0.99–1.21, 2.69–3.65, 3.75–4.56 μg L^− 1 and 23.82–32.78 mg g^− 1 for Cu, Zn, Pb, Cd, Cr, Ni, Mn and Fe, respectively. The corresponding concentration values in the sediments were 8.65–12.16, 51.78–58.06, 36.52–42.15, 3.23–3.98, 9.03–12.75, 34.31–49.63, 3.28–4.56 and 64.20–70.22 μg g^− 1 for Cu, Zn, Pb, Cd, Cr, Ni, Mn and Fe, respectively. The highest accumulated metals were Fe, Zn and Mn in both P. caerulea and B. barbatus, while the lowest one was Cd. The accumulation of metals was more pronounced in P. caerulea than B. barbatus. The highest concentrations of all metals in water, sediments and mollusca were recorded at Adabiya harbour north of the Gulf, while the lowest concentrations were recorded at Gabal El-Zeit and Hurghada. Land based activities and ships awaiting berth are the main source of metal pollution in the northern part of the Gulf.     

舟山港海域海洋生物体内主要污染物分析

在舟山港海域共设5个站位,于2005年5～6月对该海域生物体内石油烃、铜、锌、铅、镉、总汞、砷的残留量进行了监测,其中1#、4#、5#站位只进行了重金属监测。监测结果显示:所有检测指标均符合《海洋生物质量》二类评价标准,调查海域生物体质量整体良好;污染物在生物体内的含量表现出较大种间差异,除汞外,其他污染物质在运动性不强的贝类中的含量均要高于鱼类,其中石油烃为18.20mg/kg,铜11.97mg/kg,锌19.14mg/kg,铅0.46mg/kg,镉0.13mg/kg,砷1.58mg/kg。     

Intra-annual variability of distribution patterns and fluxes of dissolved trace metals in a subtropical estuary (Danshuei River,Taiwan)

Water samples were collected along salinity gradients and dissolved trace metal (Cd, Cu, Ni, Pb, and Zn) concentrations were determined in a macro-tidal, mountainous estuary (Danshuei River Estuary) in northern Taiwan. Bi-monthly surveys were conducted between March 2001 and June 2002, during both wet and dry seasons. This study investigated intra-annual variability, fluxes, and the extent of addition or removal of dissolved trace metals in the estuary, which is characterized by the fluctuation of redox interface according to river flow conditions. In sub-oxic and anoxic waters, the presence of reduced sulfur species led to the formation of metal-sulfide minerals that sequester metals out of the water column. Therefore, trace metal fluxes and removal/addition rates are seasonally variable, largely by the extent of estuarine hypoxia. In the 9 sampling expeditions over the 16-month period, fluxes of dissolved trace metals out of the Danshuei River Estuary were estimated as follows: Cd, ? 0.33–4.46 mol/day; Cu, ? 48–1112 mol/day; Ni, 1836–6586 mol/day; Pb, 2.47–11.59 mol/day; and Zn, 361–2656 mol/day. For elements such as Cd and Cu, the removal in the Danshuei River Estuary during dry seasons was so dramatic that there were net fluxes from the coast to the estuary (negative fluxes). Ni behaved near conservatively in this estuary, thus its river endmember concentrations directly determined Ni fluxes out of the estuary. Removal of Pb was effectively enhanced by the presence of higher suspended particulate matter concentrations in the upper estuary and the formation of Fe- and Mn-oxides and oxyhydroxides that precipitate out of the water column in mid-estuary, which generally leaves low effective river endmember Pb concentrations, thus low fluxes out of the estuary.     

Synoptic transects on the distribution of trace elements (Hg,Pb, Cd,Cu, Ni,Zn, Co,Mn, Fe,and Al) in surface waters of the Northern- and Southern East Atlantic

