Carbonate chemistry dynamics and carbon dioxide fluxes across the atmosphere–ice–water interfaces in the Arctic Ocean: Pacific sector of the Arctic

Climatic changes in the Northern Hemisphere have led to remarkable environmental changes in the Arctic Ocean, which is surrounded by permafrost. These changes include significant shrinking of sea-ice cover in summer, increased time between sea-ice break-up and freeze-up, and Arctic surface water freshening and warming associated with melting sea-ice, thawing permafrost, and increased runoff. These changes are commonly attributed to the greenhouse effect resulting from increased atmospheric carbon dioxide (CO₂) concentration and other non-CO₂ radiatively active gases (methane, nitrous oxide). The greenhouse effect should be most pronounced in the Arctic where the largest air CO₂ concentrations and winter–summer variations in the world for a clean background environment were detected. However, the air–land–shelf interaction in the Arctic has a substantial impact on the composition of the overlying atmosphere; as the permafrost thaws, a significant amount of old terrestrial carbon becomes available for biogeochemical cycling and oxidation to CO₂. The Arctic Ocean's role in determining regional CO₂ balance has been ignored, because of its small size (only  4% of the world ocean area) and because its continuous sea-ice cover is considered to impede gaseous exchange with the atmosphere so efficiently that no global climate models include CO₂ exchange over sea-ice. In this paper we show that: (1) the Arctic shelf seas (the Laptev and East-Siberian seas) may become a strong source of atmospheric CO₂ because of oxidation of bio-available eroded terrestrial carbon and river transport; (2) the Chukchi Sea shelf exhibits the strong uptake of atmospheric CO₂; (3) the sea-ice melt ponds and open brine channels form an important spring/summer air CO₂ sink that also must be included in any Arctic regional CO₂ budget. Both the direction and amount of CO₂ transfer between air and sea during open water season may be different from transfer during freezing and thawing, or during winter when CO₂ accumulates beneath Arctic sea-ice; (4) direct measurements beneath the sea ice gave two initial results. First, a drastic pCO₂ decrease from 410 μatm to 288 μatm, which was recorded in February–March beneath the fast ice near Barrow using the SAMI-CO₂ sensor, may reflect increased photosynthetic activity beneath sea-ice just after polar sunrise. Second, new measurements made in summer 2005 beneath the sea ice in the Central Basin show relatively high values of pCO₂ ranging between 425 μatm and 475 μatm, values, which are larger than the mean atmospheric value in the Arctic in summertime. The sources of those high values are supposed to be: high rates of bacterial respiration, import of the Upper Halocline Water (UHW) from the Chukchi Sea (CS) where values of pCO₂ range between 400 and 600 μatm, a contribution from the Lena river plume, or any combination of these sources.     

A high order linear model for the prediction of internal lee waves at the main sill of the Strait of Gibraltar

A linear theory for the physical fields in the water column under the action of large amplitude internal lee waves at the main sill of the Strait of Gibraltar is developed. The procedure is a combination of the perturbation and normal modes methods in order to study steady resonant conditions. The lowest order linear approach of the methodology resumes the Taylor–Goldstein equation, which can reconstruct the main features of the observed fields but the high order approach gives the finest structure and sometimes the largest contributions. The role of the non-linear terms is investigated up to the second order taking into account the non-linear interactions between modes, leading to an effective reconstruction of the whole water column for the velocity field.     

Biochemical composition of marine sediment from the eastern Weddell Sea (Antarctica): High nutritive value in a high benthic-biomass environment

