Catalytic Combustion of Lean Methane Assisted by Electric Field over Pd/Co<Subscript>3</Subscript>O<Subscript>4</Subscript> Catalysts at Low Temperature

A series of Pd/Co₃O₄ catalysts were prepared by Self-Propagating High-Temperature Synthesis (SHS) method in this study, and electric field was applied for catalytic combustion of lean methane over Pd/Co₃O₄ catalysts at low temperature. When electric field was applied, the catalytic combustion performance of Pd/Co₃O₄ catalysts was greatly improved, and the application of electric field could reduce the load of active element Pd to some extent while maintaining the same efficiency. Based on experimental tests and the analysis results of X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), H₂-temperature-programmed reduction (H₂-TPR) and in-situ diffuse reflectance infrared Fourier transform spectroscopy (in-situ DRIFTS), the mechanism of catalytic oxidation of CH₄ over Pd/Co₃O₄ catalysts in electric field was proposed. The catalytic combustion of CH₄ occurs only when the temperature is higher than 250 °C normally, but when electric field was applied, the whole process of CH₄ oxidation was promoted significantly and the reaction temperature was reduced. Electric field could promote the reduction of the support Co₃O₄ to release the lattice oxygen, resulting in the increase of PdO_x and the surface chemisorbed oxygen, which could provide more active sites for the low-temperature oxidation of CH₄. Furthermore, electric field could accelerate the dehydroxylation of CoOOH to further enhance the activity of the catalysts.     

平阳霉素局部注射对鼻息肉病息肉组织病理学的影响

目的通过观察平阳霉素治疗前后鼻息肉病息肉组织的病理变化情况,探讨平阳霉素治疗鼻息肉病的机制。方法应用末端脱氧核苷酸转移酶介导的脱氧三磷酸尿苷缺口末端标记法(TUNEL法)检测凋亡细胞,与相邻连续的HE染色片对位对照观察嗜酸性粒细胞的凋亡情况。结果平阳霉素治疗前鼻息肉组织嗜酸性粒细胞表达显著高于正常下鼻甲(P<0.01);治疗后鼻息肉组织中的嗜酸性粒细胞表达明显低于治疗前(P<0.01);治疗后鼻息肉组织中嗜酸性粒细胞的凋亡指数高于治疗前(P<0.01)。结论嗜酸性粒细胞是鼻息肉病息肉组织中主要的浸润炎细胞;平阳霉素可通过促进嗜酸性粒细胞凋亡达到治疗鼻息肉病的目的。     

γ-氨基丁酸在发育期大鼠视皮层长时程增强中的作用

目的　探讨γ 氨基丁酸 (GABA)在发育期大鼠视皮层诱导长时程增强 (LTP)中的作用。方法　应用视皮层脑片电生理技术 ,在大鼠视皮层脑片Ⅳ层刺激而在Ⅱ /Ⅲ层记录场电位 ,在第 2、3、5周龄的大鼠脑片中诱导LTP ,并比较发育过程中LTP的发生率以及GABA在诱导LTP中的作用。结果　在第 5周龄的大鼠脑片中诱导的LTP发生率明显低于第 2及第 3周龄的大鼠。GABAA受体拮抗剂Picrotoxin能够提高第 5周龄的大鼠LTP的发生率 ,但对于第 2及第 3周龄LTP无作用。结论　GABA对于视皮层发育关键期之前LTP的诱导并无易化作用 ;但对于发育关键期后的LTP有抑制作用     

Simulation of temperature distribution in hot filament chemical vapor deposition diamond films growth on SiC seals

In this study, the temperature and gas velocity distributions in hot filament chemical vapor deposition(HFCVD) diamond film growth on the end surfaces of seals are simulated by the finite volume method. The influence of filament diameter, filament separation and rotational speed of the substrates is considered. Firstly,the simulation model is established by simplifying operating conditions to simulate the temperature and gas velocity distributions. Thereafter, the deposition parameters are optimized as 0.6 mm filament diameter, 18 mm filament separation and 5 r/min rotational speed to get the uniform temperature distribution. Under the influence of the rotational speed, the difference between temperature gradients along the directions perpendicular to the filament and parallel to the filament becomes narrow, it is consistent with the actual condition, and the maximum temperature difference on the substrates decreases to 7.4?C. Furthermore, the effect of the rotational speed on the gas velocity distribution is studied. Finally, diamond films are deposited on the end surfaces of Si C seals with the optimized deposition parameters. The characterizations by scanning electron microscopy(SEM) and Raman spectroscopy exhibit a layer of homogeneous diamond films with fine-faceted crystals and uniform thickness. The results validate the simulation model.     

人TSHR膜外区cDNA克隆及真核表达载体的构建

目的通过生物技术获得促甲状腺激素受体膜外区表达载体,为TSHR膜外区的研究提供有力工具。方法从人甲状腺组织中提取总RNA,RT-PCR分离得到TSHR膜外区cDNA,双酶切后插入真核表达载体pcDNA3.1(+)。结果经酶切鉴定、测序分析表明TSHR膜外区片段与GenBank提供的完全相同。结论成功构建了人TSHR膜外区真核表达载体。     

城乡公交一体化模式选择分析

通过对城乡公交一体化现有的运作模式进行分类,分析各种模式的优缺点,运用层次分析法构建模式选择的指标体系,得到相应的选择模型,可为城乡公交一体化的规划与实施提供依据和方法.     

粒-巨噬细胞集落刺激因子对大鼠降钙素水平的影响

目的探讨粒-巨噬细胞集落刺激因子(GM-CSF)对大鼠降钙素水平的影响。方法给动物腹腔注射不同剂量的GM-CSF,然后用RIA试剂盒检测血中降钙素水平,同时测血中钙、磷及碱性磷酸酶。结果血清钙水平各实验组均比对照组降低,但仅大剂量组与对照组间差异有统计学意义(P<0.05);雌性大鼠血清降钙素水平各实验组均比对照组明显降低(P<0.05);实验组的血清磷均比对照组升高,但无统计学意义(P>0.05);血清碱性磷酸酶未见有显著的组间差异。结论50μg/kg的GM-CSF可以引起SD大鼠血清钙下降;10μg/kg和50μg/kg的GM-CSF均可以引起雌性大鼠的血清降钙素降低,但对血磷、血清碱性磷酸酶无显著影响。     

基于三重模式的长江堤防信息系统的研究与实现

分析了长江堤防工程的地质勘察及施工信息,提出了一种基于Client/Server,Browser/Server,Browser/ArcIMS三重架构的开发模式,构建了系统的体系结构.对后台数据库进行了优化和重组,提出了一种基于树形数据结构的"超"实体多级递归算法,给出了无限层次的动态下拉列表实现方法.引入面向对象技术,采用多种开发工具,开发了长江堤防工情信息服务系统软件,实现了DBMS与GIS的集成一体化.     

基于小波变换的高速公路意外事件检测

试验表明,基于一维连续小波变换、一维离散小波变换和二维离散小波变换建立的高速公路意外事件检测模型原型具有优良的检测性能,检测在Califonia8#基础上提高了195%,同时检测时间缩短为原来的3.4%.     

工厂高压供电线路的继电保护

介绍了在工厂高压供电线路中继电保护装置的作用;提出对保护装置的基本要求,对常用的继电保护方式的原理、特点和使用进行探讨.