Isocyanic acid and ammonia in vehicle emissions

Vehicles are considered to be an important source of ammonia (NH₃) and isocyanic acid (HNCO). HNCO and NH₃ have been shown to be toxic compounds. Moreover, NH₃ is also a precursor in the formation of atmospheric secondary aerosols. For that reason, real-time vehicular emissions from a series of Euro 5 and Euro 6 light-duty vehicles, including spark ignition (gasoline and flex-fuel), compression ignition (diesel) and a plug-in electric hybrid, were investigated at 23 and −7 °C over the new World harmonized Light-duty vehicle Test Cycle (WLTC) in the Vehicle Emission Laboratory at the European Commission Joint Research Centre Ispra, Italy. The median HNCO emissions obtained for the studied fleet over the WLTC were 1.4 mg km⁻¹ at 23 °C and 6 mg km⁻¹ at −7 °C. The fleet median NH₃ emission factors were 10 mg km⁻¹ and 21 mg km⁻¹ at 23 and −7 °C, respectively. The obtained results show that even though three-way catalyst (TWC), selective catalytic reduction (SCR), and NOx storage catalyst (NSC) are effective systems to reduce NOx vehicular emissions, they also lead to considerable emissions of the byproducts NH₃ and/or HNCO. It is also shown that diesel light-duty vehicles equipped with SCR can present NH₃ emission factors as high as gasoline light-duty vehicles at both, 23 and −7 °C over the WLTC. Therefore, with the introduction in the market of this DeNOx technology, vehicular NH₃ emissions will increase further.     

Big data driven dynamic driving cycle development for busses in urban public transportation

Field-relevant reference driving cycles, equivalent to real-life operation, are a prerequisite for the consistent development and testing of vehicles, their components, and control algorithms. Furthermore they are the basis for certification and type testing. However, a static cycle can easily be detected during vehicle testing, so that optimized control parameters could be used to obtain improved emission results under test conditions. In this paper, a novel method is described and applied to generate a dynamic driving cycle that statistically matches the real-life operation of a vehicle. The analysis is performed based on an extensive field data set obtained during an automated measurement campaign of public busses for more than a full year with 27,365 h of operation and 315,583 km driven in the city of Hamburg (Germany). The data collected is statistically compared to the static reference cycles New European Driving Cycle (NEDC) and Worldwide harmonized Light Vehicles Test Procedure (WLTP). Two micro trip models with increasing complexity are described and fit to the data set. All models are quantitatively compared to the measured data set applying a Quality of Fit (QoF) indicator. Based on the highest consistency to field data, a non-deterministic driving cycle generator is developed and its output is statistically compared to the original measurement. In contrast to the existing reference cycles, the dynamic output of the non-deterministic driving cycle generator presented in this paper is statistically proven to be consistent with real-life operation of public busses in the urban environment of Hamburg.     

Effects of battery chemistry and performance on the life cycle greenhouse gas intensity of electric mobility

Lithium traction batteries are a key enabling technology for plug-in electric vehicles (PEVs). Traction battery manufacture contributes to vehicle production emissions, and battery performance can have significant effects on life cycle greenhouse gas (GHG) emissions for PEVs. To assess emissions from PEVs, a life cycle perspective that accounts for vehicle production and operation is needed. However, the contribution of batteries to life cycle emissions hinge on a number of factors that are largely absent from previous analyses, notably the interaction of battery chemistry alternatives and the number of electric vehicle kilometers of travel (e-VKT) delivered by a battery. We compare life cycle GHG emissions from lithium-based traction batteries for vehicles using a probabilistic approach based on 24 hypothetical vehicles modeled on the current US market. We simulate life-cycle emissions for five commercial lithium chemistries. Examining these chemistries leads to estimates of emissions from battery production of 194–494 kg CO₂ equivalent (CO₂e) per kWh of battery capacity. Combined battery production and fuel cycle emissions intensity for plug-in hybrid electric vehicles is 226–386 g CO₂e/e-VKT, and for all-electric vehicles 148–254 g CO₂e/e-VKT. This compares to emissions for vehicle operation alone of 140–244 g CO₂e/e-VKT for grid-charged electric vehicles. Emissions estimates are highly dependent on the emissions intensity of the operating grid, but other upstream factors including material production emissions, and operating conditions including battery cycle life and climate, also affect life cycle GHG performance. Overall, we find battery production is 5–15% of vehicle operation GHG emissions on an e-VKT basis.     