Surface seawater samples were taken in the framework of the GEOTRACES program on “POLARSTERN” expedition ANT XXIII/1 in the Eastern Atlantic in 2005 to study the distribution of the trace elements Hg (mercury), Pb (lead), Cd (cadmium), Cu (copper), Ni (nickel), Zn (zinc), Co (cobalt), Mn (manganese), Fe (iron), and Al (aluminium). With the exception of Hg, results were compared to earlier datasets from 1989 to 1990. The particulate fraction averaged over the transect was calculated to be 49% for Cd, 23% for Mn and 50% for Fe indicating a release of these TEI's (trace elements and their isotopes) from a leachable SPM fraction in the stored and acidified samples.Total Pb concentrations ranged between 5 and 20 pmol kg^? 1 in 2005 with highest values in the ITCZ (intertropical convergence zone). In 1989 Pb concentrations were twice as high in the region of the ITCZ, while by a factor of 10–15 higher values were obtained in the North Atlantic.Total Cd and Co are dominated, by different seasonal upwelling regimes (Equatorial upwelling, Guinea Dome, Angola Dome).Total Cu, Ni, Fe, Mn and Al show nearly identical concentrations in 1990 and 2005. For total manganese and aluminium strong maxima (3–4 nmol kg^? 1 and 55 nmol kg^? 1 respectively) are observed between 23°N and 0°, while the Fe maximum (6–9 nmol kg^? 1) is located at 7°N. Total Hg concentrations ranged between 0.5 and 4.5 pmol kg^? 1.     

Strong bottom–up effects on phytoplankton community caused by a rainfall during spring and summer in Sagami Bay,Japan

To assess the consequences of bottom-up effects on phytoplankton community composition during the rainy season, phytoplankton levels and environmental factors were monitored daily from 12 April to 22 July 2003 in Sagami Bay, Japan. The relevant environmental factors were analyzed using cross-correlation analyses. Based on time-series analysis, low surface salinity conditions lasting 0 or 2 days after heavy rainfalls resulted in significant nutrient loading, such as dissolved inorganic nitrogen (DIN), into the coastal area. Also, Chlorophyll-a (Chl-a) concentration frequently increased 2 and 6 days after rainfall. Based on the high total Chl-a concentration, the time was divided into three periods, from 1 to 11 May (Period A), 26 May to 9 June (Period B) and 30 June to 22 July (Period C). The phytoplankton assemblages during Period A were dominated by two dinoflagellates, Ceratium furca and Ceratium fusus. Prior to these species blooming, the heterotrophic dinoflagellate Noctiluca scintillans was dominant. During Period B, the phytoplankton communities were dominated primarily by the diatoms Rhizosolenia delicatula, Hemiaulus sinensis and Navicula spp. Finally, Cerataulina dentata, Rhizosolenia spp., Lauderia borealis and Neodelphineis pelagica were dominant during Period C. After increases in phytoplankton abundance, available nitrogen (N) and phosphorous (P) were consumed and exhausted, which were considered a potential cause of the shift in the dominant organisms from large diatoms to pico- and nano-plankton in the low Chl-a environment. In particular, silicate (Si) was not a major limiting factor for phytoplankton production, since the Si:DIN and Si:P ratios clearly demonstrated that there were no any potential stoichiometric Si limitations, and almost all silicate concentrations were > 2.0 µM during this study. Our results reveal that nutrient sources supplied by river discharge are a main cue for strong bottom–up effects on algal bloom succession during the early summer season in Sagami Bay.     

Sediment geochemistry and mineralogy in Milos bay, SW Kyklades, Aegean Sea, Greece

This work aims at studying the geochemistry and mineralogy of Milos bay surface sediments. The bay forms an enclosed marine area, supplied totally by volcanic formations. Totally 16 samples were subjected to sedimentological (grain size), mineralogical (microscope examination and X-ray diffraction of the bulk sample and the pelitic fraction), and geochemical analyses (X-ray fluorescence in the pelitic fraction). Also the carbonate content was determined. Sediments were sandy with a high carbonate content (14–58%). The dominant minerals recognized in the pelitic fraction were smectite, kaolinite and illite, followed by chlorite, quartz, calcite, Mg-calcite and feldspars. In general, element concentrations appeared to be within the normal range, except Pb and Zn, which exhibited relatively high values. The Index of Geoaccumulation I_geo was computed, in order to investigate a possible enrichment of the surface sediments in metals. The analysis revealed again high values of I_geo class for both Pb and Zn. A careful study of the area, in relation to the quality of the catchment basins petrology, lead to a non-anthropogenic origin of these high concentrations. The enrichment of the surface sediments in Pb and Zn is attributed to the weathering of several mineral deposits, pyroclastic rocks and lavas, covering almost all Milos vicinity. A study of the geochemical data correlation coefficient matrix revealed three major groups of elements: (i) the elements of detrital origin represented by Si, Al, K and a part of the metals; (ii) the carbonates group; and (iii) a Fe–Mn oxyhydroxides–oxides group, which attracts a part of Pb, Cr and Ni.     

