铑催化剂用水合三氯化铑的制备

水合三氯化铑是制备铑催化剂的关键原材料之一。随着化工及汽车行业的发展,对铑催化剂有了更多的需求,由此对水合三氯化铑的需求量越来越大。本文综述了当前铑催化剂的应用,以及其原材料水合三氯化铑制备技术的研究进展,并且展望了未来水合三氯化铑的制备技术。     

A new method for absolute datum transfer in seafloor control network measurement

To decrease the time consumption and the labor intensity in the absolute datum transfer of traditional seafloor control network measurement, a new method, namely sailing-circle positioning method, is put forward in this paper. First, the traditional intersection positioning model is improved by considering the equivalent sound velocity profile error as an unknown parameter in the adjustment model. Second, the effect of geometric dilution of precision (GDOP) on positioning accuracy is analyzed. By seeking for the minimum of GDOP, it is concluded that the absolute datum transfer can achieve the highest accuracy in the condition of sailing along a circle relative to other sailing paths. Moreover, the optimal radius of the circle for the accurate datum transfer is also given out. Besides, the correlation between the accuracy of datum transfer and the sound velocity error in this method is analyzed. Finally, the new method was tested and verified by the experiments in Songhua lake with the water depth of 60 m and in South China sea with the water depth of 2000 m, respectively. These experiment results show that the new method can improve the accuracy and efficiency of traditional datum transfer method significantly.     

铁路预应力路堤加固技术数值研究

研究目的:铁路预应力路堤在国内外尚属一种新型路基加固法,其受力变形特性暂未得到系统化研究,相关加固设计理论仍处于探索性阶段。因此,有必要通过数值手段了解预应力路堤的工作状态,以掌握其加固性能。鉴于此,借助ABAQUS软件平台构建预应力路堤仿真系统,分析差异化预应力加固参数对路堤变形和承载能力的影响以及预应力加固构件的受力特征。研究结论:(1)路堤本体段坡面较优加固位置为距本体顶面以下0.3倍本体高度处;(2)坡率1∶1的预应力路堤在第1、2排侧压板分别施加50 k Pa、100 k Pa预压荷载时,其变形与承载力均可达传统路堤(坡率1∶1.5)水平,并可通过提升加固标准进一步强化路堤承载性能;(3)当对第1、2、3排侧压板分别施加50 k Pa、100 k Pa、100 k Pa预压荷载时,路堤内部附加围压S11>13.5 k Pa区域大致呈"x"形分布并形成横贯路堤的"预压加固区";(4)侧压板锚固区受力集中且复杂,应注意保障锚固区板体强度;(5)力筋在路堤加载前后的应力变化量与坡面侧向变形特征相关;(6)本研究成果可为铁路预应力路堤的加固设计提供技术指导。     

Study on shaft alignment of propulsion shafting system depending on single reaction force supporting position of aft stern tube bearing

Journal of Marine Science and Technology - Trends of large-scale ships have seen propulsion shaft and propeller sizes increase. This has enabled shafts to have greater stiffness, yet has caused...     

全自动化码头发展视域下的集装箱可视化智能理货系统研究

当今,在信息化程度非常高的自动化、无人化集装箱码头理货,常规人盯岸桥的方式已经落伍,我国理货行业如何突破传统理货技术瓶颈,打造适应成本最低、效率最高的整合后物流链的生产工艺已成为行业发展的关键课题。通过现场安装摄像头,采用OCR、RFID、PLC、激光、红外线等进行智能识别箱号、拖车号、拍照验残、全程监控,经过理货业务智能处理系统的处理等,最终实现了通过室内监控即可进行集装箱理货信息的实时传输与共享,体现人性化操作的同时实现了理货的智能化。这一理货工艺的革新加快推动了理货行业的转型升级,并能取得良好的经济效益和社会效益。     

Hybrid process of fabricating high-quality micro wine-glass fused silica resonators

A new hybrid method, which combines improved glass-blown technology with wet etching, is reported to fabricate micro wine-glass resonators with high-quality fused silica. The optimum placement is compared to achieve the resonators with good shell shape. The typical shell diameter is about 4mm and its thickness covers from dozens to hundreds of micrometers. The etching rates in corrosion solutions with different ratios and at different thicknesses of hemispherical shells are studied. We also conclude how to precisely control the thickness. The corrosion solutions with different ratios of HF solution to NH₄F solution make the spherical shells rougher in different degrees. The best roughness is 0.581 nm in the 1: 8 ratio corrosion solution while the original roughness is 0.537 nm. This fact shows that the resonator remains atomically smooth surface. Based on the glassblowing spherical fused silica structure, the thickness of the resonator is effectively controlled by buffered oxide etch (BOE) technology according to the measured etching rate. The measured resonant frequency of the hemispherical shell at ambient pressure and room temperature is 1.75 kHz of rocking mode which is close to the simulated frequency. Using such a low-cost hybrid approach, we can fabricate high-quality microscale resonators in batch.     

