Long-term changes of inorganic nutrients in the Lagoon of Venice (Italy)

The paper aims at investigating the trends of the concentrations of dissolved inorganic nitrogen (DIN) and phosphorous in the Lagoon of Venice, Italy, in the last 35 years. The trend analysis of ammonia nitrogen, nitrate nitrogen and reactive phosphorus (RP) yielded rather different results. The decrease in ammonia nitrogen concentration, in particular, in the basin influenced by severe industrial discharges, is accurately described by a negative exponential model. The nitrate concentration did not show significant interannual trends, while wide seasonal variations have been detected. Reactive phosphorus concentration increased until the end of the 1970s at the stations close to the industrial area as well as in those influenced by river discharges and by sewages of the city of Venice. The sudden decrease that followed was most likely related with environmental policies, namely the improvement of wastewater purification treatments and the regulation of phosphorus use in detergents.     

Galvanic corrosion behaviour of HE 20 / MDN 138 & HE 20 / MDN 250 alloys in natural seawater

In view of their excellent mechanical properties, workability and heat treatment characteristics, MDN 138 & MDN 250 have been widely used in missile, rocket and aerospace industries. With light weight and high performance characteristics HE 20 aluminium alloy acts as an important material in defence and aerospace applications. The galvanic corrosion behaviour of the metal combinations HE 20 / MDN 138 and HE 20 / MDN 250, with 1:1 area ratio, has been studied in natural seawater using the open well facility of CECRI’s Offshore Platform at Tuticorin for a year. The open circuit potentials of MDN 138, MDN 250 and HE 20 of the individual metal, the mixed potential and galvanic current of the couples HE 20 / MDN 138 and HE 20 / MDN 250 were periodically monitored throughout the study period. The calcareous deposits on MDN 138 and MDN 250 were analysed using XRD. The results of the study reveal that that HE 20 has offered required amount of protection to MDN 138 & MDN 250.     

Inorganic carbon fluxes through the boundaries of the Greenland Sea Basin based on in situ observations and water transport estimates

A carbon budget for the exchange of total dissolved inorganic carbon C_T between the Greenland Sea and the surrounding seas has been constructed for winter and summer situations. An extensive data set of C_T collected over the years 1994–1997 within the European Sub-polar Ocean Programmes (ESOP1 and ESOP2) are used for the budget calculation. Based on these data, mean values of C_T in eight different boxes representing the inflow and outflow of water through the boundaries of the Greenland Sea Basin are estimated. The obtained values are then combined with simulated water transports taken from the ESOP2 version of the Miami Isopycnic Coordinate Ocean Model (MICOM). The fluxes of inorganic carbon are presented for three layers; a surface mixed layer, an intermediate layer and a deep layer, and the imbalance in the fluxes are attributed to air–sea exchange, biological fixation of inorganic carbon, and sedimentation. The main influx of carbon is found in the surface and the deep layers in the Fram Strait, and in the surface waters of direct Atlantic origin, whereas the main outflux is found in the surface layer over the Jan Mayen Fracture Zone and the Knipovich Ridge, transporting carbon into the Atlantic Ocean via the Denmark Strait and towards the Arctic Ocean via the Norwegian Sea, respectively. The flux calculation indicates that there is a net transport of carbon out of the Greenland Sea during wintertime. In the absence of biological activity, this imbalance is attributed to air sea exchange, and requires an oceanic uptake of CO₂ of 0.024±0.006 Gt C yr⁻¹. The flux calculations from the summer period are complicated by biological fixation of inorganic carbon, and show that data on organic carbon is required in order to estimate the air–sea exchange in the area.     

On the dense water spreading off the Ross Sea shelf (Southern Ocean)

In this study, current meter and hydrological data obtained during the X Italian Expedition in the Ross Sea (CLIMA Project) are analyzed. Our data show a nice agreement with previous data referring to the water masses present in this area and their dynamics. Here, they are used to further analyze the mixing and deepening processes of Deep Ice Shelf Water (DISW) over the northern shelf break of the Ross Sea. In more detail, our work is focused on the elementary mechanisms that are the most efficient in removing dense water from the shelf: either classical mixing effects or density currents that interact with some topographic irregularity in order to drop to deeper levels, or also the variability of the Antarctic Circumpolar Current (ACC) which, in its meandering, can push the dense water off the shelf, thus interrupting its geostrophic flow. We also discuss in detail the (partial) evidence of dramatic interactions of the dense water with bottom particulate, of geological or biological origin, thus generating impulsive or quasi-steady density-turbidity currents. This complex interaction allows one to consider bottom particular and dense water as a unique self-interacting system. In synthesis, this is a first tentative analysis of the effect of bottom particulate on the dense water dynamics in the Ross Sea.     

