亚硝胺

与二烯烃橡胶相比，EPDM的双键很少：为了提高EPDM胶料的硫化速度，需要加入大量的促进剂。由于某些促进剂中含有仲胺，这是亚硝胺的主要来源，因此人们正在考虑使用一类新的促进剂。考察了不同硫化体系对亚硝胺排放、加工参数和物理性能的影响，片采用试验设计方法对硫化体系进行了优化。     

Public transit subsidies, output effect and total factor productivity

This paper extends previous works on total factor productivity decomposition when firms receive both operating and capital subsidies. It shows that previous works considered either the lump-sum or substitution effects of these subsidies but not together. Using constrained cost minimization as the framework it offers formal proofs to show that cost increases are inevitable if the total effects of the subsidies are considered, and that total factor productivity growth results from increasing amounts of subsidies under economies of scale and in the absence of technical change. Applications of the decomposition equations derived to a sample of transit systems finds near constant returns to scale and negative contributions of these subsidies to total factor productivity growth. Technical change reverses this decline and results in total factor productivity growth. Further, it finds that the lump-sum effects of the subsidies reduce total factor productivity more than does the substitution effect.     

Silicon dynamics in the Oder estuary, Baltic Sea

Studies on dissolved silicate (DSi) and biogenic silica (BSi) dynamics were carried out in the Oder estuary, Baltic Sea in 2000–2005. The Oder estuary proved to be an important component of the Oder River–Baltic Sea continuum where very intensive seasonal DSi uptake during spring and autumn, but also BSi regeneration during summer take place. Owing to the regeneration process annual DSi patterns in the river and the estuary distinctly differed; the annual patterns of DSi in the estuary showed two maxima and two minima in contrast to one maximum- and one minimum-pattern in the Oder River. DSi concentrations in the river and in the estuary were highest in winter (200–250 μmol dm^− 3) and lowest (often less than 1 μmol dm^− 3) in spring, concomitant with diatom growth; such low values are known to be limiting for new diatom growth. Secondary DSi summer peaks at the estuary exit exceeded 100 μmol dm^− 3, and these maxima were followed by autumn minima coinciding with the autumn diatom bloom. Seasonal peaks in BSi concentrations (ca. 100 μmol dm^− 3) occurred during the spring diatom bloom in the Oder River. Mass balance calculations of DSi and BSi showed that DSi + BSi import to the estuary over a two year period was 103.2 kt and that can be compared with the DSi export of 98.5 kt. The difference between these numbers gives room for ca. 2.5 kt BSi to be annually exported to the Baltic Sea. Sediment cores studies point to BSi annual accumulation on the level of 2.5 kt BSi. BSi import to the estuary is on the level of ca. 10.5 kt, thus ca. 5 kt of BSi is annually converted into the DSi, increasing the pool of DSi that leaves the system. BSi concentrations being ca. 2 times higher at the estuary entrance than at its exit remain in a good agreement with the DSi and BSi budgeting presented in the paper.     

Benthic sediment composition and nutrient cycling in an Intermittently Closed and Open Lake Lagoon

Surfical sediments within Corunna Lake, a moderate size Intermittently Closed and Open Lake Lagoon (ICOLL), were examined for solid phase nutrient concentrations (TN, TP, TOC,) and solute exchange rates between the sediment and water column (O₂, NO₃–N, NH₄–N, FRP, and N₂). The surfical sediments in Corunna Lake contained high concentrations of TN (5 mg/g dry mass), total phosphorus (0.6 mg/g dry mass), and TOC (~ 5% dry mass). The carbon stable isotope ratio (δ¹³C) and TOC:TN ratios (δ¹³C ~ ? 24, TOC:TN ~ 11–14) demonstrated that the composition of the organic matter in the sediment was a mixture derived primarily of degraded planktonic matter. The close association between TP and Fe concentrations highlighted the potential role Fe plays in mediating Filterable Reactive Phosphorus (FRP) concentrations in the water column of Corunna Lake. In situ benthic chamber incubations were used to measure benthic fluxes. Solute exchange rates between the sediment and water column in Corunna Lake were similar to other reported studies (O₂ = ? 469 to ? 1765 µmol m^? 2 h^? 1, NH₄–N = 0.1–63 µmol m^? 2 h^? 1, NO₂/NO₃–N = 0 µmol m^? 2 h^? 1, FRP = ? 4–1.6 µmol m^? 2 h^? 1and N₂ = 12–356 µmol m^? 2 h^? 1). As more carbon was deposited and mineralized the efficiency of the bacterial population to denitrify nitrogen in the sediment decreases. The linkage between land use and benthic biogeochemistry was also explored. A dairy farm exists in the middle catchment of Corunna Lake, and the receiving bay sediment consistently demonstrated the highest oxygen consumption rates in winter and spring (? 1408 µmol m^? 2 h^? 1 in winter, ? 1691 µmol m^? 2 h^? 1 in spring) and lowest denitrification efficiencies during summer (~ 3%). Nitrate/nitrite fluxes were not observed during any of the chamber incubations, with the concentrations of nitrate/nitrite being below detection limits (< 10 μg/L). Seasonal changes influenced the rates of solute exchange between the sediment and water column. Critical measures of solute exchange for NH₄–N and biogenic N₂ indicated that seasonal temperature changes play a significant role in mediating the reaction rates of sedimentary based biogeochemical processes. Measurable FRP fluxes were small but greater in the benthic sediments which received higher carbon inputs. Sediments have a high capacity to adsorb P which is released as sediment oxygen demand increases as a result of increases in labile carbon loads.     