Monitoring trace elements (Al, As, Cr, Cu, Fe, Mn, Ni and Zn) in deep and surface waters of the estuary of the Nerbioi-Ibaizabal River (Bay of Biscay, Basque Country)

Deep water samples (in contact with the sediment) were collected at eight different points of the estuary of the Nerbioi-Ibaizabal River (Bay of Biscay, Basque Country), both at low and high tides, during four sampling campaigns (May, September and December 2005 and March 2006). Superficial water was also sampled in March 2006. Temperature, pH, redox potential, dissolved oxygen and electrical conductivity corresponding to each sample were measured in situ at each sampling point using a multiparametric probe. The physico-chemical parameters found are typical of highly stratified estuaries, with an acceptable oxygenation level. After filtering and acidifying the samples, they were analysed by inductively coupled plasma/mass spectrometry (ICP/MS) to simultaneously determine the total concentration of Al, As, Cr, Cu, Fe, Mn, Ni and Zn. Concentrations in the μg kg^− 1 level were found in all cases (c_Cr and c_Ni, 1–10; c_Al, c_As and c_Zn, 10–50; c_Cu and c_Mn, 10–100 and c_Fe, 100–400 μg kg^− 1). A probable net input of Al, Cr, Mn and Zn via the main (Nerbioi-Ibaizabal) and some of the tributary rivers (Galindo, Asua and Gobela) was identified. Evidence of a common source of Al and Zn to the estuary was found. Correlation analysis of data revealed connections between variables (concentration of Cu, Fe and As with salinity, as well as c_Al with c_Zn, c_Cu with c_Fe, c_As with c_Fe, and c_As with c_Cu). Principal Component Analysis (PCA) of data allowed the samples to be grouped according to sampling campaign, with two principal components accounting for 62% of the total variance. In addition, plots of element concentration against salinity suggested a conservative behaviour for As, Cu and Fe and a non-conservative one for Cr. Not clear mixing behaviour was observed for the rest of elements.     

A trace metal (Pb, Cd, Zn, Cu) balance for surface waters in the eastern Gotland Basin, Baltic Sea

Trace metal inventories and transboundary fluxes were estimated for the surface waters of the eastern Gotland Basin, and a mass balance for this water body was derived.The study area was delineated by a box which bordered vertically by the sea surface and the halocline and horizontally by the coast of Gotland and the coast of Latvia/Lithuania. For the calculation of the trace metal inventories in the box, a high-resolution sampling was carried out during different seasons. Additional sediment trap studies were performed to calculate the vertical particulate trace metal fluxes through the halocline.The following transboundary fluxes have been estimated: (a) atmospheric input of trace metals; (b) lateral transport from adjacent bodies of surface water; (c) diapycnal fluxes of dissolved trace metals at the halocline; (d) sinking of trace metals, associated with particles, through the halocline, (e) vertical advection through the halocline.The lateral transport into and out of the surface box is important for the metals (Cd, Cu, Zn) with “nutrient-like” behaviour. For particle reactive elements like lead, vertical sedimentation and lateral transport out of the box as much as atmospheric input and lateral input into the box are in the same order of magnitude. Turbulent diapycnal mixing plays a minor role compared to the advective fluxes.The estimated range for the residence times for the region under investigation are  0.5–1.3 years for Pb;  2–11 years for Zn,  7–36 years for Cd and 42–89 years for Cu. This demonstrates that the system reacts very fast for particle reactive elements like Pb, while for copper sedimentation processes are not the preferential sink and can be neglected.     

Time series for dissolved cadmium at a coastal station in the Western Baltic Sea

Concentrations of dissolved Cd, Cd(diss), were measured weekly from June 1991 to June 1994 at a coastal station in the western Baltic Sea. The mean concentration of 204 pmol/dm³ is about 50% higher than in open Baltic Sea surface waters. A distinct seasonal cycle was observed with elevated concentrations in winter and spring (272 pmol/dm³) and lower values in summer and autumn (131 pmol/dm³). Relating the seasonal changes in Cd(diss) to the nutrient cycle revealed ΔCd(diss)/ΔNO₃ and ΔCd(diss)/ΔPO₄ ratios which are consistent with other measurements and seem to confirm the concept of a nutrient-like biogeochemistry of Cd. However, a time shift of two to three months exists between the depletion of nutrients in spring and the depletion of Cd(diss). Possibly, this indicates a decoupling of Cd(diss) from nutrients during the spring plankton bloom. However, no final conclusions can be drawn yet.Cd(diss) concentrations decreased significantly during the three year measurement period, whereas nitrate concentrations increased. A possible linkage between eutrophication and the Cd budget of the Baltic Sea is discussed.     

