ICP-AES法测定霍加拉特剂中7种金属元素

采用王水湿式消化处理样品,建立了ICP-AES法同时测定霍加拉特剂中Mn、Cu、Na、Al、Ca、Mg和Fe等7种金属元素的方法。通过谱线选择、条件优化和基体匹配等方法消除元素间干扰和基体效应,探讨了酸类型及酸度值对谱线强度的影响,研究了溶液浓度对精密度及线性相关系数的影响。方法的线性相关系数均大于0.999,Mn、Cu、Na、Al、Ca、Mg和Fe的最佳谱线分别为Mn257.610nm、Cu327.393nm、Na589.592nm、Al396.153nm、Ca317.933nm、Mg285.213nm、Fe238.204nm,相应的检出限分别为0.0008、0.0009、0.012、0.028、0.010、0.001、0.004μg/mL,对应测定值的相对标准偏差分别为0.34%、0.87%、0.87%、0.54%、0.48%、0.84%、0.55%,加标回收率为94.2%～104.4%。该方法简便、快捷、准确,可在测定其他催化剂中金属含量时推广应用。     

一维激波结构的数值分析

建立了一维激波结构模型,对Burnett方程进行简化得到STNM方程,通过在均匀网格上采用二阶空间差分对无量纲化后的STNM方程进行数值计算,得到了激波内部参数变化剖面。以氩气为研究对象对一维激波结构进行数值分析计算。结果表明随着马赫数增大,omage数对于激波结构的影响增大,在相同omage数条件下,马赫数变化对激波内部参数变化的影响显著。     

A frequency-based maritime container assignment model

This paper transfers the classic frequency-based transit assignment method of Spiess and Florian to containers demonstrating its promise as the basis for a global maritime container assignment model. In this model, containers are carried by shipping lines operating strings (or port rotations) with given service frequencies. An origin–destination matrix of full containers is assigned to these strings to minimize sailing time plus container dwell time at the origin port and any intermediate transhipment ports. This necessitated two significant model extensions. The first involves the repositioning of empty containers so that a net outflow of full containers from any port is balanced by a net inflow of empty containers, and vice versa. As with full containers, empty containers are repositioned to minimize the sum of sailing and dwell time, with a facility to discount the dwell time of empty containers in recognition of the absence of inventory. The second involves the inclusion of an upper limit to the maximum number of container moves per unit time at any port. The dual variable for this constraint provides a shadow price, or surcharge, for loading or unloading a container at a congested port. Insight into the interpretation of the dual variables is given by proposition and proof. Model behaviour is illustrated by a simple numerical example. The paper concludes by considering the next steps toward realising a container assignment model that can, amongst other things, support the assessment of supply chain vulnerability to maritime disruptions.     

斜岩岩溶地质钻孔桩施工技术

介绍了湘桂铁路客专横寨特大桥斜岩、岩溶地质钻孔桩施工工艺,重点阐述了钻孔桩施工中出现溶洞、斜岩、地表塌陷等特殊情况的处理方法。     

A shockwave profile model for traffic flow on congested urban arterials

In this paper a new traffic flow model for congested arterial networks, named shockwave profile model (SPM), is presented. Taking advantage of the fact that traffic states within a congested link can be simplified as free-flow, saturated, and jammed conditions, SPM simulates traffic dynamics by analytically deriving the trajectories of four major shockwaves: queuing, discharge, departure, and compression waves. Unlike conventional macroscopic models, in which space is often discretized into small cells for numerical solutions, SPM treats each homogeneous road segment with constant capacity as a section; and the queuing dynamics within each section are described by tracing the shockwave fronts. SPM is particularly suitable for simulating traffic flow on congested signalized arterials especially with queue spillover problems, where the steady-state periodic pattern of queue build-up and dissipation process may break down. Depending on when and where spillover occurs along a signalized arterial, a large number of queuing patterns may be possible. Therefore it becomes difficult to apply the conventional approach directly to track shockwave fronts. To overcome this difficulty, a novel approach is proposed as part of the SPM, in which queue spillover is treated as either extending a red phase or creating new smaller cycles, so that the analytical solutions for tracing the shockwave fronts can be easily applied. Since only the essential features of arterial traffic flow, i.e., queue build-up and dissipation, are considered, SPM significantly reduces the computational load and improves the numerical efficiency. We further validated SPM using real-world traffic signal data collected from a major arterial in the Twin Cities. The results clearly demonstrate the effectiveness and accuracy of the model. We expect that in the future this model can be applied in a number of real-time applications such as arterial performance prediction and signal optimization.     

