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931.
菜籽油生物柴油化学动力学机理的构建   总被引:1,自引:0,他引:1  
采用气‐质联用仪测量了以菜籽油为原料制备的生物柴油的酯类组成成分和比例,根据主要组分的分子式和含量,拟合得到生物柴油的分子式。确定了以丁酸甲酯和正庚烷组成的混合燃料来替代生物柴油,采用“叠加法”构建得到一种新的生物柴油化学动力学机理。通过对影响主要污染物生成的基元反应进行敏感性分析,筛选出新机理中需要修正的基元反应。调整指前因子修正化学反应速率常数,模拟不同扰动下CO2和C2 H4的摩尔分数,分析模拟结果与试验结果的平均误差。研究结果表明:生物柴油的拟合分子式为C19 H36 O2;丁酸甲酯和正庚烷组成的混合燃料在分子式、分子量、黏度等方面较丁酸甲酯与实际的生物柴油更为接近,可用来替代生物柴油;在指前因子略增大的扰动下,新机理计算的CO2和C2 H4摩尔分数的平均误差均较小。  相似文献   
932.
This paper presents a novel approach to apply the physiological signal of the human brain to the sound quality evaluation of automotive sound. In the previous work, psychoacoustic metrics were applied to the sound quality evaluation of automotive sound. Loudness among psychoacoustic metrics is used for one of major sound metrics for the objective evaluation of the sound quality of the acceleration sound inside a car. Subjective evaluation of the sound quality of the acceleration sound shows different results depending on the two different groups of participants. One group liked powerful sound when a car is accelerated: the other group liked the refine sound. Loudness of the acceleration sound is not correlated with the subjective rating of the former group whilst it is correlated with that of the latter group. This evaluation suggests that for the people who like the powerful acceleration sound, it needs to find the sound metric for the objective evaluation of the sound quality of the acceleration sound. In this paper, a driver’s brain signal is measured using electroencephalography (EEG) when a driver hears the acceleration sound of passenger cars. The signal is analyzed to obtain the relationship between brain signals and human perception. According to these results, the alpha wave correlates to the human perception of powerful sound quality of passenger cars. This interesting relationship can be used for objective evaluation of passenger car sounds.  相似文献   
933.
Spray sizing that records fluorescent emission and scattered light has been widely applied to spray diagnostics over the last two decades. Different experimental strategies have been developed, but comparing the different solutions offered has remained of interest to experimentalists. In this work, a comparison of two fluorescence strategies for measuring droplet size in the liquid phase of a last-generation DI diesel spray is conducted. The natural fluorescent emission of a commercial diesel fuel and the fluorescence emitted by a tracer (Rhodamine B) are compared using theoretical and experimental approaches. The LIF/Mie ratio commonly called Planar Droplet Sizing (PDS) technique is applied in two different ways to elucidate the possible advantages of using a fluorescent dopant. The sprays were injected under non-evaporative conditions into a constant pressure vessel that simulates densities present at the moment of injection in currently used passenger car diesel engines. Characterization of the signal properties was performed by measuring the absorption coefficient, fluorescence emission spectrum, quantum yield and lifetime of both configurations. The scattered light and fluorescence intensities were calculated to verify the dependencies of the droplet surface and volume. When applying the two techniques to quantify droplet size in dense diesel sprays, the results show that signal weakness and lack of control over the properties of natural fluorescence produce distortion in the shape of the spray and cause measurements to be unreliable.  相似文献   
934.
A lot of high-speed lines are planned all around the world. Economic and politic stakeholders of the served areas expect a lot of positive effects in terms of local economic development. If it is not always the case, some local economic dynamic indirectly linked to high-speed rail service (HSRS) can exist in some areas and in some conditions. The aim of this paper is to put in evidence the heterogeneity of the wider effects of a HSRS according to places. Using innovation theories, which underline the coproduction of services, we analyze the arrival of a HSRS in an area as a set of innovation services. We put forward that these innovations are different according to the countries and to the local areas. It is a first level of heterogeneity. Furthermore, potential use and appropriation of innovations linked to HSRS by local stakeholders which depend on the characteristics of the area are very different. This is a second level of heterogeneity. Finally, we put forward that the appropriation depends on the kind of strategies of the stakeholders. This is the third level of heterogeneity. Consequently, we underlined the necessity to go beyond the analysis of HSRS effects because the link between HSRS and local economic development is based on a coproduction.  相似文献   
935.
The present paper discusses the modeling of tool geometry effects on the friction stir aluminum welds using response surface methodology. The friction stir welding tools were designed with different shoulder and tool probe geometries based on a design matrix. The matrix for the tool designing was made for three types of tools, based on three types of probes, with three levels each for defining the shoulder surface type and probe profile geometries. Then, the effects of tool shoulder and probe geometries on friction stirred aluminum welds were experimentally investigated with respect to weld strength, weld cross section area, grain size of weld and grain size of thermo-mechanically affected zone. These effects were modeled using multiple and response surface regression analysis. The response surface regression modeling were found to be appropriate for defining the friction stir weldment characteristics.  相似文献   
936.
