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171.
2,6-二苯基苯酚中间体合成研究   总被引:1,自引:0,他引:1  
阐述了以环己酮为原料进行自缩合反应合成2,6-二苯基苯酚中间体三聚酮。考察了使用不同催化剂、反应温度、反应时间、催化剂用量、移除反应生成水等不同条件对反应的影响。试验表明,在以氢氧化钾为催化剂,反应温度175℃,反应时间2.5h-3h条件下,环己酮转化率达到80%,三聚酮收率达到38.9%,三聚酮选择性达到48.4%。  相似文献   
172.
RMFC码头作为连岸设施,周围布置有锚泊系统,其工作海域水深很浅,深度随距海岸线距离而变化。由于利用多刚体水动力学的计算分析难以保证结果的正确性,因此,采用试验方法研究RMFC码头的运动性能。假定单元间的接头和系泊系统可有效承担风、浪、流诱导产生的载荷,通过试验研究RMFC码头典型单元六自由度运动,以验证此种RMFC码头布置形式的有效性。  相似文献   
173.
以长江口深水航道治理二期工程为依托,进行基床基础防波堤的动力软化判别标准的研究,分析在波浪作用下3个不同沉降量的典型断面下卧地基土的自重应力、附加静应力、波浪作用的附加动应力分布间的关系,初步得出该地区软粘土可能出现动力软化现象的判别标准。  相似文献   
174.
盾构施工筹划原则及影响因素分析   总被引:2,自引:2,他引:0  
以北京地铁4号线11合同段(灵境胡同-新街口)四站三区间的盾构施工筹划为例,重点分析影响盾构施工筹划的因素;以方案比较的方法,介绍了确定三区间总体筹划方案的详细过程.  相似文献   
175.
舰载直升机的起降安全涉及到舰机两方面,且影响因素较多。本文首先对舰载直升机起降安全因素进行了系统分析,梳理了其关键影响因素舰船空气流场中各特性参数对直升机操作性能的影响。然后介绍了用于舰船空气流场测量的三种典型方法,对舰船空气流场的深入研究有重要指导意义,并可为机舰动态配合研究提供参考。  相似文献   
176.
In order to study the diffusion law of grouting slurry in the water-rich sand layer under flowing water conditions, a grouting test model consisting of a main test system, a grouting system, and a measurement system was developed. And for detecting the diffusion scope of the grouts, a new resistivity method was proposed. It is found that the relationship between grouting pressure and grouting rate during the test is strong. Under hydrodynamic conditions, the grouting slurry diffuses elliptically. Due to gravity and the effect of the upper water flow, the center of gravity of the ellipsoid is below the grouting outlet, and the grouting effectively improves the physical and mechanical properties of water-rich sand bodies. At the same time, the resistivity method has a good application effect on the detection of grouting diffusion range. The range of slurry diffusion obtained by the resistivity method is basically consistent with the boundary of the stone body after excavation, indicating that the resistivity method is reliable for detection of grouting range in dynamic water-rich sand layer. © 2018, Editorial Office of "Modern Tunnelling Technology". All right reserved.  相似文献   
177.
Combining the present situation and development trend of different tunnel support technologies at home and abroad, this paper analyzes the problems of rockburst in hard rock tunnels and large deformation in soft rock tunnels caused by high ground stress. It is concluded that: 1) regarding the rockburst problem, the current support technology is mainly influenced by the rock burst mechanism which is dominated by static factors, and so the used support components are generally of smaller deformation performance and "passive support" properties; 2) as the rockburst is the result of dynamic-static stress coupling, and only the anchor bolt has the "active support" attribute in the current "shotcrete+anchor bolt+wire net" support system, so the best support system should have the two functions of active support and energy release in terms of the rockburst problem, and the key focus of the research and development is anchorage members; 3) there are three main support types for large deformation in soft rock tunnels, e.g. the heavy support, layered support and yielding support. Among them, the heavy support system in underground cavern with large deformation is easy to induce excessive surrounding rock pressure, and so the applicable conditions are limited. The layered support system is still not the best choice due to its immature theoretical study, difficult determination of the thickness value and the installation time of each support layer and the interference to construction progress. With the characteristics of timely support and yielding while supporting, the yielding support system can give full play to the performance values of surrounding rocks and supporting materials, and make both of them reach the optimal state, so it is the best choice for supporting the soft rock tunnels with large deformations. © 2018, Editorial Office of "Modern Tunnelling Technology". All right reserved.  相似文献   
178.
