排序方式: 共有124条查询结果,搜索用时 15 毫秒
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介绍了氢气纯化装置的市场需求和国内外技术现状,阐述了QCNB-40/15型全自动高压氢气纯化装置的研制过程,说明了技术路线,阐述了关键技术和技术难点的解决方法.本装置工作在15 MPa下,可以在不放空氢气的情况下.将粗氢一步纯化为99.999%的高纯氢.具有较高的技术优势. 相似文献
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隧道工程穿越区域性含油气地层或煤系地层经常会遇到硫化氢和瓦斯等有毒有害气体。在隧道掌子面前方围岩体内部预注碱液是从根本上去除硫化氢的方法,利用碱液与硫化氢在围岩内部发生化学反应,从而达到固硫的目的。通过分析隧道围岩气-液两相流渗流机理和渗流场-化学场耦合机理,基于Van-Genuchten模型建立考虑硫沉积条件下的围岩气-液两相流渗流场-化学场耦合运移方程,给出解耦方法和计算流程,引入碱液有效饱和度的定义并推导有效饱和度方程。通过对比分析考虑耦合与不考虑耦合条件下、不同注碱压力条件下和不同钻孔布置条件下碱液饱和度、压力和流速分布,研究了围岩注碱固硫和瓦斯抽采的运移规律。研究结果表明,在围岩渗透率较低,硫化氢浓度较高的条件下,隧道掌子面内碱液饱和度在考虑耦合作用时明显低于不考虑耦合作用,应考虑硫沉积堵塞围岩孔隙而造成孔渗结构损伤的影响。注碱压力较小时,碱液饱和度分布局限于隧道掌子面范围内,随着注碱压力的增加,碱液饱和度向隧道围岩深部扩散,碱液压力在5~10 MPa时,碱液均匀向围岩四周扩散,有利于吸收硫化氢和驱替瓦斯,应根据围岩物理力学特性,采用中、低压注入碱液,提高固硫效率。加密钻孔间距可显著提高隧道掌子面内碱液压力和流速分布,验证了同等条件下,小间距钻孔布置具有较高的渗流能力和瓦斯驱替能力,实际工程中应根据围岩地质条件,通过数值模拟和现场试验,综合对比钻孔布置的经济性与注碱固硫的效率来确定钻孔间距和数量。研究成果可为富硫化氢和瓦斯隧道的灾害治理提供参考。 相似文献
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Jing-quan Deng Peng-liang Hou 《西安交通大学学报(英文版)》2009,21(1):46-48
Annealing of carbon nanotubes (CNTs) by the hydrogen flame in air was investigated in this study. Raman spectroscopy and scanning electron microscopy were used to characterize the products. The peak width of Raman spectra decreased with the increase in the annealing time. The CNTs were not stable in the hydrogen flame and the etching rate of the CNTs by hydrogen flame was very high. The hydrogen flame annealing had some effects on improving the crystallinity of CNTs. 相似文献
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污染物排放研究一直都是燃气轮机燃烧室的热门课题。本文研究了短环形燃烧室分别混烧氢气和裂解气后对NOx排放的有利影响和不利影响。添加的氢气质量分数分别为1%和10%,添加的裂解气质量分数分别为1%、10%和15%。比较了使用不同燃油方案的燃烧室流场结果,分析了燃烧效率、出口温度、NOx排放与其他燃烧室性能参数。结果证实氢气可有效改进燃烧效率,但同时其易燃性与极快的化学反应速度又会导致火焰温度升高以及NOx排放量增大,这一点违背了降低排放的初衷。而混烧裂解气既可保留氢气的优点,同时组分水蒸气的存在又能吸收高温区部分热量,降低火焰温度,有利于降低NOx排放。从而使得燃烧室在保持较高的燃烧效率和较低的出口温度的同时,NOx排放量不会剧烈增加。 相似文献
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Escalating apprehension about the harmful effects of widespread use of conventional fossil fuels in the marine field and in internal combustion engines in general, has led to a vast amount of efforts and the directing of large capital investment towards research and development of sustainable alternative energy sources. One of the most promising and abundant of these sources is hydrogen. Firstly, the use of current fossil fuels is discussed focusing on the emissions and economic sides to emphasize the need for a new, cleaner and renewable fuel with particular reference to hydrogen as a suitable possible alternative. Hydrogen properties, production and storage methods are then reviewed along with its suitability from the economical point of view. Finally, a cost analysis for the use of hydrogen in internal combustion engines is carried out to illustrate the benefits of its use as a replacement for diesel. The outcome of this cost analysis shows that 98% of the capital expenditure is consumed by the equipment, and 68.3% of the total cost of the equipment is spent on the solar photovoltaic cells. The hydrogen plant is classified as a large investment project because of its high initial cost which is about 1 billion US$; but this is justified because hydrogen is produced in a totally green way. When hydrogen is used as a fuel, no harmful emissions are obtained. 相似文献
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目的探讨氧化应激在大鼠弥漫性轴索损伤(DAI)中的作用及氢气对其治疗作用。方法将118只SD雄性大鼠随机平均分为假手术组、DAI模型组和氢气干预组。采用头颅瞬间旋转损伤装置制作大鼠DAI模型,干预组每日2次腹腔注射高纯度氢气(10mL/kg)。各组于预定时间点行神经功能评分、组织形态学、碘化丙啶(PI)染色及脑组织超氧化物歧化酶(SOD)、过氧化氢酶(CAT)活力和丙二醛(MDA)含量检测。结果与假手术组比较,DAI后脑组织MDA含量升高(P<0.01),SOD及CAT活力下降(P<0.01),神经细胞肿胀,大量神经元变性、坏死,胶质细胞增多,PI阳性细胞增加(P<0.01),神经功能缺损加重(P<0.01)。给予氢气干预后脑组织MDA显著下降(P<0.01),SOD及CAT活力增强(P<0.01),组织形态学观察改善,PI阳性细胞数减少(P<0.01),神经功能缺损改善(P<0.05)。结论氧化应激参与了DAI急性期脑损伤的病理生理过程,自由基的大量产生及抗氧化酶活力的下降可能导致脑损伤的加重;氢气通过改善抗氧化酶活力并减轻自由基损伤改善DAI急性期脑损伤。减轻氧化应激程度对DAI急性期脑保护具有重要意义。 相似文献