Purification effects of C2Cl6 on A00 aluminum

The effects of several fluxes on purification, microstructures and properties of A00 aluminum have been studied. The experimental results and analyses indicate that many cracks and large porosities exist in the surface film above the melt purified by C₂Cl₆ and that the film is floc and mostly composed of Al₂O₃ and pure aluminum, which carries many carbon particles and AlCl₃ not fully volatilized. And then over 50% (mass fraction) of the all-melting residue is pure aluminum, which is one of the major reasons for high melting loss. Moreover, because of a mass of gas bubbles and a state of seethe, there are many inclusions which size is under 10 ??m in the microstructure of A00 aluminum purified with C₂Cl₆ or fluxes containing C₂Cl₆. With this purifying method, the aluminum crystal grains are extended along the radius that was observed firstly and the average crystal size of A00 aluminum are about 100?C150 ??m. In addition, small size inclusions have little affected on tensile strength and micro inclusions under 10 ??m have little affected on elongation.     

Novel experimental strategy for high resolution AFM imaging of membrane-associated bacterial toxins

Bacterial pore-forming toxins （PFTs） are essential virulence factors of many human pathogens. Knowl- edge of their structure within the membrane is critical for an understanding of their function in pathogenesis and for the development of useful therapy. Atomic force microscopy （AFM） has often been employed to structurally interrogate many membrane proteins, including PFTs, owing to its ability to produce sub-nanometer resolution images of samples under aqueous solution. However, an absolute prerequisite for AFM studies is that the samples are single-layered and closely-packed, which is frequently challenging with PFTs. Here, using the prototypical member of the cholesterol-dependent cytolysin family of PFTs, perfringolysin O （PFO）, as a test sample, we have developed a simple, highly robust method that routinely produces clean, closely-packed samples across the entire specimen surface. In this approach, we first use a small Teflon well to prepare the supported lipid bilayer, remove the sample from the well, and then directly apply the proteins to the bilayer. For reasons that are not clear, bilayer preparation in the Teflon well is essential. We anticipate that this simple method will prove widely useful for the preparation of similar samples, and thereby enable AFM imaging of the greatest range of bacterial PFTs to the highest possible resolution.     

Estimation of delay variability at signalized intersections for urban arterial performance evaluation

Urban arterial performance evaluation has been broadly studied, with the major focus on average travel time estimation. However, in view of the stochastic nature of interrupted flow, the ability to capture the characteristics of travel time variability has become a critical step in determining arterial level of service (LOS). This article first presents a stochastic approach that integrates classic cumulative curves and probability theories in order to investigate delay variability at signalized intersections, as a dominant part of the link travel time variability. This serves as a basis for arterial travel time estimation, which can be obtained through a convolution of individual link travel time distributions. The proposed approach is then applied in the estimation of travel time along one arterial in Shanghai, China, with abundant automatic vehicle identification (AVI) data sources. The travel time variability is evaluated thoroughly at 30-min intervals, with promising results achieved in comparison to the field measurements. In addition, the estimated travel time distributions are utilized to illustrate the probability of multiple LOS ranges, namely, reliability LOS. The results provide insights into how we might achieve a more reliable and informative understanding of arterial performance.     

Robust control for four-wheel-independent-steering electric vehicle with steer-by-wire system

A four-wheel-independent-steering (4WIS) electric vehicle (EV) with steer-by-wire (SBW) system is proposed in this paper. The fast terminal sliding mode controller (FTSMC) is designed for the SBW system to suppress external disturbances. Taking unstructured and structured uncertainties into consideration, a robust controller is designed for the 4WIS EV utilizing μ synthesis approach and the controller order reduction is implemented based on Hankel-Norm approximation. Since sideslip angle is the feedback signal of robust controller and it is hard to measure, the extended Kalman filter (EKF) is employed to estimate sideslip angle. To evaluate the vehicle performance with the designed control system, step and sinusoidal steering maneuvers are simulated and analyzed. Simulation results show that the designed control system have good tracking ability, strong robust stability and good robust performance to improve vehicle stability and handing performance.