非能动氢气复合装置的开发设计

非能动氢气复合装置是核电站发生严重事故时用于消除安全壳内氢气的安全设备之一。我们提出采用催化消氢的原理,利用新研制的全金属型催化剂消除氢气,并利用反应热,以温度梯度为推动力,非能动地进行反应。该方法不仅适用于核电站超设计基准事故下消氢,还适用于设计基准事故下的消氢。其他场合下的消氢也可选用。     

阳极氧化法制备消氢催化剂金属载体及其性能研究

用阳极氧化法制备消氢催化剂金属载体,以磷酸为电解液考察了温度、氧化时间、氧化电压、电流最大密度以及水封处理对氧化膜表面的影响,用SEM表征方法对多孔氧化铝膜进行了表征.结果表明,氧化膜厚度达13.4 μm.孔径达100 nm.将Pt-Pd负载在自制的载体上制成消氢催化剂,该催化剂可在常温、氢气浓度1.1%～1.3%、空...     

Pt/SDB疏水催化剂的制备及其用于水相消氢

将疏水催化剂应用于水相消氢可以提高电解水制氧装置的氧气纯度.本文以聚苯乙烯 - 二乙烯基苯(SDB)树脂为载体制备了高度分散的Pt/SDB疏水催化剂,并将其应用于水相消氢实验中.结果表明,6%的Pt/SDB催化剂消氢活性最高.在H2/O2空速(GHSV)10 000 h-1,水流量30 L/h,温度60 ℃时,氢气消除率达到了80%.采用X射线衍射、X射线光电子能谱、扫描电子显微镜、热重分析仪对制备的催化剂进行了表征.分析发现,制备的催化剂具有良好的疏水性,Pt已被还原为0价态并以高度分散态存在,平均粒径小于5 nm.     

MgH2-Na2Ti3O7微米棒复合材料的 吸氢性能及其改性机制

采用固相法合成尺寸为微米级别的钛酸钠(Na_2Ti_3O_7)催化剂,并通过球磨法与氢化镁(MgH_2)复合,以此来催化改性MgH_2的吸氢性能.等温吸氢实验表明:MgH_2-Na_2Ti_3O_7微米棒复合材料在275℃和150℃下吸收3%H_2的时间分别为10 s和15 min,甚至在低至50℃下30 min内还能吸收1%的H_2,而纯MgH_2在275℃下30 min内仅能吸收1.5%的H_2.进一步研究发现,MgH_2吸氢性能的提高归因于Na_2Ti_3O_7在MgH_2基体中的均匀分布以及在循环过程中原位生成的TiH_2.文中创新性地采用Na_2Ti_3O_7微米棒作为催化剂并将其均匀分布在MgH_2中,可为下一代高性能储氢材料的设计提供一种新思路.     

消氢催化剂的应用研究

通过对Pb／Al2O3，Pb/MnO2、Pd／C、Pd／TiO2四种消氢催化剂在不同条件下失效时间的试验研究，得出了温度、反应时间、和含钯量对催化剂失效时间的影响。试验结果表明：本文所用四种催化剂在脱氢反应中必须加温才能保持活性，否则要定期进行活化再生。     

TiH1.971催化Mg纳米晶储氢性能研究

采用湿化学球磨法制备了Mg+TiH1.971复合体系,并以对比分析法研究了催化剂Mg+TiH1.971对Mg纳米晶的储氢性能改善效果.研究结果表明,Mg+TiH1.971纳米晶复合体系在室温下20℃左右就能开始吸氢,而Mg纳米晶则需40℃.吸氢后的Mg+TiH1.971(w(TiH1.971)=5％)在220℃下开始放...     

降低船舶NOx排放的NO催化氧化联合SCR试验研究

用浸渍法制备钴基催化剂,考察了载体、活性组分负载量、焙烧温度、助剂等制备条件对钴基催化剂催化氧化NO性能的影响,结果表明：以ZrO2为载体,活性组分负载量为10%,表面活性剂含量5%,在350℃焙烧的催化剂具有最佳的NO催化氧化性能,在NO进口浓度700ppm、O2体积分数5%、空速27000 h-1的条件下,200℃时NO氧化率可达49%,满足快速SCR的条件。对NO催化剂进行孔隙结构及XRD表征,结果表明催化剂比表面积的大小不是决定催化剂活性的必要条件,而Co3O4晶体平均颗粒尺寸的大小对催化剂活性有一定影响。考察了空速对催化剂效率的影响,发现NO催化氧化剂在较高空速下仍居有一定活性,并对低温、高空速条件下SCR的反应效率有较大提升。在180℃时,SCR的NO去除效率由联合前的53%提高至65%。     

Cr助剂对甲醇水蒸气重整制氢铜系催化剂性能影响的研究

通过正交试验初步确定催化剂的制备工艺,结合单因素实验对催化剂的组成进行了深入考察。在H2O/CH3OH摩尔比为1.3、液空速为1.5 h-1、反应温度为220℃和250℃的条件下,考察了铬助剂对催化剂性能的影响。结果表明,Cu/Cr质量比为1∶1时催化效果最佳,出口气体中CO的含量降低了50%,甲醇的转化率提高了20%。     

消氢技术和设备

本文综述了消氢技术基本原理，综述了国内外各种消氢设备和消氢技术的应用情况。     

非能动氢复合器消氢性能研究:催化板数量影响

采用计算流体力学方法对具有相同尺寸的非能动氢复合器稳态消氢过程进行了模拟,分析了催化板数量改变对复合器消氢性能的影响。在所分析催化板数量范围内,随着催化板数量增加,消氢速率和消氢效率先线性增大,再呈抛物线变化;催化板表面温度先增大再有所减小。氢气局部点火风险随着催化板数量增加而增大。     

Errata

正In the paper"Influence of Fouling Assemblage on the Corrosion Behaviour of Mild Steel in the Coastal Waters of The Gulf of Mannar,India"in Vol.12,No.4,Page:509,References were lost,and the two authors’biographies were identical.The correct text is shown below.We apologize to the authors and our readers for any inconvenience caused by the errors.     