Development of the World-wide harmonized Light duty Test Cycle (WLTC) and a possible pathway for its introduction in the European legislation

This paper presents the World-wide harmonized Light duty Test Cycle (WLTC), developed under the Working Party on Pollution and Energy (GRPE) and sponsored by the European Union (with Switzerland) and Japan. India, Korea and USA have also actively contributed. The objective was to design the harmonized driving cycle from “real world” driving data in different regions around the world, combined with suitable weighting factors. To this aim, driving data and traffic statistics of light duty vehicles use were collected and analyzed as basic elements to develop the harmonized cycle. The regional driving data and weighting factors were then combined in order to develop a unified database representing the worldwide light duty vehicle driving behavior. From the unified database, short trips were selected and combined to develop a driving cycle as representative as possible of the unified database. Approximately 765,000 km of data were collected, covering a wide range of vehicle categories, road types and driving conditions. The resulting WLTC is an ensemble of three driving cycles adapted to three vehicle categories with different power-to-mass ratio (PMR). It has been designed as a harmonized cycle for the certification of light duty vehicles around the world and, together with the new harmonized test procedures (WLTP), will serve to check the compliance of vehicle pollutant emissions with respect to the applicable emissions limits and to establish the reference vehicle fuel consumption and CO₂ performance.     

Analysis of fuel consumption and pollutant emissions of regulated and alternative driving cycles based on real-world measurements

Discrepancies between real-world use of vehicles and certification cycles are a known issue. This paper presents an analysis of vehicle fuel consumption and pollutant emissions of the European certification cycle (NEDC) and the proposed worldwide harmonized light vehicles test procedure (WLTP) Class 3 cycle using data collected on-road. Sixteen light duty vehicles equipped with different propulsion technologies (spark-ignition engine, compression-ignition engine, parallel hybrid and full hybrid) were monitored using a portable emission measurement system under real-world driving conditions. The on-road data obtained, combined with the Vehicle Specific Power (VSP) methodology, was used to recreate the dynamic conditions of the NEDC and WLTP Class 3 cycle. Individual vehicle certification values of fuel consumption, CO₂, HC and NO_x emissions were compared with test cycle estimates based on road measurements. The fuel consumption calculated from on-road data is, on average, 23.9% and 16.3% higher than certification values for the recreated NEDC and WLTP Class 3 cycle, respectively. Estimated HC emissions are lower in gasoline and hybrid vehicles than certification values. Diesel vehicles present higher estimated NO_x emissions compared to current certification values (322% and 326% higher for NO_x and 244% and 247% higher for HC + NO_x for NEDC and WLTP Class 3 cycle, respectively).     

Environmental benefits from improving transportation efficiency in wood procurement systems

Forest operations use fossil fuels, which should be considered when environmental impact in the wood procurement is of concern. Road freight transportation is the most common operation in timber transportation, and thus is an important source of greenhouse gas emissions. This study assesses the impact of the new larger and heavier vehicles (LHV) on environmental emissions using the synchronized calculation method. The maximum (theoretical) and operational effects of 76 t LHV with calculations made for three weight limits (60, 64 and 68 t) are compared in Finland. Based on Enterprise Resource Planning (ERP) data, environmental energy efficiency (measured in relation to the trip) increased 9.2%. The reduction in fuel consumption was 12.5%, though this is likely to under-estimate the long-term effects that will be achieved when forest operations are fully adjusted to the maximum weight limit. A comparison with the European countries and a preliminary sensitivity analysis of the system demonstrate that the technological development to improve the transporting efficiency is essential for realizing 76 t LHV utilization in Finland.     

