Research on Electron Beam Welding of in situ TiB_(2p)/ZL101 Composite

AbstractElectron beam welding of in situ TiB2p reinforced aluminum composites was studied.The results show that no obvious pores or cracks is presented in the weld seam.The grains in the weld seam are remarkably refined and TiB2 particles distribute much more homogeneously than that in base metal.The hardness values of fusion zone and heat affected zone(HAZ)are both increased in comparison with that of base metal.There are no interface reactions between TiB2 particle and Al matrix.This results supply the evidence that the novel TiB2p reinforced aluminum composites can be well joined with the electron beam welding.     

Research on reduction of Fe<Subscript>2</Subscript>O<Subscript>3</Subscript> by biomass sawdust

The research on biomass reduction of Fe₂O₃ was carried out by using sawdust as reductant. The direct reducing agents in the biomass magnetization process were determined by comparing various biomass pyrolysis products with the reduction degree (divalent iron content in total iron), reduction temperature range and valence change of Fe₂O₃ in the reduction process. The microstructure variation of Fe₂O₃ at different stages was also analyzed by scanning electron microscopy (SEM). Nonisothermal thermogravimetric analysis (TGA) was applied to explore the thermal reduction process. The results show that the direct reducing substances in the biomass reaction with Fe₂O₃ are H₂ and bio-oil, and the reduction process can be divided into two steps: biomass pyrolyzing to release H₂ and bio-oil, and reductive volatiles reacting with Fe₂O₃. The two steps are relatively independent. The kinetic of the reduction reaction follows a first-order reaction kinetic model, with 88.99 kJ/mol activation energy and 9.55 × 10⁸ min^?1 frequency factor.     

Study on Oxidation Activity of CuCeZrO<Subscript><Emphasis Type="Italic">x</Emphasis></Subscript> Doped with K for Diesel Engine Particles in NO/O<Subscript>2</Subscript>

CuCeZrO_x and KCuCeZrO_x catalysts were synthesized and coated on the blank diesel particulate filter (DPF) substrate and a particulate matter (PM) loading apparatus was used for soot loading. The catalytic performances of soot oxidation were evaluated by temperature programmed combustion (TPC) test and characterization tests were conducted to investigate the physicochemical properties of the catalysts. The reaction mechanism in the oxidation process was analyzed with diffuse reflectance infrared Fourier transform spectroscopy. The results demonstrated that CuCeZrO_x catalyst exhibited high activities of soot oxidation at low temperature and the best results have been attained with Cu_0.9Ce_0.05Zr_0.05O_x over which the maximum soot oxidation rate decreased to 410 °C. Characterization tests have shown that catalysts containing 90% Cu have uniformly distributed grains and small particle sizes, which provide excellent oxidation activity by providing more active sites and forming a good bond between the catalyst and the soot. The low-temperature oxidation activity of soot could be further optimized due to the excellent elevated NO’s conversion rate by partially substituting Cu with K. The maximum particle oxidation rate can be easily realized at such a low temperature as 347°C.     

Catalytic Combustion of Lean Methane Assisted by Electric Field over Pd/Co<Subscript>3</Subscript>O<Subscript>4</Subscript> Catalysts at Low Temperature

A series of Pd/Co₃O₄ catalysts were prepared by Self-Propagating High-Temperature Synthesis (SHS) method in this study, and electric field was applied for catalytic combustion of lean methane over Pd/Co₃O₄ catalysts at low temperature. When electric field was applied, the catalytic combustion performance of Pd/Co₃O₄ catalysts was greatly improved, and the application of electric field could reduce the load of active element Pd to some extent while maintaining the same efficiency. Based on experimental tests and the analysis results of X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), H₂-temperature-programmed reduction (H₂-TPR) and in-situ diffuse reflectance infrared Fourier transform spectroscopy (in-situ DRIFTS), the mechanism of catalytic oxidation of CH₄ over Pd/Co₃O₄ catalysts in electric field was proposed. The catalytic combustion of CH₄ occurs only when the temperature is higher than 250 °C normally, but when electric field was applied, the whole process of CH₄ oxidation was promoted significantly and the reaction temperature was reduced. Electric field could promote the reduction of the support Co₃O₄ to release the lattice oxygen, resulting in the increase of PdO_x and the surface chemisorbed oxygen, which could provide more active sites for the low-temperature oxidation of CH₄. Furthermore, electric field could accelerate the dehydroxylation of CoOOH to further enhance the activity of the catalysts.     