The importance of oceanographic fronts to marine birds and mammals of the southern oceans

During the last 30 years, at-sea studies of seabirds and marine mammals in the oceans south of the Subtropical Front have described an association with major frontal areas. More recently, the advancement in microtechnology has allowed the tracking of individuals and investigations into how these marine predators actually use the frontal zones. In this review, we examine 1) the relative importance to apex predators of the different frontal zones in terms of spatial distribution and carbon flux; 2) the processes that determine their preferential use; and 3) how the mesoscale dynamics of frontal structures drive at-sea foraging strategies of these predators. We review published results from southern waters and place them in a broader context with respect to what has been learned about the importance of fronts in oceans farther north.Some fronts constitute important boundaries for seabird communities in southern waters. At a mesoscale the maximum values of seabird diversity and abundance correspond to the location of the main fronts. At-sea surveys show a strong curvilinear correlation between seabird abundance and sea surface temperatures. High mean species richness and diversity for whales and seabirds are consistently associated with the southern water mass boundary of the Antarctic Circumpolar Current, the Subtropical Front and the Subantarctic Front; in the case of the Polar Front mean seabird densities are more variable. At small-scales, variation in seabird occurrence has been directly related to the processes at fronts in a limited number of cases. A significant positive relation was found between some plankton feeding species and frontal temperature gradient–phytoplankton variables.Telemetric studies have revealed that several apex predators (penguins, albatrosses, seals) perform long, directed foraging trips either to the Subtropical front or Polar Front, depending on locality. Seabirds with low flight costs, such as albatrosses, are able to reach fronts at long distances from colonies, showing variable foraging strategies as a function of the distances involved. Diving birds such as King penguins, that travel at a higher cost and lower speed, rely on the predictable spatial distribution of mesopelagic fish found close to the Polar Front. They may use the currents associated with eddies as oceanographic cues in the active search for frontal zones. Once in these areas they dive preferentially in and below the depth of the thermocline where catches per unit effort are high. Elephant seals concentrate foraging activity principally inside or at the boundary of cyclonic eddies. These mesoscale features appear to offer exceptional productivity favourable for foraging by various diving top predators.The connection between biophysical parameters at fronts and predators is likely to be made through biological enhancement. Top predators appear to forage at locations where prey are advected by physical processes and others where prey are produced locally. Long-term research on at-sea distributions and demographic parameters of top predators are essential to assess the consequences of potential shift in front distributions in relation to global warming. Such environmental changes would add to the impact of fish extraction by the industrial fisheries on the southern food webs.     

Hydrographic cruises off northwest Africa: the Canary Current and the Cape Ghir region

We present hydrographic data for several sections located along the African coastline and off Cape Ghir, carried out at times of weak surface winds (October 1995 and September 1997). The main sections are near the continental slope, at mean distances between 100 and 150 km from the coastline. North of Cape Ghir (31°N) the geostrophic transport (referenced to 650 m) of North Atlantic Central Water through these sections is 3.7 and 2.0 Sv for 1995 and 1997, respectively. This confirms that a major fraction of the water transport by the Canary Current flows east, into the continental slope off northwest Africa, at latitudes above Cape Ghir. Most of this flow continues south past Cape Ghir, along the coast and probably through the eastern passages of the Canary Archipelago. A significant fraction, however, may escape through surface Ekman transport (0.3–0.5 Sv during the early fall season) and by offshore flow at Cape Ghir (1.1 Sv in September 1997, referenced to 650 m). Despite the weak winds the Cape Ghir filament was clearly visible, characterized by localized coastal upwelling associated to a cyclonic shallow structure and cold (and fresh) waters stretching offshore as a very shallow feature (50–100 m deep). The satellite images show that the surface temperature field is highly variable, in rapid response to the surface winds, always with a core region of relatively cold water and commonly with one or two associated eddies. Our results support the existence of two recirculation cells in the area: a horizontal one that connects the interior eastern boundary currents with the coastal region and a vertical one related to both wind-induced and filament upwelling. The data also show a salinity subsurface maximum at the root of the filament, linked to water inflow from northern latitudes, and a subsurface anticyclonic eddy over the Agadir canyon, likely related to the poleward slope undercurrent.     