Lean burn is an effective way to improve spark ignition engine fuel economy. In this paper, the combustion and emission characteristics of a lean burn natural gas fuelled spark ignition engine were investigated at various throttle positions, fuel injection timings, spark timings and air fuel ratios. The results show that ignition timings, the combustion duration, the coefficient of variation (COV) of the indicated mean effective pressure (IMEP) and engine-out emissions are dependent on the overall air fuel ratio, spark timings, throttle positions and fuel injection timings. With the increase of the air fuel ratio, the ignition delays and combustion duration increases. Fuel injection timings affect ignition timings, combustion duration, IMEP, and the COV of the IMEP. Late fuel injection timings can decrease the COV of the IMEP. Moreover, the change in the fuel injection timings reduces the engine-out CO, total hydrocarbon (THC) emissions. Lean burn can significantly reduce NOx emissions, but it results in high cyclic variations.  相似文献   
937.
The objective of this experimental study is to investigate the characteristics of the size distribution and the number concentration of PM (particulate matters) emitted from the diffusion flame of a boiler burner, which has the same type of combustion as a diesel engine. This study is performed to investigate the emission characteristics of nanoparticles generated from diffusion combustion in diesel fuel, and it considered fuel factors and the reaction characteristics of the nanoparticles on the DOC (Diesel oxidation catalyst). The factors examined in this experiment included the sulfur content in the fuel, the blend of the diesel fuel containing biodiesel and bio-ethanol, and the concentration of engine oil (0.1% and 1.0%) blended with diesel fuel. The particle size distribution of the nanoparticles exhausted from the boiler burner was measured by an SMPS (scanning mobility particle sizer). The number concentration of PM that were smaller than 70 nm in diameter greatly increased in the rear of the DOC when fuel containing 250 ppm of sulfur was used. The experiment also suggested that the particle number concentration in both the front and rear of the DOC was lower when ULSD (ultra low sulfur diesel) fuel blended with biodiesel and bio-ethanol, which are oxygenated fuels, was used than when only ULSD fuel was used. The higher the content of engine oil in the fuel, the higher the particle number concentration was in the front and rear of the catalyst. When the first dilution air temperature is increased from 30°C to 180°C, the nanoparticle number concentration dramatically dropped in the rear of the catalyst when fuel containing 250 ppm of sulfur was used, while the particle size distribution remained almost the same when the fuel with engine oil was used.  相似文献   
938.
The objective of this work was to investigate the effects of injection conditions and swirl on D.I. diesel combustion using a transparent engine system. The test engine is equipped with a common rail injection system to control injection conditions and to obtain split injection characteristics. A combustion analysis and steady flow test were conducted to measure the heat release rate due to cylinder pressure and the swirl ratio. In addition, spray and diffusion flame images were obtained using a high speed camera. The LII & LIS methods were also used to obtain 2-D soot and droplet distributions. High injection pressure was found to shorten ignition delay, as well as to enhance peak pressure. The results also revealed that the heat release rate in the premixed combustion region was markedly reduced through the use of pilot injection, while the soot distribution and the heat release rate in the diffusion combustion region were increased. The swirl effect was found to shorten ignition delay at certain injection timings, and to enhance the heat release rate in all experimental conditions.  相似文献   
939.
In modern four-stroke automotive engine technology, variable valve timing and lift control offer potential benefits for making a high-performance engine. In this paper, a novel design named dual-mode electrohydraulic fully variable valve train (EHFVVT) for both engine intake and exhaust valves is introduced. The system is mainly controlled by either proportional flow control valves or proportional pressure relief valves, and hence two different families of valve displacement patterns can be achieved. The construction of the mathematical model of the valve train system and its dynamic analysis are also presented in this paper. Experimental and simulation results show that the dual-mode electrohydraulic variable valve train can achieve fully variable valve timing and lift control, and has the potential to eliminate the traditional throttle valve in the gasoline engines. With the proposed system, the engine performance at various speeds and loads will be significantly improved.  相似文献   
940.
Exhaust gas recirculation (EGR) is an emission control technology that allows for a significant reduction in NOx emissions from light- and heavy-duty diesel engines. The primary effects of EGR are a lower flame temperature and a lower oxygen concentration of the working fluid in the combustion chamber. A high pressure loop (HPL) EGR is characterized by a fast response, especially at lower speeds, but is only applicable if the turbine upstream pressure is sufficiently higher than the boost pressure. On the contrary, for the low pressure loop (LPL) EGR, a positive differential pressure between the turbine outlet and the compressor inlet is generally available. However, a LPL EGR is characterized by a slow response, especially at low and moderate speeds. In this study, of the future types of EGR systems, the dual-loop EGR system (which has the combined features of the high-pressure loop EGR and the low-pressure loop EGR) was developed and was optimized under five selected operating conditions using a commercial engine simulation program (GT-POWER) and the DOE method. Finally, significant improvements in the engine exhaust emissions and performance were obtained by controlling several major variables.  相似文献   
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