Fe-Mn-Al-Cr合金双极板在模拟PEMFC环境中的电化学性能

采用电化学方法测定一种Fe-Mn-Al-Cr合金在模拟PEMFC环境中的极化曲线以及在PEMFC工作电位下的电流密度随时间变化的曲线.结果表明,Fe-Mn-Al-Cr合金在0.05 mol/L H2SO4＋2 mg/L F-溶液中呈现明显的活化-钝化转变.在恒电位极化过程中,阴极一侧表面能够形成稳定的钝化膜,钝化电流密度低于l6μA.cm-2.而在阳极一侧则产生了大量溶解的金属离子.     

Recycling of aluminum from fibre metal laminates

Recycling of aluminum alloy scrap obtained from delaminated fibre metal laminates (FMLs) was studied through high temperature refining in the presence of a salt flux. The aluminum alloy scrap contains approximately mass fraction w(Cu) = 4.4%, w(Mg) = 1.1% and w(Mn) = 0.6% (2024 aluminum alloy). The main objective of this research is to obtain a high metal yield, while maintaining its original alloy compositions. The work focuses on the metal yield and quality of recycled Al alloy under different refining conditions. The NaCl-KCl salt system was selected as the major components of flux in the Al alloy recycling. Two different flux compositions were employed at NaCl to KCl mass ratios of 44:56 and 70:30 respectively, based on either the eutectic composition, or the European preference. Different additives were introduced into the NaCl-KCl system to study the effect of flux component on recycling result. Although burning and oxidation loss of the alloying elements during re-melting and refining take place as the drawbacks of conventional refining process, the problems can be solved to a large extent by using an appropriate salt flux. Experimental results indicate that Mg in the alloy gets lost when adding cryolite in the NaCl-KCl salt system, though the metal yield can reach as high as 98%. However, by adding w(MgF₂) = 5% into the NaCl-KCl salt system (instead of using cryolite) all alloying elements were well controlled to its original composition with a metal yield of almost 98%.     

Durability of concrete made with manganese slag as supplementary cementitious materials

This paper discusses mineral composition and pore microstructure characteristics of water-cooled manganese slag and its effects on durability of concrete. The Mn slag has an alveolate pore structure, and the ground Mn slag is characterized by multiangular shape which consists of α′-C₂S, C₃MS₂, CaO·MnO·2SiO₂ and C₂AS. Experimental results show that the Mn slag has potential hydraulic reactivity. Concrete made with Mn slag as supplementary cementitious materials (SCMs) exhibits very low strength loss and weight loss in the synthetic seawater corrosion and freezing-thawing cycle tests. The research provides useful reference for knowing about Mn slag and for applying Mn slag to improve the durability of concrete.     

Formation of nanometer coherent structures during spinodal decomposition and ordering coexistence phase transformation in Fe-24Al alloys

The nanometer coherent structure evolution of spinodal decomposition and ordering coexistence phase transformation in Fe-24Al alloys is investigated by the microscopic phase field kinetic model. The results show that the concentration and long-range order parameters all continuously change towards to their equilibrium values during phase transformation. With the increase of elastic interaction energy, the anisotropy along [01] or [10] elastic soft direction is more obvious and the time reaching equilibrium state is also shortened. According to the results, the formation of nanometer coherent structures during phase transformation is composed of the initial decreasing stage of order degree stage, the incubation stage, the continuous increasing stage of concentration order parameter and long-range order parameter, and the later stable stage. The spinodal decomposition and ordering is interaction; the initial ordering stage is a necessary condition of the coexistence phase transformation. The nanometer coherent structures are not found to grow during the whole phase transformation. The simulation results are in accordance with the results in experiment obtained by the aging treatment in Fe-24Al alloys.     

Ni-Mn合金的去合金化

在氩气保护下,应用真空熔炼炉分别制备了Ni30Mn70与Ni55Mn45合金.测定了这两种合金在(NH4)2SO4溶液中的圾化曲线,然后对其进行去合金化实验.结果显示,Ni30Mn70合金在1M(NH4)2S04溶液中去合金化后,试样表面呈现“泥裂”结构.Ni55Mn45在1M(NH4)2S04溶液中不同电位下去合金化...     

锂空气电池研究进展分析

目前,锰酸锂、磷酸铁锂、三元材料锂离子蓄电池由于其能量密度不能满足电动车续驶里程的需要,国外都在积极开发新一代动力蓄电池。2013年1月24日,丰田与宝马宣布进行锂空气电池研究。为此,本期将锂空气电池研究进展分析介绍给大家,供读者参考。     

OXSILAN~工艺 替代传统磷化前处理工艺的应用现状

随着金属表面预处理行业的不断发展,特别是在全球范围内对绿色环保的高度重视,Oxsilan~~对于涂装行业来说,已经不再陌生,如今Oxsilan~已成功地在汽车和汽车零部件行业的涂装工艺中替代了已有百年历史的传统磷化技术,对节能减排、保护环境正在发挥着积极的作用。从工艺角度了解Oxsilan~~工艺     

车用尼龙及其复合材料的性能与应用

尼龙及其复合材料是汽车常用的塑料材料之一,研究其结构与性能有助于扩大其在汽车上的应用.文章以汽车上应用最广泛的尼龙、玻璃纤维增强尼龙、尼龙聚丙烯合金和尼龙丁腈橡胶合金材料为例,分析它们内部结构的不同以及在力学性能上的区别.针对不同材料的不同性能,列举了这些材料制造的具体零部件和使用现状.由于尼龙及其复合材料具有很高的性价比,其应用范围必将不断扩大.今后对尼龙及其复合材料缺陷的优化和改进,将成为这种材料的研究方向.     

合金电缆在污水处理行业的应用前景

通过对比新型合金电缆与传统铜芯电缆的各项技术参数,并结合水处理行业的电缆应用现状,论证了合金电缆在以水处理行业为代表的市政基础设施工程中具有较好的应用前景,并提出了其在实际应用中的设计要点。     

不同微观形貌铁酸锰纳米材料的制备及表征

利用非表面活性剂水热法、醋酸铵溶剂热法和共沉淀法制备了不同微观形貌铁酸锰纳米材料,并进行了扫描电子显微镜（SEM）、X射线衍射（XRD）和傅立叶红外光谱（FTIR）等的形貌和结构的表征.结果表明：非表面活性剂水热法和醋酸铵溶剂热法所制备的产品均为结晶良好的尖晶石型铁酸锰纳米材料,具有金属-氧键的红外特征峰,其微观形貌前者为棒形与块状混合,后者为纳米球.共沉淀法所制备的铁酸锰微观形貌为颗粒状,低浓度OH-（[OH-] =0.5M、1.0M）的反应条件有利于尖晶石型铁酸锰纳米晶的生成.