Influence of driving patterns on vehicle emissions: A case study for Latin American cities

On-board real-time emission experiments were conducted on 78 light-duty vehicles in Bogota. Direct emissions of carbon monoxide (CO), carbon dioxide (CO₂), nitrogen oxides (NO_x) and hydrocarbons (HC) were measured. The relationship between such emissions and vehicle specific power (VSP) was established. The experimental matrix included both gasoline-powered and retrofit dual fuel (gasoline–natural gas) vehicles. The results confirm that VSP is an appropriate metric to obtain correlations between driving patterns and air pollutant emissions. Ninety-five percent of the time vehicles in Bogota operate in a VSP between −15.2 and 17.7 kW ton⁻¹, and 50% of the time they operate between −2.9 and 1.2 kW ton⁻¹, representing low engine-load and near-idling conditions, respectively. When engines are subjected to higher loads, pollutant emissions increase significantly. This demonstrates the relevance of reviewing smog check programs and command-and-control measures in Latin America, which are widely based on static (i.e., idling) emissions testing. The effect of different driving patterns on the city’s emissions inventory was determined using VSP and numerical simulations. For example, improving vehicle flow and reducing sudden and frequent accelerations could curb annual emissions in Bogota by up to 12% for CO₂, 13% for CO and HC, and 24% for NO_x. This also represents possible fuel consumption savings of between 35 and 85 million gallons per year and total potential economic benefits of up to 1400 million dollars per year.     

The limits of partial life cycle assessment studies in road construction practices: A case study on the use of hydrated lime in Hot Mix Asphalt

Extensive published literature shows that hydrated lime improves Hot Mix Asphalt (HMA) durability. Its impact on the environmental impact of HMA has not been investigated. This paper presents a comparative Life Cycle Assessment (LCA) for the use of HMA without hydrated lime (classical HMA) and with hydrated lime (modified HMA) for the lifetime of a highway. System boundaries cover the life cycle from cradle-to-grave, meaning extraction of raw materials to end of life of the road. The main assumptions were: 1. Lifetime of the road 50 years; 2. Classical HMA with a life span of 10 years, maintenance operations every 10 years; 3. Modified HMA with an increase in the life span by 25%, maintenance operations every 12.5 years. For the lifetime of the road, modified HMA has the lowest environmental footprint compared to classical HMA with the following benefits: 43% less primary total energy consumption resulting in 23% lower emissions of greenhouse gases. Partial LCAs focusing only on the construction and/or maintenance phase should be used with caution since they could lead to wrong decisions if the durability and the maintenance scenarios differ. Sustainable construction technologies should not only consider environmental impact as quantified by LCA, but also economic and social impacts as well. Avoiding maintenance steps means less road works, fewer traffic jams and hence less CO₂ emissions.     

The role of alternative fuel vehicles: Using behavioral and sensor data to model hierarchies in travel

Greater adoption and use of alternative fuel vehicles (AFVs) can be environmentally beneficial and reduce dependence on gasoline. The use of AFVs vis-à-vis conventional gasoline vehicles is not well understood, especially when it comes to travel choices and short-term driving decisions. Using data that contains a sufficiently large number of early AFV adopters (who have overcome obstacles to adoption), this study explores differences in use of AFVs and conventional gasoline vehicles (and hybrid vehicles). The study analyzes large-scale behavioral data integrated with sensor data from global positioning system devices, representing advances in large-scale data analytics. Specifically, it makes sense of data containing 54,043,889 s of speed observations, and 65,652 trips made by 2908 drivers in 5 regions of California. The study answers important research questions about AFV use patterns (e.g., trip frequency and daily vehicle miles traveled) and driving practices. Driving volatility, as one measure of driving practice, is used as a key metric in this study to capture acceleration, and vehicular jerk decisions that exceed certain thresholds during a trip. The results show that AFVs cannot be viewed as monolithic; there are important differences within AFV use, i.e., between plug-in hybrids, battery electric, or compressed natural gas vehicles. Multi-level models are particularly appropriate for analysis, given that the data are nested, i.e., multiple trips are made by different drivers who reside in various regions. Using such models, the study also found that driving volatility varies significantly between trips, driver groups, and regions in California. Some alternative fuel vehicles are associated with calmer driving compared with conventional vehicles. The implications of the results for safety, informed consumer choices and large-scale data analytics are discussed.     

