Fluxes of dissolved inorganic carbon in three estuarine systems of the Cantabrian Sea (north of Spain)

The diffusive and in situ fluxes of dissolved inorganic carbon (DIC) and total alkalinity (TA) have been measured and an estimation has been made of the water–atmosphere fluxes of CO₂ in three estuarine systems of the Cantabrian Sea during the spring of 1998. Each of these systems undergoes a different anthropogenic influence. The diffusive fluxes of dissolved inorganic carbon and total alkalinity obtained present values ranging between 0.54–2.65 and 0.0–2.4 mmol m⁻² day⁻¹, respectively. These ranges are in agreement with those of other coastal systems. The in situ fluxes are high and extremely variable (35–284 mmol TA m⁻² day⁻¹, 43–554 mmol DIC m⁻² day⁻¹ and 22–261 mmol dissolved oxygen (DO) m⁻² day⁻¹), because the systems studied are very heterogeneous. The values of the ratio of the in situ fluxes of TA and DIC show on average that the rate of dissolution of CaCO₃ is 0.37 times that of organic carbon oxidation. Equally, the interval of variation of the relationship between the benthic fluxes of inorganic carbon and oxygen (F_DIC/F_DO) is very wide (0.3–13.9), which demonstrates the different contributions made by the processes of aerobic and anaerobic degradation of the organic matter, as well as by the dissolution–precipitation of CaCO₃. The water–atmosphere fluxes of CO₂ present a clear dependence on the salinity. The brackish water of these systems (salinity<20), where maximum fluxes of 989 mmol m⁻² day⁻¹ have been estimated, act as a source of CO₂ to the atmosphere. The more saline zones of the estuary (salinity>30) act as a sink of CO₂, with fluxes between −5 and −10 mmol m⁻² day⁻¹.     

A high order linear model for the prediction of internal lee waves at the main sill of the Strait of Gibraltar

A linear theory for the physical fields in the water column under the action of large amplitude internal lee waves at the main sill of the Strait of Gibraltar is developed. The procedure is a combination of the perturbation and normal modes methods in order to study steady resonant conditions. The lowest order linear approach of the methodology resumes the Taylor–Goldstein equation, which can reconstruct the main features of the observed fields but the high order approach gives the finest structure and sometimes the largest contributions. The role of the non-linear terms is investigated up to the second order taking into account the non-linear interactions between modes, leading to an effective reconstruction of the whole water column for the velocity field.     

Hydrographic cruises off northwest Africa: the Canary Current and the Cape Ghir region

We present hydrographic data for several sections located along the African coastline and off Cape Ghir, carried out at times of weak surface winds (October 1995 and September 1997). The main sections are near the continental slope, at mean distances between 100 and 150 km from the coastline. North of Cape Ghir (31°N) the geostrophic transport (referenced to 650 m) of North Atlantic Central Water through these sections is 3.7 and 2.0 Sv for 1995 and 1997, respectively. This confirms that a major fraction of the water transport by the Canary Current flows east, into the continental slope off northwest Africa, at latitudes above Cape Ghir. Most of this flow continues south past Cape Ghir, along the coast and probably through the eastern passages of the Canary Archipelago. A significant fraction, however, may escape through surface Ekman transport (0.3–0.5 Sv during the early fall season) and by offshore flow at Cape Ghir (1.1 Sv in September 1997, referenced to 650 m). Despite the weak winds the Cape Ghir filament was clearly visible, characterized by localized coastal upwelling associated to a cyclonic shallow structure and cold (and fresh) waters stretching offshore as a very shallow feature (50–100 m deep). The satellite images show that the surface temperature field is highly variable, in rapid response to the surface winds, always with a core region of relatively cold water and commonly with one or two associated eddies. Our results support the existence of two recirculation cells in the area: a horizontal one that connects the interior eastern boundary currents with the coastal region and a vertical one related to both wind-induced and filament upwelling. The data also show a salinity subsurface maximum at the root of the filament, linked to water inflow from northern latitudes, and a subsurface anticyclonic eddy over the Agadir canyon, likely related to the poleward slope undercurrent.     