Within the SCAR's international EASIZ programme, as part of the benthic–pelagic coupling experiment, grain size and organic matter contents in marine surface sediment were measured. Samples were taken during the austral autumn of 2000 from 3 regions in the eastern Weddell Sea: Kapp Norvegia, Four Seasons Bank, and Austasen.In general, sediments were fine sand with a grain size fraction < 200 μm representing more than 40% of the total weight. The sediments from Four Seasons Bank (64 to 107 m depth) were coarser than those from Austasen and Kapp Norvegia (209 to 480 m depth), presumably due to winnowing of fine sediment at shallow depths. Organic carbon (OC) content ranged from 0.25% to 1.2% and constituted 10% to 97% of the total carbon. The samples from Kapp Norvegia presented the highest OC values. Overall, protein (PRT), lipid (LPD), and carbohydrate (CHO) contents were similar to those in sediment from cold regions (e.g., the North Atlantic and the Ross Sea) but higher than those in sediment from other Antarctic and more septentrional regions (e.g., the Ross Sea and the Mediterranean). The difference within the Antarctic is explained through the local conditions in Terra Nova Bay and Kapp Norvegia. In the Antarctic, PRT and LPD carbon were the main contributors to the biopolymeric carbon (BPC). In the eastern Weddell Sea shelf, the BPC accounted for more than 90% of the OC in most of the samples. More than 82% of the total PRT, LPD, and CHO were present in the fraction < 200 μm. This work remarks the existence of sediments with a high nutritional value persistent several weeks after the spring–summer pulse of fresh organic matter. It is also highlighted the high potential availability of these sediments (due to its grain size) for the benthic communities inhabiting this high-latitude continental shelf.     

Using a random displacement model to simulate turbulent particle motion in a baroclinic frontal zone: A new implementation scheme and model performance tests

Numerical artifacts can limit accurate simulation of turbulent particle motion when Lagrangian particle-tracking models are implemented in hydrodynamic models with stratified conditions like fronts. Yet, modeling of individual particle motion in frontal regions is critical for understanding sediment dynamics as well as the transport and retention of planktonic organisms. The objective of this research was to develop a numerical technique to accurately simulate turbulent particle motions in a particle-tracking model embedded within a hydrodynamic model of a frontal zone. A new interpolation scheme, the ‘water column profile’ scheme, was developed and used to implement a random displacement model for turbulent particle motions. A new interpolation scheme was necessary because linear interpolation schemes caused artificial aggregation of particles where abrupt changes in vertical diffusivity occurred. The new ‘water column profile’ scheme was used to fit a continuous function (a tension spline) to a smoothed profile of vertical diffusivities at the x–y particle location. The new implementation scheme was checked for artifacts and compared with a standard random walk model using (1) Well Mixed Condition tests, and (2) dye-release experiments. The Well Mixed Condition tests confirmed that the use of the ‘water column profile’ interpolation scheme for implementing the random displacement model significantly reduced numerical artifacts. In dye-release experiments, high concentrations of Eulerian tracer and Lagrangian particles were released at the same location up-estuary of the salt front and tracked for 4 days. After small differences in initial dispersal rates, tracer and particle distributions remained highly correlated (r = 0.84 to 0.99) when a random displacement model was implemented in the particle-tracking model. In contrast, correlation coefficients were substantially lower (r = 0.07 to 0.58) when a random walk model was implemented. In general, model performance tests indicated that the ‘water column interpolation’ scheme was an effective technique for implementing a random displacement model within a hydrodynamic model, and both could be used to accurately simulate diffusion in a highly baroclinic frontal region. The new implementation scheme has the potential to be a useful tool for investigating the influence of hydrodynamic variability on the transport of sediment particles and planktonic organisms in frontal zones.     

Environmental changes in the western Black Sea related to anthropogenic and natural conditions

The Black Sea northwestern shelf (NWS) ecosystem has been subjected to the strongest anthropogenic pressure of the entire Black Sea as about 80% of the freshwater runoff is discharged there.This paper presents a review of the global environmental changes related mainly to increased eutrophication in the western Black Sea basin.A case study (CoMSBlack 92a cruise) attempts to highlight the interaction of some natural and anthropogenic factors responsible for specific chemical and biological features in the western Black Sea environment. The significance of processes located near the Danube river mouth, which, due to their relatively small space scale, have not been recognized before, is clarified. Hydrological processess of specific importance to the distribution and transformation of antropogenic inputs are river plume dynamics, coastal upwelling and mixing and downwelling over the shelf break and slope in this part of the basin. A layer of low hydrological variability (“conservative layer”) appears to be a natural feature of the area, hypothesized to precondition specific biological and chemical processes there.The results suggest that the interplay between the Danube anthropogenic nutrient load with the natural hydrological fronts and gradients provides opportunities for enhanced biological activity thus contributing to the global environmental changes in the Black Sea NWS.     