The travel and environmental implications of shared autonomous vehicles,using agent-based model scenarios

Carsharing programs that operate as short-term vehicle rentals (often for one-way trips before ending the rental) like Car2Go and ZipCar have quickly expanded, with the number of US users doubling every 1–2 years over the past decade. Such programs seek to shift personal transportation choices from an owned asset to a service used on demand. The advent of autonomous or fully self-driving vehicles will address many current carsharing barriers, including users’ travel to access available vehicles.This work describes the design of an agent-based model for shared autonomous vehicle (SAV) operations, the results of many case-study applications using this model, and the estimated environmental benefits of such settings, versus conventional vehicle ownership and use. The model operates by generating trips throughout a grid-based urban area, with each trip assigned an origin, destination and departure time, to mimic realistic travel profiles. A preliminary model run estimates the SAV fleet size required to reasonably service all trips, also using a variety of vehicle relocation strategies that seek to minimize future traveler wait times. Next, the model is run over one-hundred days, with driverless vehicles ferrying travelers from one destination to the next. During each 5-min interval, some unused SAVs relocate, attempting to shorten wait times for next-period travelers.Case studies vary trip generation rates, trip distribution patterns, network congestion levels, service area size, vehicle relocation strategies, and fleet size. Preliminary results indicate that each SAV can replace around eleven conventional vehicles, but adds up to 10% more travel distance than comparable non-SAV trips, resulting in overall beneficial emissions impacts, once fleet-efficiency changes and embodied versus in-use emissions are assessed.     

A comparative life-cycle energy and emissions analysis for intercity passenger transportation in the U.S. by aviation,intercity bus,and automobile

Intercity passenger trips constitute a significant source of energy consumption, greenhouse gas emissions, and criteria pollutant emissions. The most commonly used city-to-city modes in the United States include aircraft, intercity bus, and automobile. This study applies state-of-the-practice models to assess life-cycle fuel consumption and pollutant emissions for intercity trips via aircraft, intercity bus, and automobile. The analyses compare the fuel and emissions impacts of different travel mode scenarios for intercity trips ranging from 200 to 1600 km. Because these modes operate differently with respect to engine technology, fuel type, and vehicle capacity, the modeling techniques and modeling boundaries vary significantly across modes. For aviation systems, much of the energy and emissions are associated with auxiliary equipment activities, infrastructure power supply, and terminal activities, in addition to the vehicle operations between origin/destination. Furthermore, one should not ignore the embodied energy and initial emissions from the manufacturing of the vehicles, and the construction of airports, bus stations, highways and parking lots. Passenger loading factors and travel distances also significantly influence fuel and emissions results on a per-traveler basis. The results show intercity bus is generally the most fuel-efficient mode and produced the lowest per-passenger-trip emissions for the entire range of trip distances examined. Aviation is not a fuel-efficient mode for short trips (<500 km), primarily due to the large energy impacts associated with takeoff and landing, and to some extent from the emissions of ground support equipment associated with any trip distance. However, aviation is more energy efficient and produces less emissions per-passenger-trip than low-occupancy automobiles for trip distances longer than 700–800 km. This study will help inform policy makers and transportation system operators about how differently each intercity system perform across all activities, and provides a basis for future policies designed to encourage mode shifts by range of service. The estimation procedures used in this study can serve as a reference for future analyses of transportation scenarios.     

Real world vehicle emissions: Their correlation with driving parameters

Vehicular population in developing countries is expected to proliferate in the coming decade, centred on Tier II and Tier III cities rather than large metropolis. WLTP is being introduced as a global instrument for emission regulation to reduce gap between standard test procedures and actual road conditions. This work aims at quantifying and discernment of the gap between WLTC and real-world conditions in an urban city in a developing country on the basis of driving cycle parameters and simulated emissions for gasoline fuelled light passenger cars. Real world driving patterns were recorded on different routes and varying traffic conditions using car-chasing technique integrated with GPS monitoring and speed sensors. Real-world driving patterns and ambient conditions were used to simulate emissions using International Vehicle Emissions model for average rate (g/km) and Comprehensive Modal Emissions Model for instantaneous emission (g/s) analysis. Cycle parameters were mathematically calculated to compare WLTC and road trips. The analyses revealed a large gap between WLTC and road conditions. CO emissions were predicted to be 155% higher than WLTC and HC and NOx emissions were estimated to be 63% and 64% higher respectively. These gaps were correlated to different driving cycle parameters. It was observed that road driving occurs at lower average speeds with higher frequency and magnitudes of accelerations. The positive kinetic energy required by road cycles, was 100% higher than WLTC and the Relative Positive Acceleration (RPA) demanded by road cycles, was found to be 60% higher in real-world driving patterns and thereby contribute to higher emissions.     

