Sediment profile imaging (SPI) and micro-electrode technologies in impact assessment studies: Example from two fjords in Southern Chile used for fish farming

Two state-of-the-art techniques were used to assess the impact of organic loading from fish farming in two fjords of Southern Chile, Pillan and Reñihue Fjords. A sediment profile imaging (SPI) camera was deployed and sediment microprofiles (oxygen, H₂S, redox and pH) were measured in undisturbed sediment cores collected using a HAPS corer. Four out of seven stations in Pillan Fjord were found to be severely disturbed: SPI images showed azoic conditions (no apparent Redox Potential Discontinuity layer, no evidence of aerobic life form, presence of an uneaten fish food layer, negative OSI scores). These findings were corroborated by very high oxygen consumption rates (700–1200 mmol m^− 2 day^− 1), H₂S concentrations increasing quickly within the sediment column and redox potential decreasing towards negative values within a few mm down core. Results for Reñihue Fjord were not so straightforward. SPI images indicated that most of the stations (R3 to R7) presented well-mixed conditions (high apparent RPD layers, presence of infauna, burrows, etc.), but oxygen profiles yielded consumption rates of 230 to 490 mmol m^− 2 day^− 1 and organic carbon mineralization of 2.16 to 4.53 g C m^− 2 day^− 1. These latter values were close to the limit of aerobic degradation of organic matter although no visible changes were recorded within the sediment column. In view of our findings, the importance of integrating multidisciplinary methodologies in impact assessment studies was discussed.     

Adapting the light · biomass (BZI) models of phytoplankton primary production to shallow marine ecosystems

Several authors have reported a strong linear relationship between daily phytoplankton production and the product of chlorophyll biomass, photic depth, and incident irradiance for a variety of estuaries. This “light · biomass” (BZ_pI_o) formulation has been proposed as an alternative to traditional mechanistic approaches for computing phytoplankton production in numerical estuarine models. One limitation to their application in shallow systems is that the BZ_pI_o models have been developed in relatively deep estuaries where light does not reach the bottom. We propose a nonlinear correction factor to adapt the BZ_pI_o relationship to shallow systems where light does reach the bottom. Our function takes into account variations in incident irradiance, attenuation coefficient for light, photosynthetic efficiency, and maximum rate of photosynthesis. A series of correction polynomials are proposed for various ranges of incident irradiance, and are integrated into a single multiple polynomial which applies across all irradiance levels. Our new correction factor was tested against a ¹⁴C-based productivity dataset from shallow stations in Narragansett Bay, RI and an O₂-based dataset from shallow (1.1 m) lagoon mesocosms at the University of Rhode Island. Results showed that our polynomials accurately correct BZ_pI_o-predicted rates of production in shallow water columns. Application of our correction factor to a series of shallow water productivity datasets from the literature together with theoretical calculations show how significant the shallow water correction can be, especially in very shallow water columns with low turbidity.     

Fluxes of dissolved inorganic carbon in three estuarine systems of the Cantabrian Sea (north of Spain)

The diffusive and in situ fluxes of dissolved inorganic carbon (DIC) and total alkalinity (TA) have been measured and an estimation has been made of the water–atmosphere fluxes of CO₂ in three estuarine systems of the Cantabrian Sea during the spring of 1998. Each of these systems undergoes a different anthropogenic influence. The diffusive fluxes of dissolved inorganic carbon and total alkalinity obtained present values ranging between 0.54–2.65 and 0.0–2.4 mmol m⁻² day⁻¹, respectively. These ranges are in agreement with those of other coastal systems. The in situ fluxes are high and extremely variable (35–284 mmol TA m⁻² day⁻¹, 43–554 mmol DIC m⁻² day⁻¹ and 22–261 mmol dissolved oxygen (DO) m⁻² day⁻¹), because the systems studied are very heterogeneous. The values of the ratio of the in situ fluxes of TA and DIC show on average that the rate of dissolution of CaCO₃ is 0.37 times that of organic carbon oxidation. Equally, the interval of variation of the relationship between the benthic fluxes of inorganic carbon and oxygen (F_DIC/F_DO) is very wide (0.3–13.9), which demonstrates the different contributions made by the processes of aerobic and anaerobic degradation of the organic matter, as well as by the dissolution–precipitation of CaCO₃. The water–atmosphere fluxes of CO₂ present a clear dependence on the salinity. The brackish water of these systems (salinity<20), where maximum fluxes of 989 mmol m⁻² day⁻¹ have been estimated, act as a source of CO₂ to the atmosphere. The more saline zones of the estuary (salinity>30) act as a sink of CO₂, with fluxes between −5 and −10 mmol m⁻² day⁻¹.     