Biologically induced differences in erodibility and aggregation of subtidal and intertidal sediments: a possible cause for seasonal changes in sediment deposition

This study was carried out to describe the difference in erodibility and aggregation in a tidal basin including both subtidal and intertidal study sites and to use these results to explain the shifting erosion/deposition cycles at the sites. Erosion thresholds, erosion rates and settling velocities of the eroded material were measured at a mudflat transect and at sediment cores taken from a nearby tidal channel during surveys made in May 2000 and March 2002. Surface samples were analysed for grain-size, chl. a content, faecal pellet content, dry bulk density and organic content. Additionally, surface samples were taken at eight occasions in the period January 2002 to May 2003 from shallow tidal channels in the area. These samples were analysed for mud content and showed that major shifts in sediment distribution occurred in the period. The erodibility of the mudflat was generally high due to pelletization by the mudsnail Hydrobia ulvae but close to the salt marsh much lower erodibility was found, probably due to stabilisation by microphytobenthos. In contrast, the erodibility of the channel bed seemed to be very little influenced by biological activity and the relatively low erodibility found here was caused by physical characteristics of the sediment. The sediment eroded from the mudflat was generally strongly pelletized and showed high settling velocities whereas less aggregation and lower settling velocities were found for the channel bed sediments. Temporal variations of the mudflat stability and hydrodynamics resulted in temporal variations of deposition and erosion and the changing stability at the mudflat is likely to be one of the main reasons for a general transport of fine-grained sediment from the mudflat to the channel in the cold seasons and vice versa during the rest of the year.     

Assessment of factors associated with travel time reliability and prediction: an empirical analysis using probabilistic reasoning approach

Significant efforts have been made in modeling a travel time distribution and establishing measures of travel time reliability (TTR). However, the literature on evaluating the factors affecting TTR is not well established. Accordingly, this paper presents an empirical analysis to determine potential factors that are associated with TTR. This study mainly applies the Bayesian Networks model to assess the probabilistic association between road geometry, traffic data, and TTR. The results from this model reveal that land use characteristics, intersection factors, and posted speed limits are directly associated with TTR. Evaluating the strength of the association between TTR and the directly related variables, the log odds ratio analysis indicates that the land use factor has the highest impact (0.83) followed by the intersection factor (0.57). The findings from this study can provide valuable resources to planners and traffic operators in their decision-making to improve TTR with quantitative evidence.     

The Bid-rent Land Use Model of the simple,efficient, elegant,and effective model of land use and transportation

Integrated land use/transportation forecasting models add significant policy and infrastructure alternatives analysis capabilities to the urban planning process. The financial, time, and staff requirements to develop these models has put them beyond the reach of most small to medium sized urban areas. This paper presents the land use allocation submodel of the Simple, Efficient, Elegant, and Effective model of land use and transportation (SE³M), an integrated land use and transportation forecasting model founded upon Economic Base Theory and Bid-rent Theory. The Bid-rent Land Use Model (BLUM) is an agent based, spatial competition model utilizing unique utility curves for willingness to pay and incomes for budget constrained abilities to pay for each agent. The model structure, estimation, calibration, implementation, and validation are presented. With a single year of land use data available, the validation approach used the Kappa Index of Agreement to spatially check model outputs against base year control data while controlling for agreement by chance. The U.S. territory of Guam is used as the case study/proof of concept implementation for this model framework. Once calibrated, BLUM could solve the spatial competition problem on Guam in less than two minutes of processing time with over 90% accuracy.     

The structure of dissipation in the western Irish Sea front

We report on an intensive campaign in the summer of 2006 to observe turbulent energy dissipation in the vicinity of a tidal mixing front which separates well mixed and seasonally stratified regimes in the western Irish Sea. The rate of turbulent dissipation ε was observed on a section across the front by a combination of vertical profiles with the FLY dissipation profiler and horizontal profiles by shear sensors mounted on an AUV (Autosub). Mean flow conditions and stratification were obtained from a bed mounted ADCP and a vertical chain of thermistors on a mooring. During an Autosub mission of 60 h, the vehicle, moving at a speed of ~ 1.2 m s^− 1, completed 10 useable frontal crossings between end points which were allowed to move with the mean flow. The results were combined with parallel measurements of the vertical profile of ε which were made using FLY for periods of up to 13 h at positions along the Autosub track. The two data sets, which show a satisfactory degree of consistency, were combined to elucidate the space–time variation of dissipation in the frontal zone. Using harmonic analysis, the spatial structure of dissipation was separated from the strong time dependent signal at the M₄ tidal frequency to yield a picture of the cross-frontal distribution of energy dissipation. A complementary picture of the frontal velocity field was obtained from a moored ADCP and estimates of the mean velocity derived from the thermal wind using the observed density distribution. which indicated the presence of a strong (0.2 m s^− 1) jet-like flow in the high gradient region of the front. Under neap tidal conditions, mean dissipation varied across the section by 3 orders of magnitude exceeding 10^− 2 W m^− 3 near the seabed in the mixed regime and decreasing to 10^− 5 W m^− 3. in the strongly stratified interior regime. The spatial pattern of dissipation is consistent in general form with the predictions of models of tidal mixing and does not reflect any strong influence by the frontal jet.     