The nitrogen cycle in tidal flats and eelgrass beds of Ise Bay

A tidal flat-sea grass bed ecosystem model was formulated and applied to Ise Bay to evaluate the purification capability of the shallow-water region where a new airport is expected to be built. The model results were in the range of the observed biomass for each state variable in the model. The purification capability of this shallow-water region is estimated from the model results. The inorganic nitrogen removal is estimated at 56 kg N day⁻¹; the organic particulate nitrogen removal by suspension feeders is 95 kg N day⁻¹; the organic nitrogen removal by harvest and fish predation is 25 kg N day⁻¹, and the purification capability of this site is 51 kg N day⁻¹. Potential loss of the sea grass bed by reclamation will reduce the removal ability of inorganic nitrogen as well as food sources for juvenile fishes.     

Mass balance of trace metals in the Adriatic Sea

A first order mass balance of six different trace metals (Mn, Fe, Pb, Zn, Cu, Ni) was presented for a 1-year period for the different compartments of the Adriatic Sea: compartment 1 (northern Adriatic Sea), compartment 2 (central Adriatic Sea and surface layer of the southern Adriatic Sea) and compartment 3 (deep water of the southern Adriatic Sea). The Adriatic Sea appeared to be a source of dissolved Cu, Mn and Fe for the Mediterranean Sea through the Strait of Otranto whereas for dissolved Zn and Pb the Adriatic Sea appeared to be a net sink. For dissolved Ni, inputs and outputs through the Strait of Otranto balanced each other. The residence times of all metals in compartment 1 were significantly shorter than that of water indicating significant removal. In compartments 2 and 3, residence times of Mn and Fe were relatively short suggesting removal from the water column whereas for the other metals their residence times were similar to that of water. Calculations of turnover times of metals with respect to different processes showed that in compartments 1 and 2, sedimentation was the main process that affected the content of the reservoirs whereas in compartment 3, the water flux exchanges played an important role for Zn, Cu and Ni.Most of the metals clearly undergo a very dynamic cycle of sedimentation/remobilization particularly in the Northern Adriatic Sea. In the northern Adriatic Sea, most of the Mn and Fe in deposited sediment were remobilized. This was related to diagenetic processes involving the utilisation and solubilisation of Mn and Fe oxides, which occur in the surface of the sediment in the northern Adriatic Sea. In the central Adriatic Sea, remobilization of Mn and Fe was less than in the northern Adriatic Sea, suggesting that diagenesis processes appear deeper in the sediment. Advective transport of sediment was a major source of metals for the deep basin. As much as 80% of the sediments in the South Adriatic Pit might be advected from the shelf. Remobilization fluxes in the South Adriatic Pit were significantly less than in the Northern and Central Adriatic Sea reflecting hemi-pelagic sediments.     

多台船舶柴油机润滑油油料发射光谱数据比较

为监测同型号柴油机的磨损工况和分析不同润滑油的使用性能,对16台同一型号的船舶柴油机的润滑油定期取样,利用超谱M型油料发射光谱仪分析油样中的铁、铜、铝、铅等磨损金属元素质量浓度和添加剂元素的平均值和标准偏差,利用主成分分析,根据添加剂元素对润滑油进行分类,对磨损元素的显著性水平进行检验,得到铁和铜元素质量浓度在两种不同的润滑油工作中的差异。     

Phytoplankton dynamics related to water mass properties in the Gulf of Gabes: Ecological implications