The application of prefabricated tunnel technology has been become a new research field both in China and abroad. Based on the running tunnel between Yufuhe station and Wangfuzhuang station of Jinan rail transit line R1, a new prefabricated tunnel construction technology, the PBA method is presented. This paper makes a detailed discussion on section form, supporting scheme and construction process of the PBA method. In this study, 3D a new 3D numerical model for PBA method is presented by finite difference numerical simulation software Flac and the construction processes are modeled. The rule of ground surface settlement, ground deformation and structural stress caused by PBA method is studied in detail. Results show that the structure of PBA method can effectively control the deformation magnitude and scope. Stress concentration appears at the prefabricated connection parts and the reinforcement needs to check. The total assembled structure forms the load-bearing system after the completion of the lateral wall. The built-in depth of the precast pile and pile bottom grouting quality should to be ensured to control the displacement of the precast piles. The results of this study will be a useful reference for similar projects in the future. © 2018, Editorial Office of "Modern Tunnelling Technology". All right reserved.  相似文献   
179.
Jacking force is the most important parameter in jacking pipe engineering, and reasonable calculation of jacking forces plays an important role in safe and smooth pipe jacking construction. There are many calculation methods for pipe jacking force at present, and the calculation results may be affected to some extent by different cal⁃ culation methods. For this reason, calculation methods of jacking force (frictional resistance) were collected and a comparative analysis was conducted with aspects to the advantages, disadvantages and applicabilities. The results show that as for the jacking force calculated by empirical formulae, the soil layer classifications corresponding to giv⁃ en frictional force per unit area and relevant factors to be considered are different, and the values of frictional force per unit area between pipe and soil in the same soil layer are also different; as for the jacking force calculated by theo⁃ retical formulae, the calculation methods for vertical earth pressure at crown are different and much effected by the pipe buried depth; as for the jacking force calculated by numerical simulation, the selected theories for the simula⁃ tion program and the construction factors to be considered during simulation are different. © 2018, Editorial Office of "Modern Tunnelling Technology". All right reserved.  相似文献   
180.
Considering the influence of many factors (soil loss, frontal additional thrust, the friction force of the shield shell and the additional grouting force), a method for improving the uniform soil body movement model is pro-posed, and a mechanical calculation model is established to study the calculation method for soil body deformation caused by double-line parallel shield driving. Based on the Mindlin solutions of elastic mechanics, the theoretical solutions for soil body deformations caused by the last three factors are calculated; considering the uniform soil body movement model, the theoretical solutions for soil body deformations caused by soil loss are calculated, then the to-tal theoretical solutions for soil body deformations under multiple factors are obtained by means of superposition. The vertical surface settlement, vertical horizontal displacement, and vertical displacements of the soil body at different depths of Hangzhou Metro Line 1 are calculated to analyze the variation laws. Meanwhile the influential factors for horizontal displacement variation are studied. The research shows that with a change of depth, the settlement of the soil body changes within the scope of 10 to 13 m in the horizontal direction near where the maximum settlement occurs;the direction of the horizontal displacement of the soil body changes with a change of the positional relationship be-tween the calculation points and the tunnel; and with an increase of interval J for the two tunnels, the horizontal dis-placement of the soil body of a deep double-line tunnel decreases while the displacement near the surface changes slightly. © 2018, Editorial Office of "Modern Tunnelling Technology". All right reserved.  相似文献   
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