预切槽技术及其应用中的关键技术问题

随着我国隧道建设的大发展,面临的复杂地质和环境问题以及劳动力紧张问题也越来越突出。预切槽法是一种独特的施工技术,是介于浅埋暗挖法和盾构法之间的一种方法,它和浅埋暗挖法配合可以形成复杂地质和地面环境下的新型隧道施工技术。采用此法可大大提高施工的机械化水平,同时可有效地控制地表沉降。文章论述了预切槽工法的机械组成、控制地层变形的基本原理以及应用中的关键技术问题,相信这种工法必将以其良好的控制地层变形能力和灵活性重新得到重视。     

On the fundamental diagram and supply curves for congested urban networks

Macroscopic fundamental diagrams (MFD) of traffic for some networks have been shown to have similar shape to those for single links. They have erroneously been used to help estimate the level of travel in congested networks. We argue that supply curves, which track vehicles in their passage through congested networks, are needed for this purpose, and that they differ from the performance curves generated from MFD. We use a microsimulation model, DRACULA and two networks, one synthesizing the network for Cambridge, England, and one of the city of York, England, to explore the nature of performance curves and supply curves under differing patterns of demand.We show that supply curves differ from performance curves once the onset of congestion is reached, and that the incorrect use of performance curves to estimate demand can thus seriously underestimate traffic levels, the costs of congestion, and the value of congestion relief measures. We also show that network aggregated supply curves are sensitive to the temporal distribution of demand and, potentially, to the spatial distribution of demand. The shape of the supply curve also differs between origin–destination movements within a given network.We argue that supply curves for higher levels of demand cannot be observed in normal traffic conditions, and specify ways in which they can be determined from microsimulation and, potentially, by extrapolating observed data. We discuss the implications of these findings for conventional modelling of network management policies, and for these policies themselves.     

磁悬浮铁路隧道净空面积及内轮廓的研究

参考国内外磁悬浮列车高速通过隧道引发空气动力学效应的资料,针对TR08常导磁悬浮列车,分隧道长度L≤150 m和L＞ 150 m两种情况,对不同速度目标值下(350 km/h单双线、400 km/h单双线、450 km/h单双线)隧道内轮廓的选取进行了比选分析,分析结果对就磁悬浮铁路隧道轮廓的选取有一定的参考价值.     

基于管片错台的通缝拼装盾构隧道纵向变形安全评估

以上海软土地区通缝拼装地铁盾构隧道为研究对象,根据隧道管片环缝接头处的详细构造,对管片错台模式下的隧道纵向变形进行了研究,建立了隧道纵向结构变形安全评估方法,确定了相应的控制准则和评估流程,形成了一套隧道结构纵向变形的安全评估体系.     

当前铁路隧道施工亟待解决的若干技术问题

高速铁路隧道工程建设标准高,施工难度大,安全风险高,施工管理要求严格。文章以贵广铁路隧道工程为实例,结合当前国内隧道施工技术现状和贵广铁路隧道创新技术的现场实践,研究分析了制约隧道施工安全和施工效率的突出技术问题,取得了一系列研究成果:①基于精细爆破技术的微台阶开挖工艺可有效解决IV、V级围岩隧道开挖进度与工序安全距离之间的矛盾;②得益于通风技术和空气净化技术的进步,无轨运输方式可以适应于长大隧道的施工;③隧道仰拱快速施工设备和隧道沟槽移动模架的开发应用填补了这一领域的空白;④信息化施工是未来隧道施工技术发展的大趋势。