Developments of CO2-emissions and costs for small electric and combustion engine vehicles in Germany

Electric vehicles have the potential to lower emissions in the mobility sector, but especially high costs might hinder their market development. This paper aims to access environmental and economic impacts and potentials by comparing CO₂-emissions and costs of small vehicles. Considering actual data it is analysed, if and under which conditions electric vehicles are financially competitive for private consumers and under which conditions emissions can be saved. For this, a multiple-stage approach is focusing on (1) emissions during production and operation, (2) private costs and (3) external costs of emissions. A model of total cost of ownership is applied for the analysis of private and external costs.Results show that emissions of electric vehicles exceed emissions of combustion engine vehicles in the production phase, but electric vehicles cause fewer emissions during operation. Total emissions can be saved by electric vehicles even with low annual driving distances (2500–5500 km/a today). Results highly depend on the form of electricity production.Today, private costs of electric vehicles exceed the costs of combustion engine vehicles. Due to cost decreases electric vehicles can gain financial advantages in the future. External costs are high, especially for combustion engine vehicles (up to 15% of private costs), but in none of the considered cases high enough to give electric vehicles a financial advantage today. This picture will change in the future.     

Assessing CO2 emissions of electric vehicles in Germany in 2030

Electric vehicles are often said to reduce carbon dioxide (CO₂) emissions. However, the results of current comparisons with conventional vehicles are not always in favor of electric vehicles. We outline that this is not only due to the different assumptions in the time of charging and the country-specific electricity generation mix, but also due to the applied assessment method. We, therefore, discuss four assessment methods (average annual electricity mix, average time-dependent electricity mix, marginal electricity mix, and balancing zero emissions) and analyze the corresponding CO₂ emissions for Germany in 2030 using an optimizing energy system model (PERSEUS-NET-TS). Furthermore, we distinguish between an uncontrolled (i.e. direct) charging and an optimized controlled charging strategy. For Germany, the different assessment methods lead to substantial discrepancies in CO₂ emissions for 2030 ranging from no emissions to about 0.55 kg/kWh_el (110 g/km). These emissions partly exceed the emissions from internal combustion engine vehicles. Furthermore, depending on the underlying power plant portfolio and the controlling objective, controlled charging might help to reduce CO₂ emissions and relieve the electricity grid. We therefore recommend to support controlled charging, to develop consistent methodologies to address key factors affecting CO₂ emissions by electric vehicles, and to implement efficient policy instruments which guarantee emission free mobility with electric vehicles agreed upon by researchers and policy makers.     

Environmental benefits analysis of electric vehicles in the Czech Republic

The article evaluates the environmental benefits of electric vehicles using well-to-wheel analysis in the Czech Republic. The power consumption per kilometer is determined from the combined cycle of the New European Driving Cycle. Using information from the integrated registry of polluters and mandatory disclosures of the CEZ company the specific harmful emissions production per 1 kW h of electricity is determined. The combination of electricity consumed and the production of harmful emissions per 1 kW h of electricity determine the indirect harmful emissions of an electric vehicle per kilometer. Computer simulation of the indirect production of harmful emissions is performed on the Mitsubishi MiEV engine, typical for an electric vehicle.     

China’s electric car frustrations

By 2020, the vehicle population in China will likely exceed 280 million—exacerbating national energy security, urban air pollution, and traffic congestion. In response, many local and regional governments in China are pursuing an expanding array of measures to restrain growth in personal vehicle ownership and, along with the central government, reducing emissions and energy use of vehicles. One prominent strategy is the promotion of new energy vehicles, especially plug-in electric vehicles (PEVs). Large subsidies were offered—up to $27,600 (171,000 RMB) per vehicle in some regions, including almost $9200 (57,000 RMB) from the central government—which suggests that China is making a major commitment to PEVs. But sales have been meager. In 2013, only 17,600 PEVs, mostly buses and utility trucks, were sold, less than 0.1% of total civilian vehicle sales. Several factors explain the failure of PEV sales to take off: (1) protectionism by local governments; (2) uncertainty over which electric-drive vehicle technologies to promote and what consumers are willing to pay, (3) lagging investments in charging infrastructure, and (4) conservative investment behavior by automakers and battery manufacturers. The central government issued directives to local governments in late 2013 to reduce barriers to out-of-town companies, resulting in modest sales increases in early 2014, but a more coherent, broader, and effective set of policies, incentives, and strategies are needed to overcome consumer and industry resistance and the lack of charging infrastructure.     