Lagrangian flow in the California Undercurrent, an observation and model comparison

During the period 1992–1998, 38 isobaric RAFOS floats were deployed to sample the subsurface flow of the California Undercurrent. The deployments, released over the California continental slope west of San Francisco, have sampled robust year-round poleward subsurface flow associated with the Undercurrent most seasons and the combined inshore current and Undercurrent in winter. Two other types of flow have been seen: a region of weak flow with little net displacement just west of the California Undercurrent, and an active westward propagating eddy field. This eddy field appears to be the primary mechanism for moving floats from the Undercurrent into the ocean interior. The observations and statistics from the RAFOS floats are compared with Lagrangian estimates of particles tracked in a global high resolution ocean simulation in order to evaluate the fidelity of the model along an eastern boundary. The results show that the model reproduces the general character of the flow reasonably well, but underestimates both the mean and eddy energies by a substantial amount.     

A study of factors influencing the severity of road crashes involving drunk drivers and non drunk drivers

In this study, an attempt has been made to develop Multinomial Logit (MNL) model by analysing the drunken and non drunken drivers involved in road crashes on Indian highways. Multinomial Logit model has been deployed to assess the influence of various parameters like vehicular, environment and geometric factors on the set of drivers who were found to be drunk at the time of getting involved in the road crash and those who were not under the influence of alcohol at the time of meeting with the road crash. The total economic cost of road crashes in the case of non-drunk driver road crash is Rs. 1046.27 million whereas in the case of drunk driver road crashes it is estimated to be Rs. 204.50 million. Further, it can be observed that economic cost of drunk driver road crashes is varying from 13 to 19 % across different types of road crashes.     

The compressive behavior of advanced double hull structure—A review of current research at David Taylor

It has long been recognized that the compressive behavior of primary ship structural components plays a vital role in the design of surface ship hulls. This is equally as true for the new advanced double hull concept as it is for the more conventional surface ship configurations. What is different, however, is the nature of the structural mechanics phenomena which must be addressed due to the double hull's more radical departure from conventional design and construction practices. With increasing interest and attention being shown in this new concept, the David Taylor Model Basin has over the past few years initiated a number of research efforts which have and are continuing to address various aspects of the behavior of double hulls and their components to primary compressive loadings. These studies have as their ultimate goal the development of practical, user oriented design methods for double hull structure and as such currently focus on more approximate, rather than mathematically rigorous, approaches to the various structural phenomena being considered. This paper is in essence a progress report on a selected number of these efforts and describes the results achieved to date as well as the ongoing efforts and those planned for the future. This report focuses primarily on three recent studies: (1) a preliminary look at the relative significance of local versus general instability failure of double hull structure; (2) small scale experimental analysis of double hull sections using rigid vinyl modelling; and (3) the application of beam-on-elastic-foundation analysis methods for high aspect stiffened plates as it relates to double hull structure. In addition to these major topics, the report also includes a brief discussion of other ongoing and planned efforts relevant to the advanced double hull.     

The continental shelf and the exclusive economic zone: the problem of delimitation at UNCLOS III

If the Third United Nations Conference on the Law of the Sea succeeds in adopting a new Caracas Convention on the Law of the Sea, it is likely to embody detailed provisions on the delimitation of both the continental shelf and the new zone, the exclusive economic zone. In this paper, the most recent draft of these rules—contained in the Revised Single Negotiating Text—is subjected to a detailed and critical scrutiny which leads to the conclusion that the Sixth Session of the Conference still has a great deal of work to do before agreement can be reached on a satisfactory set of rules.