Evaluating the energy performance of a SUV hybrid electric vehicle

This paper analyzes the energetic performance of the hybrid Lexus RX 400h, through on-board measurements. Several speed profiles were analyzed, for three driving types, successive stop and go cycles, three speed profiles, crossing an electronic toll collection booth, and a roundabout. In stop and go situations the internal combustion engine did not work (the torque needed to impulse the vehicle in the stop and go situations was only supported by the electric engines), as well as in the situations of constant low speeds (50 or 60 km h^?1). The auxiliary support given by the electric engines in the accelerations, as well as the importance of the energy regeneration system on the batteries’ load recovery is also demonstrated. When compared with similar conventional vehicles, the Lexus RX 400h has lower combined energy consumption between 1.2% and 60%.     

Estimation of the effects of aircraft noise on residential satisfaction

This study assesses the effects of aircraft noise on residential satisfaction, an important indicator of subjective well-being. A structural equation model is specified that estimates the relationships between objective variables, noise annoyance variables and residential satisfaction. Secondary data-analysis is used to estimate the model. The survey was conducted in 1996/1997 among the population living within a 25-km radius of Amsterdam Schiphol, the largest airport in the Netherlands. The effect of aircraft noise annoyance is found to be relatively small. In addition, the objective level of aircraft noise exposure is found to be a better predictor of residential satisfaction than its subjective counterpart. The most important determinants of residential satisfaction are found to be road traffic noise annoyance, age and neighbor noise annoyance.     

Scantling multi-objective optimisation of a LNG carrier

Numerous real-world problems related to ship design can be solved by various alternatives. However, the scantling design has conflicting objectives such as minimum production cost, minimum weight and maximum moment of inertia (stiffness). Therefore a multi-purpose solution had to be settled in order to meet all these requirements at once. Ship design is a complex endeavour requiring successful coordination of many different disciplines, both technical and non-technical. Basic design is the least defined stage of the ship design process and seeks to define the optimal amidships section structure. For that purpose, recent improvements have been made to a numerical tool in order to optimise the scantling of ship sections by considering production cost, weight and moment of inertia in the optimisation objective function. A multi-criteria optimisation of a LNG carrier is conducted in this paper to illustrate the analysis process. Pareto frontiers are obtained and results have been validated by the Bureau Veritas rules. The methodology presented in this paper has demonstrated its effectiveness in optimising scantling of ships at a very early design stage thanks to a management of critical problems usually studied at a later stage of the design.     

A regional railroad network optimization model for coal transportation

A regional railroad network is presented to evaluate the system's response to increased coal traffic. An optimal, multimodal, coal-shipping pattern is developed for the study region to minimize total costs and to efficiently use the existing network. A two-stage, general model allocates resources among demands and then assigns flows to the network according to efficiency criteria. The model is sufficiently general to permit modification for specific needs, assumptions and data. Government agencies and industries can apply the model in resource allocation decisions and transportation policy analysis.     

Network representation,continuum approximations and a solution to the spatial aggregation problem of traffic assignment

This paper complements the preceding one, which showed how one could modify equilibrium traffic assignment algorithms for networks with many centroids. In this one it is shown how one can substitute centroids by zones with continuous population densities. The technique, which is mathematically guaranteed to approximate a flow pattern in accordance with Wardrop's user equilibrium criterion, requires some geometrical calculations which can be handled off-line. With the suggested approach, it is possible to represent the spatial distribution of trip ends more realistically and this allows traffic assignment models to capture the effects of short and intrazonal trips in a way previously impossible. The method is shown to be computationally feasible.