分散剂用量对α-Al(OH)_3合成的影响

以Al(NO3)_3及NH_3·H_2O为原料,采用化学沉淀法在不同PEG分散剂用量的情况下制备α-Al(OH)_3纳米颗粒,并通过FSEM与BET的表征方法对样品进行了表征。结果表明,随着PEG分散剂用量的增大,合成得到的α-Al(OH)_3纳米粉体的粒径先减小后增大,原料硝酸铝溶液的浓度为0.1 mol/L,当PEG分散剂用量为0.5 g时,制备得到的α-Al(OH)_3颗粒粉体的平均粒径达最小约为100 nm,此时的团聚现象也较少。     

络合沉淀法制备纳米Co3O4的工艺研究

以Co(NO3)2·6H2O等钴盐,NH3·H2O,H2O2和NaOH为原料,采用络合沉淀法在水溶液中直接制备出了纳米Co3O4,通过X射线衍射仪(XRD)和扫描电镜(SEM)等观测,讨论了不同反应物、反应物之间的摩尔比和反应温度等制备条件对反应产物组成和结构的影响.研究结果表明本制备工艺能够制得纯度高,分散性能好,颗粒分布均匀,结晶度较高的球形纳米Co3O4.纳米Co3O4的最佳制备工艺条件[Co(NH3)6](NO3)3与Co(NO3)2 的摩尔比为2.5～31,NaOH 与Co(NO3) 2的摩尔比为0.9～1.21,反应温度为80℃.     

Al2O3(Pt)修饰SnO2气体传感器的制作及性能分析

论述了以共溶溶胶凝胶法,半透膜渗析技术,合成了SnO2纳米粉体.采用旁热式结构,制成了Al2O3(Pt)修饰SnO2双层膜的气体传感器.实验结果表明,Al2O3(掺3%Pt)修饰SnO2双层膜气体传感器对甲烷有好的选择性和较高的灵敏度,在5000ppm时灵敏度最高可达到5倍以上.     

固相法制备新型吖啶橙-磷钼酸电荷转移配合物

以Keggin结构磷钼酸和吖啶橙为原料，采用室温固相合成法合成一种新型电荷转移配合物[C17H19N3]2，H3PMo12o40·H2O,通过元素分析，FTIR，UV—vis，XPS，TG等方法对合成的配合物进行了表征．结果表明：杂多酸与吖啶橙之间存在着电荷转移相互作用，形成电荷转移配合物后，杂多阴离子仍保持Keggin结构，但由于受给体的影响，杂多阴离子的4个特征IR峰有不同程度的红移或蓝移．     

臭氧对船舶废气中氮氧化物的氧化试验研究

用管式反应器试验研究了反应温度、[O3]/[NO]对臭氧氧化NO的影响.结果表明,O3/N2/O2体系在常温、200℃、275℃下均不发生反应,N2不能被O3氧化;在O3/NO/N2/O2体系中,NO主要氧化为NO2,只有1～6(10-6)其他氮氧化物生成.如N2O and N2O3.当[O3]/[NI]=1、反应温度分别为常温和200℃时,NO氧化率都达到100%,而在275℃时,NO氧化率只有72%.表明反应温度影响显著,其原因主要与较高温度下O3分解加快有关.O3在不同温度下的分解试验发现,O3在常温下分解很慢;200℃时分解加快,在反应器中停留9 S时,O3的分解率为59%,而275℃时分解更快,在反应器中停留9 s时,O3的分解率为80%.试验结果还表明,NO氧化率与[O3]/[NO]成线性关系.     

溶剂热法制备纳米α-Fe2O3

以Fe(acac)3为单源前驱体,聚乙烯醇为表面活性剂,在不同溶剂条件下,采用溶剂热合成方法成功地制备了α-Fe2O3纳米颗粒,并用X-射线衍射(XRD)、能量分散谱仪(EDS)、扫描电镜(SEM)、透射电镜(TEM)和选区电子衍射(SAED)等测试手段对产物进行了表征。研究结果表明:以无水乙醇为溶剂所制得的α-Fe2O3平均颗粒尺寸为10 nm,粒径分布均匀;以正丁醇为溶剂所制得的α-Fe2O3纳米颗粒呈球形,平均颗粒尺寸为40 nm。     