Benthic sediment composition and nutrient cycling in an Intermittently Closed and Open Lake Lagoon

Surfical sediments within Corunna Lake, a moderate size Intermittently Closed and Open Lake Lagoon (ICOLL), were examined for solid phase nutrient concentrations (TN, TP, TOC,) and solute exchange rates between the sediment and water column (O₂, NO₃–N, NH₄–N, FRP, and N₂). The surfical sediments in Corunna Lake contained high concentrations of TN (5 mg/g dry mass), total phosphorus (0.6 mg/g dry mass), and TOC (~ 5% dry mass). The carbon stable isotope ratio (δ¹³C) and TOC:TN ratios (δ¹³C ~ ? 24, TOC:TN ~ 11–14) demonstrated that the composition of the organic matter in the sediment was a mixture derived primarily of degraded planktonic matter. The close association between TP and Fe concentrations highlighted the potential role Fe plays in mediating Filterable Reactive Phosphorus (FRP) concentrations in the water column of Corunna Lake. In situ benthic chamber incubations were used to measure benthic fluxes. Solute exchange rates between the sediment and water column in Corunna Lake were similar to other reported studies (O₂ = ? 469 to ? 1765 µmol m^? 2 h^? 1, NH₄–N = 0.1–63 µmol m^? 2 h^? 1, NO₂/NO₃–N = 0 µmol m^? 2 h^? 1, FRP = ? 4–1.6 µmol m^? 2 h^? 1and N₂ = 12–356 µmol m^? 2 h^? 1). As more carbon was deposited and mineralized the efficiency of the bacterial population to denitrify nitrogen in the sediment decreases. The linkage between land use and benthic biogeochemistry was also explored. A dairy farm exists in the middle catchment of Corunna Lake, and the receiving bay sediment consistently demonstrated the highest oxygen consumption rates in winter and spring (? 1408 µmol m^? 2 h^? 1 in winter, ? 1691 µmol m^? 2 h^? 1 in spring) and lowest denitrification efficiencies during summer (~ 3%). Nitrate/nitrite fluxes were not observed during any of the chamber incubations, with the concentrations of nitrate/nitrite being below detection limits (< 10 μg/L). Seasonal changes influenced the rates of solute exchange between the sediment and water column. Critical measures of solute exchange for NH₄–N and biogenic N₂ indicated that seasonal temperature changes play a significant role in mediating the reaction rates of sedimentary based biogeochemical processes. Measurable FRP fluxes were small but greater in the benthic sediments which received higher carbon inputs. Sediments have a high capacity to adsorb P which is released as sediment oxygen demand increases as a result of increases in labile carbon loads.     

Remaining fatigue life assessment of corroded mooring chains using crack growth modelling

Failures caused by the combined actions of fatigue, corrosion and wear are important safety concerns for mooring chains used on floating structures in the oil and gas industry. Prediction of remaining corrosion fatigue life based on surface condition could therefore be a useful tool for the continued safe operation of corroded chains. This paper investigates the use of crack growth modelling for estimating the remaining corrosion fatigue life of mooring chains that exhibit significant pitting corrosion damage. A crack growth modelling approach is used to produce remaining fatigue life estimates for a selection of severely pitted mooring chains. Using fatigue crack growth rate test results for grade R4 high strength mooring chain steel, empirical crack growth laws are presented for free corrosion and cathodic protection conditions at load ratio R = 0.1. Two different methods for establishing equivalent cracks from surface scans of corrosion damage are presented. The mooring chains are proof loaded as part of their manufacturing process. Residual stresses introduced during this process have therefore been determined by finite element analysis and accounted for in the fatigue crack growth predictions. One of the equivalent crack models, accounting for the single dominant corrosion pit, provided quite accurate fatigue life predictions when compared with full scale test results.     

