联萘二甲酸的合成与拆分

光学纯的联萘二甲酸是不对称催化反应的重要催化剂和合成中间体,但由于制备困难,目前并未得到广泛的应用.以廉价的2-甲基萘为原料,经过2次溴代、水解成醇,继而氧化成羧酸,再经酯化、乌尔曼偶联反应、水解得到消旋的联萘二甲酸,然后用奎宁拆分,最终生成光学纯的联萘二甲酸.操作简单安全,原料廉价易得,拆分前总收率为50.8%,最终产品的光学纯度值为99%.     

地网测量仪用数字变频电源设计

利用SPCE061A单片机的片上资源,根据SPWM原理,以高级语言生成波形数据表格,以查表调用的方式提高了变频电源频率合成的速度和精度。电源具有较高的效率,实测表明该电源波形质量好,适合在地网接地电阻测量中应用。     

载人潜水器概念设计中的总体多学科设计模型及分析

介绍了大深度载人潜器概念设计中总体多学科设计模型的建模方法和过程,并开发了总体设计集成程序(Concept Design of Deep Manned Submersible,CDMS),采用7000m载人潜器的设计数据对其进行了测试,验证该模型是可靠的,可用于载人潜器的性能分析和多学科优化设计中。此外,以7000m载人潜器为例,对潜器的重量/浮容积特性进行了分析,讨论了几个主要设计参数对潜器重量/浮容积性能的影响,获得了一些有价值的结论,可供同类型载人潜器总体设计时参考。     

怠速工况下车内结构噪声传递路径分析与控制研究

以控制怠速工况下车内结构噪声为研究目标,采用子结构模态综合法和边界元法建立基于试验仿真数据的传递路径分析模型,分析怠速工况下驾驶员右耳位置20~100Hz频率范围内各路径的激励力及声学灵敏度,计算各路径结构噪声贡献情况。通过对发动机右悬置车身侧支架进行结构改进、提高其1阶固有频率,使怠速工况下目标响应点主要峰值频率最大降幅为3.72d B,整体噪声水平下降2.50d B。     

一种固态聚醚型聚羧酸减水剂的合成及其机理研究

采用自由基本体聚合方法合成了一种便于包装运输储存的固态高效高性能聚醚型聚羧酸减水剂,通过对比实验研究了不同合成因素对水泥净浆流动度的影响关系,并优化了合成工艺.最佳工艺确定为：引发剂用量0.15g,链转移剂用量0.15g,丙烯酸用量8.17g,反应时间2h时,合成的固态聚醚型聚羧酸减水剂的减水效果最佳.采用表面张力,Zeta电位和吸附量初步探究其作用机理,其优异的分散效果主要依靠空间位阻实现.     

基于物元分析的立交方案综合评价方法

针对立交方案的综合评价问题,利用物元分析理论进行研究,提出基于物元分析的立交方案综合评价方法.选取占地面积、通行能力、工程造价、施工难易程度等4大类13个指标作为评价因子,将方案分为优、良、中、一般4个等级,通过确定待评物元、建立节域物元矩阵、经典域物元矩阵,计算各评价因子权重和综合关联隶属度,得到不同方案及各评价因子对4个级别的隶属程度,通过比较选出了整体最优方案.结果表明,将物元分析理论用于立交方案的比选是可行的,不但能够比选出整体最优方案,而且能够分析出各评价因子之间的细微差别,具有较高的精确度.     

基于DDS技术的铁路移频信号发码器

描述直接数字频率合成器DDS(Direct Digital Synthesizer)的组成,构建一种基于DDS的六路铁路信号发码器.分析信号的产生精度.给出系统的硬件框图和软件流程图.     

大型舰船姿态运动极短期预报的一种AR算法

本文提出并严格地证明了一种AR模型的预报算法,利用该算法可对大型舰船运动姿态进行预报,在物理仿真系统中取得满意的结果。     

A generalized partite-graph method for transportation data association

There are many problems in transportation which involve reconstructing the associations between different entities. For example, data points related to a vehicle from different sensors could be matched to reconstruct the trajectories of vehicles. Or, in population synthesis for microsimulation, lists of persons, dwellings, and vehicles could be generated individually from source data and then matched into synthetic households. There are numerous other examples. The unifying theme is a desire to construct realistic unit-level associations from aggregate or anonymized data. The problem demands a method that is behaviorally consistent and operationally efficient to handle large datasets. We adapt concepts from graph theory to formulate this class of problems as a k-partite graph. This approach is generic and can incorporate expectations of behavior in the form of edge weights. A Dijkstra algorithm based solution is proposed for a subset of k-partite graphs which permits a direct comparison with pair-wise matching and applied to a case study of bicycle tracklets. We then propose an iterative improvement algorithm as a generic method and apply it to a complete k-partite graph in a population synthesis case study. The first case study shows that the k-partite algorithm outperforms the previously used pair-wise matching algorithms. The second case study demonstrates the generality of the proposed algorithm to all k-partite graphs and shows that the generic method is fast and scalable to large problems. As a whole, this paper aims to show that k-partite methods are behaviorally consistent, efficient, and potentially applicable to a wide variety of transportation data association problems.     

SYNTHESIS OF THERMAL RESPONSE FACTORS AND Z-TRANSFER FUNCTION COEFFICIENTS FOR CALCULATION OF ROOM TEMPERATURE VARIATION

1IntroductionTheresearchesonthecalculatingapproachtodynamicair-conditioningloadshaveledtoatechnicalrevolutioninthefieldofair-condition-ing.Themethodssuchasthethermalresponsefactormethod(TRFM)andthez-transferfunc-tioncoefficientmethod(ZTFM)areknownbymoreandmoreresearchersandtechnicians.Thedynamicmethodscanbetterreflectthecharac-teristicsofpracticalobjectsthanthesteadymethods,andsomeachievementshavebeenmadeinthedynamiccalculationfield,buttherearestillmanyproblemsthatmustbesolved.Uptonow,ther…