K_2CO_3/AC常温下脱除密闭空间CO_2反应机理

密闭空间CO2脱除是环境控制和生命保障系统的重要任务,研究适用于密闭空间高活性可再生CO2清除剂至关重要。本文利用热重分析系统对钾基负载型吸收剂K2CO3/AC(AC为活性炭)进行实验。在20℃,1%CO2和2%H2O基准工况下,对比吸收剂和载体AC的反应特性,探索K2CO3/AC常温下脱除密闭空间CO2反应机理,并探究温度、CO2浓度和H2O浓度等反应条件对脱碳特性影响。结果表明:载体AC对H2O和CO2脱除机制为物理吸附作用;K2CO3/AC主要依靠活性组分K2CO3与二者的化学反应,在H2O气氛中通过水合反应迅速转化为K2CO3·1.5H2O,在CO2/H2O气氛中通过碳酸化反应生成KHCO3,表现出优越的反应活性。K2CO3/AC的碳酸化反应性能随着温度升高而减弱,随着CO2浓度和H2O浓度增加而增强。该研究结果确定了K2CO3/AC常温下脱除低浓度CO2反应机理,为常温下密闭空间CO2脱除技术提供了理论基础。     

一种新型金属有机骨架化合物［Co3（Hbdc）2（bdc）2］·4DMF·2H2O的合成、表征与晶体结构

以柱状二齿配体吡嗪和对苯二甲酸（H2bdc）为混合配体,在溶剂热条件下与过渡金属离子Co2＋组装反应,得到一个新型金属有机骨架化合物[Co3（Hbdc）2（bdc）2]·4DMF·2H2O （1）．通过红外光谱、热重和单晶X射线衍射等分析手段对其进行了表征与分析．结果表明,化合物1的晶体属单斜晶系,空间群为C2/c．中心Co原子通过不同配位模式的bdc配体相连构成三维开放结构,孔道内填充了结晶的DMF和水分子．     

Nd2O3掺杂钛酸锶钡基陶瓷介电性能及微观形貌研究

采用传统固相法制备了Nd2O3掺杂(Ba0.7Sr0.3)TiO3基电容器介质陶瓷,研究了不同Nd2O3掺杂含量以及烧结时间对体系微观形貌及介电性能的影响.结果表明:适量Nd2O3掺杂有利于提高体系室温相对介电常数并降低室温介电损耗且随Nd2O3添加量增大,(Ba0.7Sr0.3)TiO3基陶瓷部分晶粒异常长大.(Ba0.7Sr0.3)TiO3基陶瓷居里温度随Nd2O3添加量增大向低温方向移动.随着烧结时间延长,Nd2O3改性的(Ba0.7Sr0.3)TiO3基陶瓷平均粒径显著增大,体系室温相对介电常数显著提高,而室温介电损耗降低.由于粒界缓冲作用减弱,(Ba0.7Sr0.3)TiO3基陶瓷相对介电常数及介电损耗的温度稳定性随烧结时间增长有所降低.     

氧烛隔热结构的设计

氧烛在放氧过程中,外壁表面温度会超过300 ℃.为保证氧烛的使用安全,需设计合理的隔热结构.试验证明,将氧烛外壳设计成夹套式结构,在夹套内填充一定量的Al2(SO4)3·18H2O,或将氧烛放在夹套式结构的防护筒内使用,在夹套内填充二氧化硅气凝胶,都能将氧烛的外壁温度控制在安全温度以内.     

Errata

正In the paper"Influence of Fouling Assemblage on the Corrosion Behaviour of Mild Steel in the Coastal Waters of The Gulf of Mannar,India"in Vol.12,No.4,Page:509,References were lost,and the two authors’biographies were identical.The correct text is shown below.We apologize to the authors and our readers for any inconvenience caused by the errors.     

Journal of Marine Science and Application 2014 Sum. Contents

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第34届海洋、离岸及极地工程国际会议(英文)

正St.John's,Newfoundland,Canada,May 31-June 5,2015 OMAE2015 is the ideal forum for researchers,engineers,managers,technicians and students from the scientific and industrial communities from around the world to: meet and present advances in technology and its scientific support;     

联合作战计划和执行系统

全球指挥控制系统(GCCS)实施当前美国海军网络中心战信息基础设施的联合计划网络。联合作战计划和执行系统(JOPES)支持GCCS实现联合计划。JOPES有两类计划：时间不限的精密预案计划生成作战计划、方案计划或职能计划；时间敏感的危机行动计划生成作战命令或战役方案。前者在和平时期创建的作战计划是后者的计划基础，加速应付危机的能力。     

Eastbound or westbound ?