Coupled heat and mass transfer analysis of NH<Subscript>3</Subscript>-H<Subscript>2</Subscript>O falling film absorption on inner tube surface with low solution flow rates

NH₃-H₂O falling film absorption usually takes place with low solution flow rate in real absorption refrigeration system. An experimental study of inner vertical absorption is carried out for the consideration of air-cooling absorber. Variable working conditions are tested to evaluate the heat and mass transfer performances.The traditional evaluation method based on log-mean-temperature（concentration） difference is criticized for its lack of theoretical basis while simultaneous heat and mass transfer process occurs. A new method proposed by Kim and Infante Ferreira is modified to evaluate the experimental results with reasonable assumptions. The method is based on the derivation of coupled heat and mass transfer differential equations of NH₃-H₂O absorption process.The analysis of the same experimental data shows that the new method realizes better consistency with smaller error, especially in heat transfer aspect. Heat and mass transfer performance is enhanced with the increase of solution Reynolds number. Sub-cooling of inlet weak solution also has positive influence on the absorption process,which should be evaluated by the new method correctly. Two correlations are developed to evaluate both Nusselt and Sherwood numbers for the design of air-cooling absorber.     

Monte Carlo simulation of B2-L2<Subscript>1</Subscript> ordering transitions in Au-Cu-Al alloy systems

The B2-L2₁ ordering transitions in Au-Cu-Al shape-memory alloys are studied by the Monte Carlo exchange simulations, where a set of the first, the second and the third nearest-neighbor mixing potentials for Cu-Al in the Au-Cu-Al alloys are calculated from first principals using the Connolly-Williams methods. To ensure the phase stability of the β-Au-Cu-Al, the investigation includes the range of compositions Au₂Cu_1−x Al_1+x (−0.15 ⩽ x ⩽ 0.15). The B2-L2₁ transition temperatures are predicted, and are in agreement with the experimental results. The atomic ordering around vacancy of the L2₁ structure is further discussed.     

Investigation on the formation mechanism of ordered carbide (FeMn)<Subscript>3</Subscript>AlC in the Al added twinning-induced plasticity steels

The spinodal composition zone in Al added Fe-Mn-Al-C twinning-induced plasticity（TWIP） steels can be determined by contents of Al and C and aging temperature together, based on the thermodynamic analysis. Precipitation of ordered（FeMn）₃AlC carbide by the mechanism of spinodal decomposition occurs in the C-rich and Al-rich zone with low aging temperature. Increase of aging temperature shrinks spinodal composition zone to the high Al and C contents. As a result, the precipitation of（FeMn）₃AlC carbide alters from spinodal decomposition to classical nucleation-growth manner gradually. Further calculation indicates that the diffusion of Al can play a key role in determining the growth rate of（FeMn）₃AlC carbide at high aging temperature.     

组合效应对腹板削弱型梁柱节点的影响

采用数值模拟方法分析了混凝土楼板组合效应对钢框架腹板开圆孔削弱型梁柱节点的影响,着重讨论了节点承栽力、弹塑性阶段的应变分布、梁塑性区的产生和扩展情况,并与未考虑组合效应此类节点的性能进行了对比．削弱截面与柱的距离和削弱半径是重要的削弱参数,决定了腹板削弱型节点塑性区的扩展特征．研究结果表明,组合效应对腹板开圆孔削弱型梁柱节点区域的应变分布和塑性区扩展影响显著,其削弱参数的确定须充分考虑楼板组合效应．     

PS/2键盘在嵌入式系统中的应用研究

PS/2键盘应用于嵌入式系统可增加电路设计的灵活性,针对如何使用这种接口介绍了PS/2接口协议,主要讨论了由可编程器件实现PS/2接口的方法,并提出了一种采用队列处理键盘数据的方法,该方法具有模块化、可移植性好的优点.     

SO2-4/TiO2-SiO2固体超强酸光催化降解茜素红染料的实验研究

采用共沉淀-浸渍法制备了SO42-/TiO2-SiO22型固体超强酸催化剂,研究工艺条件对茜素红水溶液脱色率的影响.结果表明:在催化剂用量为2.0 g/L,溶液pH值为8,水样初始浓度为50 mg/L,光距为12 cm,光照反应时间为3 h的最佳条件下,其对茜素红的脱色率可大于92.02%.     