Is there any relationship between phytoplankton seasonal dynamics and the carbonate system?

Production of calcium carbonate by marine calcifying organisms has been shown to decrease under increasing CO₂. This effect appears to be driven by a decrease in [CO₃²⁻]. The modelling study here described aims at investigating whether the success of a marine calcifying phytoplankton species, the coccolithophore Emiliania huxleyi, may be tied to [CO₃²⁻]. The work highlights the complex interactions between the carbonate system variables and spring blooms, and the possibility of a link to the competition between calcifying vs. non-calcifying species on the Bering Sea shelf. We find that the strong seasonal cycle in [CO₃²⁻] is driven primarily by carbon drawdown during spring blooms. The interesting outcome of this work is the fact that E. huxleyi bloom timings always coincide with periods of high [CO₃²⁻], which is consistent with studies showing coccoliths malformations and a slowdown in calcification at low [CO₃²⁻]. Whether the condition of high [CO₃²⁻] can be considered a crucial ecological factor for the success of E. huxleyi, however, remains an open and important question needing further investigation.     

Estimation of air–sea CO2 fluxes in the Bay of Biscay based on empirical relationships and remotely sensed observations

An empirical algorithm has been developed to compute the sea surface CO₂ fugacity (fCO₂^sw) in the Bay of Biscay from remotely sensed sea surface temperature (SST_RS) and chlorophyll a (chl a_RS) retrieved from AVHRR and SeaWiFS sensors, respectively. Underway fCO₂^sw measurements recorded during 2003 were correlated with SST_RS and chl a_RS data yielding a regression error of 0.1 ± 7.5 µatm (mean ± standard deviation). The spatial and temporal variability of air–sea fCO₂ gradient (ΔfCO₂) and air–sea CO₂ flux (FCO₂) was analyzed using remotely sensed images from September 1997 to December 2004. An average FCO₂ of ? 1.9 ± 0.1 mol m^? 2 yr^? 1 characterized the Bay of Biscay as a CO₂ sink that is suffering a significant long-term decrease of 0.08 ± 0.05 mol m^? 2 yr^? 2 in its capacity to store atmospheric CO₂. The main parameter controlling the long-term variability of the CO₂ uptake from the atmosphere was the air–sea CO₂ transfer velocity (57%), followed by the SST_RS (10%) and the chl a_RS (2%).     

Fatigue crack growth behaviour of A5083 series aluminium alloys and their welded joints

We investigated the difference in fatigue behaviour between the aluminium alloys A5083-O and A5083-H321, which are used as structural components in ships and high speed craft. We obtained S–N curves for the base materials and the welded joints made of A5083-O. The relationships between the fatigue crack propagation rates and the stress intensity factor ranges ΔK, ΔK _eff and ΔK _RPG (Toyosada et al. in Int J Fatigue 26(9):983–992, 2004) were determined. Additionally, the evolution of fatigue crack growth for the base materials and the welded joints made of A5083-O was measured. We also carried out numerical simulations of fatigue crack growth for both base metals and their welded joints made of A5083-O. The difference in fatigue crack growth behaviour for each alloy and the validity of the numerical simulations of fatigue crack growth based on the RPG stress criterion (Toyosada et al. 2004) in the base materials and their welded joints was investigated.     

Quasi-simultaneous observation of currents,salinity and nutrients in the Changjiang (Yangtze River) plume on the tidal timescale

During both the spring- and the neap-tide periods of November 2005, quasi-simultaneous observations were carried out by six boats over 26 h at 12 stations in the Changjiang (Yangtze River) plume. The simultaneous observations provided the actual distribution isopleths of salinity and nutrients that displayed considerable intra-tidal variations at surface, especially in the southeastern section of the study area. The lack of synopticity in sampling might lead to large discrepancies of the interpolated contours of salinity from the actual distribution isopleths. No clear flood-ebb asymmetry of salinity stratification was observed; whereas at inner stations, surface-to-bottom bulk velocity difference (current layering) always tended to be greater during the ebb fraction of a semidiurnal cycle. At a given station, the weaker neap tides commonly induced stronger salinity stratification, less intra-tidal variability of salinity and nutrients, and less intrusion of bottom saltwater. Nutrients (SiO₃^2?, NO₃^?, and PO₄^3?) showed more nonconservative behaviors during the neap tides, presumably as a result of the prolonged residence time of seawater and decreased suspended particulate matter levels than during the spring tides.     