The spatial distribution of chlorophylls and carotenoids was recorded throughout the Gulf of Gabes (South Ionian Sea) in March 2007, and was related to patterns of the physical structure and the nutrient concentrations.Two distinct water masses were identified based on the temperature and salinity (T–S) analysis: a cool and less salty Modified Atlantic Water (MAW) and a saltier Mediterranean Mixed Water (MMW). There was no significant difference in the mean nitrogen and phosphate concentrations between MMW and MAW, although the silica values were significantly higher in MAW. The Integrated chlorophyll a mean value was about 4 mg m^? 2, with a maximum of 13 mg m^? 2 at MAW stations.Higher Chlorophyll a records in typical MAW stations were mainly due to chlorophytes, which contributed up to 58% of the pigments concentrations in the MAW and about 46% in the MMW. The contribution of chlorophytes to total Chlorophyll a was found to be relatively stable throughout the water column. The contribution of diatoms, which were twofold higher in the MMW than in the MAW, did not exceed 17% of chlorophyll a and was mainly due to subsurface maxima. The chlorophytes, pelagophytes, prymnesiophytes and cryptophytes all together accounted for more than 77% of total chlorophyll a in the MAW and about 67% in the MMW.There were statistically significant differences between MMW and MAW in the pigment contribution of cyanobacteria and pelagophytes. These two taxa accounted for 13% and 24% of chlorophyll a respectively in the MAW and MMW indicating that these differences concerned phytoplankton classes at relatively low contributions to total chlorophyll a.     

10 Towards a Safer Environment：（7）How apatite minerals remediate Pb,Zn and Mn from wastewater？

To evaluate the effectiveness of apatite mineral in removing different contaminants from low quality water in the industrial city of abha,Asir region,southwestern of Saudi Arabia two phosphatic clay dominated by apatite mineral were selected.In situ remediation experiment proved that apatite mineral has the highest affinity for Pb and removed more than 94% from initial Pb concentration.The rest of contaminants followed the descending order of:Zn>Mn>Cu>Co>Ni.The sorption of Pb,Zn and Mn onto apatite mineral was well characterized by the Langmuir model.Ternary-metal addition induced competitive sorption among the three metals,with the interfering effect of Pb>Zn>Mn.During metal retention by apatite mineral calcium and phosphate were determined in equilibrium solution.Calcium increased and phosphate decreased with increasing metal disappearance.The greatest increase of calcium and the largest phosphate reduction were found with Pb+2 sorption. This is suggested that Pb+2 retention by apatite was through the dissolution of apatite which mean release of Ca and P into solution and formation of pyromorphite(lead phosphate)as consuming of P.Obtained results suggested that there are two general mechanisms for the ability of apatite mineral to take up Pb2+,Zn+2 and Mn+2.The first is (ion-ion exchange mechanism)concerned with adsorption of ions on the solid surface followed by their diffusion into apatite mineral and the release of cations originally contained within apatite.The second is (dissolution- precipitation mechanism)concerned to the dissolution of apatite in the aqueous solution containing Pb2+,Zn+2 and Mn+2 followed by the precipitation or coprecipitation.Pb+2 desorption responding to solution pH may indicate that not all the Pb+2 was chemisorbed and fraction of Pb+2 was weakly adsorbed or complexed on the surface of apatite mineral.     

天津典型湿地地表水环境质量分析与评价

采用单因子污染指数法,以天津典型湿地即七里海、北大港、团泊洼和大黄堡湿地为研究对象,根据枯水期和丰水期的监测结果,对其水环境质量进行分析与评价,结果表明:4个湿地水质的pH、As、Cd、Pb浓度较低,均能达到《地表水环境质量标准》I类标准要求;除团泊洼外,其他湿地水体的铬浓度均能达到《地表水环境质量标准》II类标准;而COD、总氮、总磷和汞浓度含量较高,远高于《地表水环境质量标准》V类标准;湿地外围河流如七里海湿地的潮白新河,团泊洼湿地的独流咸河与大邱庄排污河,北大港窑地桥污水河等多为排污河,水质很差,这些外围河流对湿地的水环境质量影响较大。     

ICP-AES法分析六氟化钨中的金属粒子

提出了用电感耦合等离子体原子发射光谱(ICP-AES)法测定高纯六氟化钨中铬、锰、铁、钴、镍、铜、锌、镁、钙、钠、钾、铅及钼等金属元素的含量。六氟化钨极易与空气中的水分发生反应,为此设计了一套与空气隔离的密闭取样系统。在装有待测金属元素的取样器内,先后加入氨水、硝酸、氢氟酸使其溶解并定容,作为ICP-AES分析的待测溶液。在优化的实验条件下,得出各元素的检出限小于0.005mgL-1,方法的回收率在90.5%~104.2%之间,测定值的相对标准偏差(n=11)在3.2%~7.8%之间。最终试验分析结果表明,样品满足高纯六氟化钨技术指标的要求。