二维数字试件中骨料模型分析

建立混凝土的细观数字试件,进行数值模拟试验,探讨骨料体积率、骨料级配对混凝土的力学性能的影响具有重要的意义。二维数字试件是采用广泛的一种模型,其中的骨料面积率、剖面级配与三维模型中的骨料体积率和体积级配的关系还没有专门的探讨,然而此项工作对二维数字试件的建立与应用具有很大影响。本文以计算机试验为手段,针对随机的三维骨料投放进行大量的计算机模拟试验,阐述骨料面积率、剖面级配与骨科体积率和三维级配的规律,建立了二维数字试件模型中骨料模型,为二维细观数字试件的研究奠定了基础。     

Emme/2中路网数据优化方法研究

通过对Emme/2交通规划软件各个模块的深入分析,结合实际操作经验,指出Emme/2在分配路网数据的输入模块存在的不足,针对不足提出了一套有效的解决方案,使Emme/2基础路网数据输入简单化,从而达到缩短整个交通预测周期的目标。     

Emme/2中路网数据优化方法研究

通过对Emme/2交通规划软件各个模块的深入分析,结合实际操作经验,指出Emme/2在分配路网数据的输入模块存在的不足,针对不足提出了一套有效的解决方案,使Emme/2基础路网数据输入简单化,从而达到缩短整个交通预测周期的目标.     

Pro/E教学中若干问题的对策研究与实践

针对Pro/E教学过程中存在的一些实际问题进行了研究,提出了相应的解决方法。本文把这些技巧和经验总结出来供大家参考,为Pro/E的使用者提高绘图质量和效率提供一些帮助。     

船舶工程类专业应用型本科创新人才协同培养模式研究

根据应用型本科人才培养和船舶工程类专业的特点,从人才培养方案和课程体系的制定、实训基地建设、教师队伍建设等方面阐述了船舶工程类专业应用型本科创新人才协同培养模式的构建.     

项目教学法在《船舶 CAD/CAM》课程教学中的应用研究简

“项目教学法”是一种典型的以学生为中心的教学方法,特别适合船舶CAD/CAM这种理论性和实践性都非常强的课程教学。文章从项目的设计、实施等方面介绍了项目教学法在《船舶CAD/CAM》课程教学中的应用。     

Tam?o:在上川岛还是在屯门澳——Tam?o考订研究的学术史回顾

Tam(a)o地望的考订是早期中葡关系史研究中的一个热点问题.本文对研究中影响较大的两派意见的争论过程进行了学术回顾和评析.文章指出,此一研究经历了两个阶段纠正上川岛说之误和确定Tam(a)o屯门澳内何岛;对上川岛说提出质疑,是Tam(a)o考订研究的重要进展,将考察的目光由上川岛转向南头附近的屯门海澳,使此一研究沿着正确的思路发展;在此基础上,通过中外原始文献和地图资料的互补互证,较为妥善地解决了Tam(a)o为屯门澳内何岛的问题.最后,文章强调了正确把握学术史和准确运用原始资料对于史学创新的重要性.     

纳米SiO2对混凝土盐类结晶循环性能的影响

为了改善混凝土在海水、土壤等盐环境中的性能,通过混凝土强度试验,研究了掺纳米SiO2混凝土在盐类结晶循环中的性能,并通过扫描电子显微镜（SEM）和X-射线衍射分析（XRD）对混凝土微观结构进行了研究.结果表明：纳米SiO2能够改善混凝土的性能;从性能和经济两方面考虑,推荐纳米SiO2的最佳掺量（质量分数）为1%.与基准混凝土相比,在110次循环后,掺纳米SiO21%的混凝土的耐腐蚀循环系数和相对耐腐蚀循环系数分别提高11%和20%.微观结构分析表明,纳米SiO2可以改善混凝土界面结构,降低氢氧化钙的含量.     

UV/H2O2降解水中2,4-二氯酚试验研究

用UV／H2O2光氧化反应器,以2,4-二氯酚为指代物,研究了不同2,4-二氯酚起始浓度、H2O2浓度、pH值及温度对2,4-二氯酚去除效果的影响．实验结果表明,UV／H2O2是对2,4-二氯酚脱毒的一种有效方法,75min内2,4-二氯酚去除率可达到98％以上．     

PASP在高钙高碱水质中的阻垢性能研究

通过液相法合成了聚天冬氨酸(PASP),并对其在普通水质、高温水质、高钙高碱水质条件下的阻垢性能进行了详细试验.结果表明,PASP阻垢率高,具有良好的热稳定性,对高钙高碱有良好的抗负荷冲击能力,是一种阻垢性能良好的绿色水处理化学品.