In terms of equal sailing distances, where is the inflexion when ships depart from ports in the Asian Continent to New York via Suez and/or Panama？
The answer is China South Port Group （Hong Kong, Shenzhen and Guangzhou）.     

Recent progress on wave induced loading measurements in warships

Recent measurements of wave induced hull strain and flexure in RN warships are presented together with the derivation of the current design criteria for extreme hull girder bending loads. The history of the development of the shipboard instrumentation used is given and recent developments to improve the quality and ease of analysis of the data are described. An unexpectedly high transverse asymmetry in the longitudinal strains measured in destroyers is shown to be the result of a combination of vertical and lateral bending in oblique seas. Finally recent theoretical comparisons between the loading of Deep-Vee hulls and conventional UK rounded bilge hulls are presented which demonstrate the higher loading experienced by this type of hull form.     

桥梁防撞设施物理模型试验

物理模型试验是预报防撞设施所受撞击力及优化设计方案的主要方法之一。结合杭州湾大桥柔性防撞设施及东海大桥独立式防撞体设计方案,阐述了船—防撞体撞击试验的基本原理、方法、试验方案及相关试验结果。提出了柔性防撞系统的优化方案。试验结果表明,该方案经济有效,可供预报类似桥梁防撞设施撞击力时参考。     

印尼某电厂码头水工建筑物设计

印尼某电厂项目码头水工建筑物包括码头、防波堤和护岸等主要组成部分。在该项目水工建筑物的设计过程中,综合考虑当地的自然条件、施工能力和材料来源等因素,不断优化结构选型和结构断面。根据不同使用要求,护岸分别采用直立式和斜坡式2种结构型式,推荐的设计方案节省投资、施工方便,可供同类工程设计参考。     

Impact of regulation on the performances of long-distance transport services: A comparison of the different approaches in Sweden and Norway

Despite the many socio-economic similarities between Sweden and Norway, differences in jurisdiction, organisation, cooperation, and financing of long-distance passenger train and coach services have led to the development of four distinctively different ways of serving the markets. This paper describes how the train and coach markets have developed in the two countries, with emphasis on regulatory and industrial structure and a couple of performance variables.Looking at passenger rail, both countries separated infrastructure from operation over a decade ago. However, while Norwegian rail is characterised by an almost monopoly supplier, rail services in Sweden are partly decentralised to the responsibility of county authorities and are widely subjected to competitive tendering. The rest of the network is about to be opened up for on-the-track competition. Swedish Rail (SJ) has spent the last decades consolidating its core business (passenger rail) and sold out its other businesses. In contrast, the Norwegian state rail (NSB) has expanded its business to become a major bus operator and property owner, with extensions also into the Swedish market.The coach industry was more recently deregulated in both countries. The Swedish coach market is dominated by privately owned companies operating services to and from Stockholm. In Norway, state-owned NSB is a major coach operator on medium distance routes, and is also the largest partner of Nor-Way Bussekspress which totally dominates long-distance coach services. Further, the Norwegian coach market is characterised by cross-ownership and cooperation which has enabled an extensive route network which covers most of Norway.We find distinct differences in achievements in the two modes and in the two countries. Swedish rail services have succeeded in winning market shares and in renewing and developing both infrastructure and service levels to a greater extent than the Norwegian model. On the other hand, the Norwegian coach market seems to be more developed and efficient compared to its Swedish counterpart.The paper concludes with a discussion on the possible links between the different approaches and the performance observed, with the aim to stimulate further and more detailed research on some important issues.     

开放式数据挖掘系统模型

目前国内已经出现了少量的数据挖掘相关产品。国内数据挖掘软件无论从数量还是质量上比较，都与国外软件存在着较大的差距。随着数据仓库技术的普及，数据挖掘应用的需求越来越强烈，如何缩短这种差距，研发数据挖掘软件产品成为国内业界的一个重要问题。通过引用目前国际通用数据挖掘标准技术来构建开放式的数据挖掘系统模型，该系统模型从可扩展性、可重用性、易用性等方面得到了加强。