Seasonal study of dissolved CH4, CO2 and N2O in a shallow tidal system of the bay of Cádiz (SW Spain)

During 2004, 10 samplings were performed in order to measure dissolved methane (CH₄), carbon dioxide (CO₂) and nitrous oxide (N₂O) in the surface waters of Río San Pedro, a tidal creek in the salt marsh area of the Bay of Cádiz (SW Spain). The inner partvs of the creek is affected by the inputs coming from an intensive fish farm and the drainage of an extensive salt marsh area.Dissolved CH₄, CO₂ and N₂O concentrations ranged from 11 to 88 nM, 36 to 108 μM and 14 to 50 nM, respectively. Surface waters were in all cases oversaturated with respect to the atmosphere, reaching values of up to 5000% for CH₄, 1240% for CO₂ and 840% for N₂O. Dissolved CH₄, CO₂ and N₂O showed a significant tidal and seasonal variability. Over a tidal cycle, concentrations were always highest during low tide, which points to the influence of the inputs from the fish farm effluent and the drainage of the adjacent salt marsh area, as well as in situ production within the system. Dissolved CH₄, CO₂ and N₂O seasonal patterns were similar and showed maximum concentrations in summer conditions. Using four different parameterizations to calculate the gas transfer coefficients [Liss, P.S. and Merlivat, L., 1986. Air-sea exchange rates: introduction and synthesis. In P. Buat-Ménard (Ed.), The Role of Air-Sea Exchanges in Geochemical Cycling. Reidel, Dordrecht, The Netherlands, p. 113–127.; Clark, J.F., Schlosser, P., Simpson, H.J., Stute, M., Wanninkhof, R., and Ho, D.T., 1995. Relationship between gas transfer velocities and wind speeds in the tidal Hudson River determined by the dual tracer technique. In: B. Jähne and E. Monahan (Eds.), Air-Water Gas Transfer: AEON Verlag and Studio, Hanau, Germany, pp. 785–800.; Carini, S., Weston, N., Hopkinson, G., Tucker, J., Giblin, A. and Vallino, J., 1996. Gas exchanges rates in the Parker River estuary, Massachusetts. Biol. Bull., 191: 333–334.; Kremer, J.N., Reischauer, A. and D'Avanzo, C., 2003. Estuary-specific variation in the air-water gas exchange coefficient for oxygen. Estuaries, 26: 829–836.], the averaged air–water fluxes of CH₄, CO₂ and N₂O from the creek to the atmosphere ranged between 34 and 150 μmol CH₄ m^− 2 day^− 1, 73 and 177 mmol CO₂ m^− 2 day^− 1 and 24 and 62 μmol N₂O m⁻² day⁻¹, respectively.     

Prediction of wave parameters by using fuzzy inference system and the parametric models along the south coasts of the Black Sea

Forecasting of sea-state characteristics has a great importance in coastal and ocean engineering studies. Therefore, the purpose of this study was to investigate performances of Adaptive-Network-Based Fuzzy Inference System (ANFIS) and several parametric methods in the Black Sea. For this purpose, different fuzzy models with different input combinations were developed for two different wind data sources (TSMS and ECMWF) at two offshore buoy stations. It also aimed to apply several approaches to event-based data sets for wave predictions. Generally, in literature the tendency is to use time series data for wave predictions. In this kind of prediction approach, lagged time series data are taken as inputs and current or future variables are taken as output. In this study, event-based data for each independent storm were extracted from time series data. Simultaneous or concurrent data of wind speed, blowing duration, fetch length and wave characteristics were detected for each single storm. These event data were then used to set up models. The hindcast results were validated with significant wave height and mean wave period data recorded in Hopa and Sinop buoy stations. The performance of developed fuzzy models were also compared with that of four different parametric methods (Wilson, SPM, Jonswap, and CEM methods) applied for two wind data sources at both buoy stations. Finally, it was determined that in the prediction of both wave parameters (H _s and T _z) the ANFIS models (R = 0.66, squared correlation coefficient, and MAE = 0.37 m, mean absolute error, for the best model in prediction of H _s) were more accurate than the parametric methods (R = 0.63 and MAE = 0.75 m for the best model in prediction of H _s).     