Journal of Marine Science and Application 2014 Sum. Contents

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第34届海洋、离岸及极地工程国际会议(英文)

正St.John's,Newfoundland,Canada,May 31-June 5,2015 OMAE2015 is the ideal forum for researchers,engineers,managers,technicians and students from the scientific and industrial communities from around the world to: meet and present advances in technology and its scientific support;     

联合作战计划和执行系统

全球指挥控制系统(GCCS)实施当前美国海军网络中心战信息基础设施的联合计划网络。联合作战计划和执行系统(JOPES)支持GCCS实现联合计划。JOPES有两类计划：时间不限的精密预案计划生成作战计划、方案计划或职能计划；时间敏感的危机行动计划生成作战命令或战役方案。前者在和平时期创建的作战计划是后者的计划基础，加速应付危机的能力。     

Eastbound or westbound ?

In terms of equal sailing distances, where is the inflexion when ships depart from ports in the Asian Continent to New York via Suez and/or Panama？
The answer is China South Port Group （Hong Kong, Shenzhen and Guangzhou）.     

Recent progress on wave induced loading measurements in warships

Recent measurements of wave induced hull strain and flexure in RN warships are presented together with the derivation of the current design criteria for extreme hull girder bending loads. The history of the development of the shipboard instrumentation used is given and recent developments to improve the quality and ease of analysis of the data are described. An unexpectedly high transverse asymmetry in the longitudinal strains measured in destroyers is shown to be the result of a combination of vertical and lateral bending in oblique seas. Finally recent theoretical comparisons between the loading of Deep-Vee hulls and conventional UK rounded bilge hulls are presented which demonstrate the higher loading experienced by this type of hull form.     

桥梁防撞设施物理模型试验

物理模型试验是预报防撞设施所受撞击力及优化设计方案的主要方法之一。结合杭州湾大桥柔性防撞设施及东海大桥独立式防撞体设计方案,阐述了船—防撞体撞击试验的基本原理、方法、试验方案及相关试验结果。提出了柔性防撞系统的优化方案。试验结果表明,该方案经济有效,可供预报类似桥梁防撞设施撞击力时参考。     

印尼某电厂码头水工建筑物设计

印尼某电厂项目码头水工建筑物包括码头、防波堤和护岸等主要组成部分。在该项目水工建筑物的设计过程中,综合考虑当地的自然条件、施工能力和材料来源等因素,不断优化结构选型和结构断面。根据不同使用要求,护岸分别采用直立式和斜坡式2种结构型式,推荐的设计方案节省投资、施工方便,可供同类工程设计参考。     

Impact of regulation on the performances of long-distance transport services: A comparison of the different approaches in Sweden and Norway

Despite the many socio-economic similarities between Sweden and Norway, differences in jurisdiction, organisation, cooperation, and financing of long-distance passenger train and coach services have led to the development of four distinctively different ways of serving the markets. This paper describes how the train and coach markets have developed in the two countries, with emphasis on regulatory and industrial structure and a couple of performance variables.Looking at passenger rail, both countries separated infrastructure from operation over a decade ago. However, while Norwegian rail is characterised by an almost monopoly supplier, rail services in Sweden are partly decentralised to the responsibility of county authorities and are widely subjected to competitive tendering. The rest of the network is about to be opened up for on-the-track competition. Swedish Rail (SJ) has spent the last decades consolidating its core business (passenger rail) and sold out its other businesses. In contrast, the Norwegian state rail (NSB) has expanded its business to become a major bus operator and property owner, with extensions also into the Swedish market.The coach industry was more recently deregulated in both countries. The Swedish coach market is dominated by privately owned companies operating services to and from Stockholm. In Norway, state-owned NSB is a major coach operator on medium distance routes, and is also the largest partner of Nor-Way Bussekspress which totally dominates long-distance coach services. Further, the Norwegian coach market is characterised by cross-ownership and cooperation which has enabled an extensive route network which covers most of Norway.We find distinct differences in achievements in the two modes and in the two countries. Swedish rail services have succeeded in winning market shares and in renewing and developing both infrastructure and service levels to a greater extent than the Norwegian model. On the other hand, the Norwegian coach market seems to be more developed and efficient compared to its Swedish counterpart.The paper concludes with a discussion on the possible links between the different approaches and the performance observed, with the aim to stimulate further and more detailed research on some important issues.     

开放式数据挖掘系统模型

目前国内已经出现了少量的数据挖掘相关产品。国内数据挖掘软件无论从数量还是质量上比较，都与国外软件存在着较大的差距。随着数据仓库技术的普及，数据挖掘应用的需求越来越强烈，如何缩短这种差距，研发数据挖掘软件产品成为国内业界的一个重要问题。通过引用目前国际通用数据挖掘标准技术来构建开放式的数据挖掘系统模型，该系统模型从可扩展性、可重用性、易用性等方面得到了加强。