Management of coastal eutrophication: Integration of field data, ecosystem-scale simulations and screening models

A hybrid approach for eutrophication assessment in estuarine and coastal ecosystems is presented. The ASSETS screening model (http://www.eutro.org) classifies eutrophication status into five classes: High (better), Good, Moderate, Poor and Bad (worse). This model was applied to a dataset from a shallow coastal barrier island system in southwest Europe (Ria Formosa), with a resulting score of Good. A detailed dynamic model was developed for this ecosystem, and the outputs were used to drive the screening model. Four scenarios were run on the research model: pristine, standard (simulates present loading), half and double the current nutrient loading. The Ria Formosa has a short water residence time and eutrophication symptoms are not apparent in the water column. However, benthic symptoms are expressed as excessive macroalgal growth and strong dissolved oxygen fluctuations in the tide pools. The standard simulation results showed an ASSETS grade identical to the field data application. The application of the screening model to the other scenario outputs showed the responsiveness of ASSETS to changes in pressure, state and response, scoring a grade of High under pristine conditions, Good for half the standard scenario and Moderate for double the present loadings. The use of this hybrid approach allows managers to test the outcome of measures against a set of well-defined metrics for the evaluation of state. It additionally provides a way of testing and improving the pressure component of ASSETS. Sensitivity analysis revealed that sub-sampling the output of the research model at a monthly scale, typical for the acquisition of field data, may significantly affect the outcome of the screening model, by overlooking extreme events such as occasional night-time anoxia in tide pools.     

半约束模型试验--一种验证随浪和斜浪中波浪力计算的手段

本文采用半约束模型试验技术，对一条高速船在规则波中随浪和斜浪工况进行了流体动力系列试验，以探讨航运的安全性，验证作用于船体上波浪力的估算方法。对每次试验，以波动方程的形式采用数值估算方法确定环绕船模的波浪运动的时间历程。并用同样的方法从测量数据中提取垂荡和纵摇与模型测量运动，一阶波导纵荡、横荡作用力和首摇力矩。因此合理比较理论计算的波浪力与力矩的时间历程成为可能。这表明SSPA海事动力学的研究所(MDL)模型试验设施可以提供高质量的测量，与所述计算方法结合起来可用来验证理论计算和建立半经验方法。     

Observations on colony formation by the cosmopolitan phytoplankton genus Phaeocystis

Few marine phytoplankton have heteromorphic life cycles and also often dominate the ecosystems in which they occur. The class Prymnesiophyceae contains a notable exception: the genus Phaeocystis includes three species that form gelatinous colonies but also occur within their ranges as solitary cells. Phaeocystis antarctica and P. pouchetii are exclusively high latitude taxa, and are notable for regionally tremendous blooms of the colony stage. P. globosa occurs circumglobally, yet its colony blooms primarily are confined to colder waters within its range. Three additional species are warm water forms that have been reported only as solitary cells or loose aggregations that bear little resemblance to the organized colonies of the other taxa. Interpretation of existing data indicates that resource availability (light, temperature and nutrients) by itself is not sufficient to explain this distinction between cold-water colony-forming taxa and warm water solitary cell taxa, nor why colony development in P. globosa is essentially a spatially restricted phenomenon within a much broader geographic range. Colony development by P. globosa in situ has been observed at temperatures ≥20 °C, but only rarely and generally under conditions of seasonally or anthropogenically elevated nutrient supply. Data presented here demonstrate colony development at 20–22 °C in natural plankton communities from oligotrophic waters that were pre-screened through 63 μm mesh (i.e. lacking mesozooplankton and large microzooplankton), but not in unscreened communities containing microzooplankton and >63 μm zooplankton. Reduction of colony proliferation at higher temperatures by mesozooplankton grazing remains as an intriguing possibility that is consistent with available evidence to help explain differences in latitudinal extent of in situ colony development. These data are interpreted within a theoretical framework regarding the potential advantages and disadvantages of the two life cycle stages.