Benzene concentrations on board chemical tankers

Maritime transport of benzene is regulated by the International Maritime Organisation (IMO). Two important guidelines for a ship’s crew in this matter are IMO circulars 1095 and 1220. The first one describes the minimum safety standards for ships carrying liquids in bulk containing benzene while circular 1220 deals with structural guidelines for new ships carrying liquids in bulk containing benzene, but also technical developments could help in improving safety and health protection on board chemical tankers carrying benzene in bulk. The aim of the present paper is to determine the benzene concentration in the working and living environment on board a modern chemical tanker carrying benzene in bulk, where all safety, technical and operational procedures described by IMO in the above-mentioned circulars are followed. During specific cargo operations, we measured the benzene concentrations on different locations on board by means of Radiello® passive diffusive samplers. Despite all measures taken, we found an important difference in benzene concentration between operations with a benzene cargo compared to operations without benzene on board, as well as inside and outside the accommodation. Moreover, even during discharge operations, where the emission is theoretically zero, we found an important increase in the benzene concentration. In addition, we found less favourable results for the engine room.     

Effects of new bus and rail rapid transit systems – an international review

Cities worldwide are implementing modern transit systems to improve mobility in the increasingly congested metropolitan areas. Despite much research on the effects of such systems, a comparison of effects across transit modes and countries has not been studied comprehensively. This paper fills this gap in the literature by reviewing and comparing the effects obtained by 86 transit systems around the world, including Bus Rapid Transit (BRT), Light Rail Transit (LRT), metro and heavy rail transit systems. The analysis is twofold by analysing (i) the direct operational effects related to travel time, ridership and modal shifts, and (ii) the indirect strategic effects in terms of effects on property values and urban development. The review confirms the existing literature suggesting that BRT can attract many passengers if travel time reductions are significantly high. This leads to attractive areas surrounding the transit line with increasing property values. Such effects are traditionally associated with attractive rail-based public transport systems. However, a statistical comparison of 41 systems did not show significant deviations between effects on property values resulting from BRT, LRT and metro systems, respectively. Hence, this paper indicates that large strategic effects can be obtained by implementing BRT systems at a much lower cost.     

Shifting urban freight deliveries to the off-peak hours: a review of theory and practice

This paper presents a comprehensive review of the literature on off-peak hour deliveries (OPHD). The review identifies different approaches and policy levers used in the past, such as the laissez-faire approach, a road pricing approach, an incentives approach, and a regulatory approach. The paper also identifies different delivery reception schemes discussed in the literature. The authors complement the theory with a synthesis of pilot tests and the analysis of a set of interviews with practitioners (from the public sector and other organisations) in charge of OPHD programmes. The results from this review show the potential benefits that these programmes could bring about, the challenges faced in the early stages – along with potential solutions – and the significant progress that has been made in this domain in the last decade. According to the review, the results from the pilot tests tend to be positive, suggesting the importance of these programmes to reach more efficient and sustainable transportation systems.     

Environmental risk assessment of the most commonly transported chemicals: case study of Finnish coastal areas

The environmental hazard potential of a total of 15 chemicals that are transported through the Finnish coastal areas was assessed in this paper using a scoring method developed for accidents. The study indicates that the chemicals most commonly transported/handled in Finnish ports are methanol, sodium hydroxide solution, acids, pentanes, phenol, xylenes, methyl tert-butyl ether, ethanol and ethanol solutions. For the evaluation of the environmental hazardousness of various chemicals, a priority list of chemicals that are the most commonly transported regionally in marine environments was compiled for this study. The method used has many similarities to other commonly used scoring systems, but this study gave more weight to specific characteristics of an accidental release, water biota and impact on the environment. Nonylphenol, ammonia and sulphuric acid ranked as the most hazardous substances on the list. The results of the study can be used by rescue and environmental authorities and enterprises to improve preparedness for accidents and to mitigate the effects of accidental spills.     

CANDY statement of methods

This paper presents a detailed overview of CANDY, a catenary–pantograph dynamic interaction software. Authors describe the main key points of the formulation, focusing on its time-integration scheme, the pantograph and contact models as well as the solution of the initial equilibrium problem. Nonetheless one of the most important features of CANDY is its moving finite element mesh, which enables accurate results without excessive computational cost. The validation of the model against the European Standard EN 50318 and some conclusions and comments about the results of the benchmark are also included.     

Gravity model estimation with proxy variables and the impact of endogeneity on transportation planning

This study presents an alternative method for estimating gravity models by multiple linear regression that is based on proxy variables, thus circumventing the endogeneity problems arising when least-squares estimators are used. The proxy variable approach generates consistent estimators for a gravity model without endogeneity bias. The presence of endogeneity is tested for using statistical tests developed specifically for our application.We conclude that proxy variables eliminate the endogeneity and produce consistent estimators in gravity models estimated using least squares. We also find, however, that endogeneity bias has no significant impact either on gravity model prediction or on urban transportation system planning processes based on such models.     

Heavy metals in edible seaweeds commercialised for human consumption

Though seaweed consumption is growing steadily across Europe, relatively few studies have reported on the quantities of heavy metals they contain and/or their potential effects on the population's health. This study focuses on the first topic and analyses the concentrations of six typical heavy metals (Cd, Pb, Hg, Cu, Zn, total As and inorganic As) in 52 samples from 11 algae-based products commercialised in Spain for direct human consumption (Gelidium spp.; Eisenia bicyclis; Himanthalia elongata; Hizikia fusiforme; Laminaria spp.; Ulva rigida; Chondrus crispus; Porphyra umbilicales and Undaria pinnatifida).Samples were ground, homogenised and quantified by atomic absorption spectrometry (Cu and Zn by flame AAS; Cd, Pb and total As by electrothermal AAS; total mercury by the cold vapour technique; and inorganic As by flame-hydride generation). Accuracy was assessed by participation in periodic QUASIMEME (Quality Assurance of Information in Marine Environmental Monitoring in Europe) and IAEA (International Atomic Energy Agency) intercalibration exercises. To detect any objective differences existing between the seaweeds' metal concentrations, univariate and multivariate studies (principal component analysis, cluster analysis and linear discriminant analysis) were performed. It is concluded that the Hizikia fusiforme samples contained the highest values of total and inorganic As and that most Cd concentrations exceeded the French Legislation. The two harvesting areas (Atlantic and Pacific oceans) were differentiated using both univariate studies (for Cu, total As, Hg and Zn) and a multivariate discriminant function (which includes Zn, Cu and Pb).     

Association of reduced visibility with crash outcomes

Most of the information necessary for driving a vehicle is regarded as visual information. In spite of its importance, visibility conditions at the time of a crash are often not documented at a high level of detail. Past studies have not examined the quantified values of visibility and its association with crashes. The current study merged data collected from the National Oceanic and Atmospheric Administration (NOAA) with 2010–2012 Florida crash data. From the thousands of logged weather events compiled by the NOAA, the researchers isolated periods of normal visibility and comparable periods of reduced visibility in a matched-pairs study. The NOAA data provided real visibility score based on the spatiotemporal data of the crashes. Additionally, the crash data, obtained from Roadway Information Database (RID), contains several geometric and traffic variables that allow for effects of factors and visibility. The study aims to associate crash occurrence under different levels of visibility with factors included in the crash database by developing ordinal logistic regression. The intent is to observe how different visibility conditions contribute to a crash occurrence. The findings indicate that the likelihood of a crash increase during periods of low visibility, despite the tendency for less traffic and for lower speeds to prevail during these times. The findings of this study will add valuable knowledge to the realm of the impact of visibility in the way of using and designing appropriate countermeasures.