Fatigue analysis of butt welded AH36 steel joints: Thermographic Method and design S–N curve

The traditional methods of fatigue assessment of welded joints have some limitations, and are extremely time consuming. In order to overcome these difficulties, the Thermographic Method (TM), based on thermographic analyses, has been applied to predict the fatigue behaviour of butt welded joints, made of AH36 steel, largely used in shipbuilding. Experimental tests have been carried out to assess the fatigue capability in terms of S–N curves and fatigue limits. The predictions of the fatigue capability obtained resorting to the Thermographic Method show a good agreement with those derived from the traditional procedure. Moreover, the fatigue design recommendations were compared to the experimental data in order to analyse the reliability of the codes.     

Hydrodynamic performance of multiple-row slotted breakwaters

This study examines the hydrodynamic performance of multiple-row vertical slotted breakwaters. We developed a mathematical model based on an eigenfunction expansion method and a least squares technique for Stokes second-order waves. The numerical results obtained for limiting cases of double-row and triple-row walls are in good agreement with results of previous studies and experimental results. Comparisons with experimental measurements of the reflection, transmission, and dissipation coefficients (C _R , C _T , and C _E ) for double-row walls show that the proposed mathematical model adequately reproduces most of the important features. We found that for double-row walls, the C _R increases with increasing wave number, kd, and with a decreasing permeable wall part, dm. The C _T follows the opposite trend. The C _E slowly increases with an increasing kd for lower kd values, reaches a maximum, and then decreases again. In addition, an increasing porosity of dm would significantly decrease the C _R , while increasing the C _T . At lower values of kd, a decreasing porosity increases the C _E , but for high values of kd, a decreasing porosity reduces the C _E . The numerical results indicate that, for triple-row walls, the effect of the arrangement of the chamber widths on hydrodynamic characteristics is not significant, except when kd<0.5. Double-row slotted breakwaters may exhibit a good wave-absorbing performance at kd>0.5, where by the horizontal wave force may be smaller than that of a single wall. On the other hand, the difference between double-row and triple-row vertical slotted breakwaters is marginal.     

KG<Subscript>max</Subscript> curves associated with second generation intact stability criteria for different types of ships

Currently, second generation intact stability criteria are being developed and evaluated by the International Maritime Organization (IMO). In this paper, we briefly present levels 1 and 2 assessment methods for the criteria of pure loss of stability and parametric roll failure modes. Subsequently, we show the KG_max curves associated with these criteria. We compute these curves for five different types of ships and compare them with the curves embodied in the current regulations. The results show that the safety margin ensured by the first level-1 method of calculation for both pure loss of stability and parametric roll seems to be excessive in many cases. They also show that the KG_max given by the second level-1 method and by the level-2 method may be very similar. In some cases, the level-2 method can be more conservative than the second level-1 method, which is unanticipated by the future regulation. The KG_max curves associated with parametric roll confirm that the C11 container ship is vulnerable to this failure mode. The computation of the second check coefficient of parametric roll level 2 (C2) for all possible values of KG reveals the existence of both authorized and restricted areas on the surface formed by both the draft and KG, which may replace the classical KG_max curves. In consequence, it is not sufficient to check that C2 is lower than the maximum authorized value (R _PR0) for a fixed ship’s loading condition.     

Analysis of corrosion risk due to chloride diffusion for concrete structures in marine environment

