钙钛矿型La（0.3）Ca（0.7）FeO3的制备及其电化学性能

采用甘氨酸-硝酸盐燃烧法制备了钙钛矿型复合氧化物La0.3Ca0.7FeO3,并用X-射线衍射分析,扫描电镜,X-射线能谱仪对纳米晶体的晶型、晶粒大小、形貌及组成进行表征.用乙炔黑为载体制备功能氧电极,采用三电极体系,测试循环伏安曲线.结果表明：800℃焙烧2 h得到完整的晶体,晶体粒子大小均匀,粒径为17.9 nm,为菱形晶系;同时该氧电极具有明显的电催化特性.     

Air pollution history elucidated from anthropogenic spherules and their magnetic signatures in marine sediments offshore of Southwestern Taiwan

Kaohsiung City and its neighborhood in the southwestern coastal plain of Taiwan have suffered serious air pollution since the region became the largest center for heavy-industry on the island. In order to unravel the air pollution history of the region, four ²¹⁰Pb- and ¹³⁷Cs-dated sediment box cores recovered in 2006 from offshore of this area were chosen for magnetic and petrographic analyses. The data were used to distinguish changes in concentration, composition and grain size of magnetic particles in the sediments due to inputs of anthropogenic magnetic spherules. Sedimentation rates have been reasonably constant for the last one hundred years, except at the core tops which were affected by a turbidite layer induced by a typhoon in 2005. Down-core profiles of mass-specific magnetic susceptibility (χ) and saturation isothermal remanent magnetization (SIRM) are similar among the cores, and reflect similar trends to magnetic spherule counts. This reveals that χ and SIRM of modern marine sediments can be used as air pollution indicators for nearby industrialized upwind areas. The studied record indicates that industrialization of the area was gradual during 1950–1980 and boomed afterward, resulting in a high production of airborne magnetic spherules, which is consistent with evidence for poor air quality at that time. Optical and scanning electron microscopic (SEM) surveys of magnetic extracts indicate that the magnetic spherules have grain sizes ranging from a few micrometers up to 50 μm and consist mainly of iron oxides with variable Si, Al, and Ca contents. X-ray diffraction analysis on magnetic extracts from different depths in the cores further indicates that magnetite and pyrrhotite, which are derived from terrigenous detritus, form the magnetic constituents of the sediments before the area was industrialized. In contrast, during the industrial boom, anthropogenic magnetite and hematite spherules became the dominant magnetic particles in the sediments. Down-core profiles of hard isothermal remanent magnetization (HIRM) below the turbidite layer also reveal similar trends to the corresponding magnetic spherule counts, which indicate that the concentration of hematite in the sediments is also closely related to the extent of air pollution. In addition, relatively low values of χ_ARM/χ, which are indicative of coarse magnetic grains, started to occur when large magnetite spherules became significant during the industrialized period. The air pollution history elucidated from our sediment core data not only reflects the development of Kaohsiung from a small village to a highly industrialized metropolitan area in the 20th century, but it is also consistent with the most recent air pollution trends revealed by real time air quality measurements of PM₁₀. Our results demonstrate the usefulness of magnetic parameters for delineating the air pollution history of coastal marine sediments down-wind of nearby industrialized regions.     

A study of vibration and vibration control of ship structures

This paper examines the vibration characteristics and vibration control of complex ship structures. It is shown that input mobilities of a ship structure at engine supports, due to out-of-plane force or bending moment excitations, are governed by the flexural stiffness of the engine supports. The frequency averaged input mobilities of the ship structure, due to such excitations, can be represented by those of the corresponding infinite beam. The torsional moment input mobility at the engine support can be estimated from the torsional response of the engine bed section under direct excitation. It is found that the inclusion of ship hull and deck plates in the ship structure model has little effect on the frequency-averaged response of the ship structure. This study also shows that vibration propagation in complex ship structures at low frequencies can be attenuated by imposing irregularities to the ring frame locations in ships. Vibration responses of ship structures due to machinery excitations at higher frequencies can be controlled by structural modifications of the local supporting structures such as engine beds in ships.     

船舶电力推进同步发电机-推进变流器系统谐波特性仿真

对船舶电力推进用同步发电机-推进变流器系统的电压畸变进行了量化分析,建立了该系统的Matlab/Simulink仿真模型,对负载为线性和非线性的两种工况进行了仿真分析,从而确定同步发电机-推进变流器系统中的谐波特性,并针对系统中存在的谐波提出了抑制总谐波及单次谐波畸变的方法.最后,对比分析了仿真谐波畸变值和IEEE标准中规定的畸变值.     

起重船吊重跌落后的动静稳性分析

吊重跌落是起重船作业中可能遇到的严重事故.研究了吊重跌落这种极限载况对起重船舶浮态、静稳性及动稳性等性能的影响.首先建立冲击外力矩作用下船舶横摇运动数学模型,对不同旋转角度下吊重跌落后船舶横摇运动进行仿真.其次介绍BV规范和RINA规范对起重船作业过程中吊重跌落后的稳性衡准要求.最后以某实际起重船为例,分别计算两种典型载况下吊重跌落前后船舶的浮态变化和静稳性校核,实现了吊重跌落后该船的横摇运动仿真.计算结果可为该类工程船的合理设计与安全作业提供理论依据.     

VAHLE U—SMG集成系统在岸桥上的应用

随着集装箱运输船舶的大型化特别是超巴拿马船型的发展,岸桥正朝着大型化、高速化、自动化和智能化发展,由此对岸桥的可靠性、低能耗、低维护成本及各种技术参数提出了更新更高的要求。     

椒江河口航道整治与效果分析

分析了椒江水文、泥沙和河道演变特性,重点介绍支流永宁江建闸前、后椒江航道的整治思想及工程措施,并根据工程实施前后水文测验、河床地形检测成果分析整治效果.     

基于直流区域配电的舰船综合电力系统智能保护方式研究

相对于传统的舰船电力网络,直流区域配电电力网络具有容量大、电能密度大、网络拓扑结构复杂等特点.本文分析了基十时间电流原则的传统保护方法对于直流区域配电电力网络保护的局限性.并从系统论的角度分析了智能保护系统的结构和功能,即数据采集和实时数据库系统实现故障信息的采集、处理,专家系统调用实时数据库、专家数据库,输出决策指令,执行系统快速实现对网络的重构,保护.实例分析表明了该保护方法实现了较好的保护功能.     

船用辅助锅炉监控系统的设计与应用研究

文章应用工控机、PLC以及组态软件构成船用辅助锅炉自控系统,实现了船用锅炉设备的现场流程画面、实时报警、参数实时曲线、生产报表与管理报表以及锅炉的模拟仿真,满足了教学与船员评估训练的需求。