Idling stop fines for exceeding legal idling times – From the driver’s perspective

In order to reduce CO₂ emissions from motorised transport, the Taiwanese government implemented an idling policy for vehicles in 2012. This paper applies a contingent valuation framework based on stated preference questions to calculate a reasonable fine for idling vehicles based on drivers’ preferences in Taiwan. Drivers were surveyed at urban roadsides to determine the amount of money they would prefer to pay for idling in excess of the 3 min currently allowed by law. The results obtained from our spike model analysis showed that drivers would prefer to pay a fine of 1720 NTD (approximately USD 57).     

Evaluating the social cost of cruise ships air emissions in major ports of Greece

Detailed NO_x, SO₂ and PM_2.5 emissions have been estimated for cruise ships in the five busiest Greek ports (i.e. Piraeus, Santorini, Mykonos, Corfu and Katakolo) for year 2013. The emissions were analyzed in terms of gas species, seasonality and activity. The total in-port inventory of cruise shipping accounted to 2742.7 tons: with NO_x being dominant (1887.5 tons), followed by SO₂ and PM_2.5 (760.9 and 94.3 tons respectively). Emissions during hotelling corresponded to 88.5% of total and have significantly outweighed those produced during ships’ maneuvering activities (11.5% of total). Seasonality was found to play a major role, as summer emissions and associated impacts were significantly augmented. The anticipated health impacts of ship emissions can reach to €24.3 million or to €5.3 per passenger proving the necessity of control of the emissions produced by cruise ships in port cities or policy and measures towards a more efficient cruise industry.     

Potential of low viscosity oils to reduce CO2 emissions and fuel consumption of urban buses fleets

This paper shows the results of a comparative fleet test the main objective of which was to measure the influence of Low Viscosity Oils (LVO) over the fuel consumption and CO₂ emissions of urban buses. To perform this test, 39 urban buses, classified into candidate and reference groups depending on the engine oil viscosity, covered a 60,000 km mileage corresponding to two rounds of standard Oil Drain Interval (ODI). In the same way, for 9 buses of the 39 buses, the effect of differential LVO over fuel consumption and their interaction with engine LVO was assessed during the second ODI.Test results confirm that the use of LVO could reduce fuel consumption, hence CO₂ emissions. However, special attention should be taken prior to its implementation in a fleet, particularly if the vehicles are powered by engines with high mechanical and thermal stresses during vehicle operation because this could lead to friction loss increase, loss of the potential fuel consumption reduction of LVO and, in the worst scenario, higher rates of engine wear.     

The problem of cold starts: A closer look at mobile source emissions levels

While the phenomenon of excess vehicle emissions from cold-start conditions is well known, the magnitude and duration of this phenomenon is often unclear due to the complex chemical processes involved and uncertainty in the literature on this subject. This paper synthesizes key findings regarding the influence of ambient and engine temperatures on light-duty vehicle (LDV) emissions. Existing literature, as well as analytical tools like the U.S. Environmental Protection Agency’s Motor Vehicle Emission Simulator (MOVES), indicate that while total vehicle emissions have dropped significantly in recent years, those associated with cold starts can still constitute up to 80% for some pollutant species. Starting emissions are consistently found to make up a high proportion of total transportation-related methane (CH₄), nitrous oxide (N₂O), and volatile organic compounds (VOCs). After 3–4 min of vehicle operation, both the engine coolant and the catalytic converter have generally warmed, and emissions are significantly lower. This effect lasts roughly 45 min after the engine is shut off, though the cooling rate depends greatly on the emission species and ambient temperature. Electrically (pre-)heated catalysts, using the bigger batteries available on hybrid drivetrains and plug-in vehicles, may be the most cost-effective technology to bring down a sizable share of mobile source emissions. Trip chaining (to keep engines warm) and shifting to non-motorized modes for shorter trips, where the cold start can dominate emissions, are also valuable tactics.