The chloride-induced steel corrosion is one of the main causes of deterioration for reinforced concrete structures exposed to marine environments. The chloride ingress into reinforced concrete structures is even more complex since it depends on random parameters linked to transport and chemical properties of materials, which results in variability of corrosion initiation. This variation raises the need of statistical approaches to evaluate the risk of corrosion initiation due to chloride ingress. To address this issue, we use sensitivity analysis to identify the influence of input parameters on critical length of time before corrosion initiation predicted by our chloride diffusion model. Exceedance probabilities of corrosion initiation time given that input parameters exceed certain thresholds were also calculated. Results showed that the corrosion initiation time was most sensitive to: chloride effective diffusion coefficient D_e in concrete, that is a parameter controllable by relevant stakeholders; surface chloride concentration C_s, a non-controllable parameter depending on surrounding conditions. Reducing the chloride diffusion coefficient enables us to postpone the maintenance of structures. However, the interaction between controllable parameters and non-controllable surrounding conditions was revealed influential on the reliability of results. For instance, the probability that corrosion initiation time exceeds 15 years given an effective diffusion coefficient (D_e) equal to 0.1 × 10⁻¹² m²⋅s-1 can vary from 19 to 41% according to stochastic variations of chloride concentrations (C_s) values. Postponing the corrosion initiation time was combined with a decreasing probability of its occurrence.     

Vortex-induced vibrations of piggyback pipelines near the horizontal plane wall in the upper transition regime

Slender subsea structures like pipelines, jumpers and umbilicals when exposed to currents may experience vortex-induced vibrations (VIV), which can shorten their fatigue life and increase the risk of structural failure. In the present study, flow around different configurations of a piggyback pipeline close to a flat seabed has been investigated using the two-dimensional (2D) Unsteady Reynolds-Averaged Navier Stokes (URANS) equations with the k − ω Shear Stress Transport (SST) turbulence model. The Reynolds number (based on the free stream velocity and large cylinder diameter) is equal 3.6 × 10⁶ corresponding to upper-transition regime. The drag forces acting on the cylinders and base pressure coefficient value are well predicted by the present simulations, while the other hydrodynamic quantities (root-mean-square lift coefficient, Strouhal number) are predicted reasonably well as compared to published experimental data. The piggyback pipeline in the present study is modeled as two circular cylinders with a diameter ratio d/D = 0.2 (D denoting diameter of the large cylinder, d is diameter of the small cylinder). These two cylinders are clamped together at a distance G/D = 0.2. The two rigidly coupled cylinders are elastically supported and free to vibrate in two degrees of freedom. The effects on the vibration amplitudes and hydrodynamic forces are analyzed. The flow structures around the cylinders are investigated to explain the variations in observed structural responses. Depending on the angular position (α) of the small cylinder, the lock-in regime is narrower (α = 0°) or significantly wider (α = 180°) when compared to that of a single cylinder.     

Monitoring trace elements (Al, As, Cr, Cu, Fe, Mn, Ni and Zn) in deep and surface waters of the estuary of the Nerbioi-Ibaizabal River (Bay of Biscay, Basque Country)

Deep water samples (in contact with the sediment) were collected at eight different points of the estuary of the Nerbioi-Ibaizabal River (Bay of Biscay, Basque Country), both at low and high tides, during four sampling campaigns (May, September and December 2005 and March 2006). Superficial water was also sampled in March 2006. Temperature, pH, redox potential, dissolved oxygen and electrical conductivity corresponding to each sample were measured in situ at each sampling point using a multiparametric probe. The physico-chemical parameters found are typical of highly stratified estuaries, with an acceptable oxygenation level. After filtering and acidifying the samples, they were analysed by inductively coupled plasma/mass spectrometry (ICP/MS) to simultaneously determine the total concentration of Al, As, Cr, Cu, Fe, Mn, Ni and Zn. Concentrations in the μg kg^− 1 level were found in all cases (c_Cr and c_Ni, 1–10; c_Al, c_As and c_Zn, 10–50; c_Cu and c_Mn, 10–100 and c_Fe, 100–400 μg kg^− 1). A probable net input of Al, Cr, Mn and Zn via the main (Nerbioi-Ibaizabal) and some of the tributary rivers (Galindo, Asua and Gobela) was identified. Evidence of a common source of Al and Zn to the estuary was found. Correlation analysis of data revealed connections between variables (concentration of Cu, Fe and As with salinity, as well as c_Al with c_Zn, c_Cu with c_Fe, c_As with c_Fe, and c_As with c_Cu). Principal Component Analysis (PCA) of data allowed the samples to be grouped according to sampling campaign, with two principal components accounting for 62% of the total variance. In addition, plots of element concentration against salinity suggested a conservative behaviour for As, Cu and Fe and a non-conservative one for Cr. Not clear mixing behaviour was observed for the rest of elements.