Non-local simulation of the stable boundary layer with a third order moments closure model

A new higher order closure model for the stable boundary layer is presented and compared with Large Eddy Simulation data. The model includes numerical solutions for the mean values, second and third order moments equations. A satisfactory agreement is found between the calculated vertical profiles of the turbulent quantities with those provided by the LES. Furthermore the new model results are compared with profiles obtained with a lower order closure model in order to verify the effective importance of including third order dynamical equations in the model.     

The importance of oceanographic fronts to marine birds and mammals of the southern oceans

During the last 30 years, at-sea studies of seabirds and marine mammals in the oceans south of the Subtropical Front have described an association with major frontal areas. More recently, the advancement in microtechnology has allowed the tracking of individuals and investigations into how these marine predators actually use the frontal zones. In this review, we examine 1) the relative importance to apex predators of the different frontal zones in terms of spatial distribution and carbon flux; 2) the processes that determine their preferential use; and 3) how the mesoscale dynamics of frontal structures drive at-sea foraging strategies of these predators. We review published results from southern waters and place them in a broader context with respect to what has been learned about the importance of fronts in oceans farther north.Some fronts constitute important boundaries for seabird communities in southern waters. At a mesoscale the maximum values of seabird diversity and abundance correspond to the location of the main fronts. At-sea surveys show a strong curvilinear correlation between seabird abundance and sea surface temperatures. High mean species richness and diversity for whales and seabirds are consistently associated with the southern water mass boundary of the Antarctic Circumpolar Current, the Subtropical Front and the Subantarctic Front; in the case of the Polar Front mean seabird densities are more variable. At small-scales, variation in seabird occurrence has been directly related to the processes at fronts in a limited number of cases. A significant positive relation was found between some plankton feeding species and frontal temperature gradient–phytoplankton variables.Telemetric studies have revealed that several apex predators (penguins, albatrosses, seals) perform long, directed foraging trips either to the Subtropical front or Polar Front, depending on locality. Seabirds with low flight costs, such as albatrosses, are able to reach fronts at long distances from colonies, showing variable foraging strategies as a function of the distances involved. Diving birds such as King penguins, that travel at a higher cost and lower speed, rely on the predictable spatial distribution of mesopelagic fish found close to the Polar Front. They may use the currents associated with eddies as oceanographic cues in the active search for frontal zones. Once in these areas they dive preferentially in and below the depth of the thermocline where catches per unit effort are high. Elephant seals concentrate foraging activity principally inside or at the boundary of cyclonic eddies. These mesoscale features appear to offer exceptional productivity favourable for foraging by various diving top predators.The connection between biophysical parameters at fronts and predators is likely to be made through biological enhancement. Top predators appear to forage at locations where prey are advected by physical processes and others where prey are produced locally. Long-term research on at-sea distributions and demographic parameters of top predators are essential to assess the consequences of potential shift in front distributions in relation to global warming. Such environmental changes would add to the impact of fish extraction by the industrial fisheries on the southern food webs.     

Influence of the slice position on chloride migration tests for concrete in marine conditions

Chloride migration tests are used to measure the concrete capacity to inhibit chloride attack. Many researchers carry out this test in a slice of concrete extracted from the central part of cylindrical specimens, discarding about 75% of the concrete used to mold the specimens. This fact generated the question: would it be possible to extract more slices from a same specimen without losing the confidence in the results? The main purpose of this work is to answer this question. Moreover, another aim of this study was to show the difference of chloride penetration between finished faces and the formwork surfaces of concrete beams and slabs. The results indicated that it is possible to use more slices of a single specimen for a chloride migration test. Moreover, it was demonstrated that there is a significant difference of chloride penetration between the finished surface and the formwork surface of the specimens.