微波溶样/原子吸收法测定铁路危货站固体废弃物中的重金属

参照美国ＥＰＡＳＷ８４６规定的标准方法，采用Ｑ－４５型微波溶样系统消解样品，原子吸收法测定铁路桃浦危险品货站固体废渣原样、浸滤渣样、浸提液样中的重金属Ｂｅ、Ｃｄ、Ｃｒ、Ｃｕ、Ｎｉ、Ｐｂ、Ｚｎ。研究了样品的消解条件、分析的最佳条件。各元素精密度实验的相对标准偏差在０．５４％～１２．８％，标准土样的测定回收率在７６．４９％～１０３．３３％。并报告了对上海铁路局桃浦危货站现场样品的测定结果。     

船用惰性气体系统设计指南

0 前言利用锅炉烟气产生惰性气体,使货油舱惰性化,以达到防爆的方法,首先是美国石油公司于1925年提出的。但直到1932年,美国的一艘油船发生爆炸后,惰性气体才开始被用作油船的安全装置。1961年英国参考了美国的做法,也将该装置用于油船的安全防护。日本虽然在战前已采用惰性气体系统,但真正现代     

溶质原子晶界偏聚动力学模型

本文在现有晶界偏聚热力学和动力学模型的基础上，根据热力学定律、非克扩散定律及局部平衡理论，溶质原子晶界偏聚动力学模型。该模型既适合于平衡偏聚或非平衡偏聚的动力学计算，也适合于混合偏聚（平衡偏聚＋非平衡偏聚）的动力学计算。计算结果和有关实测结果基本符合。     

原子吸收光谱法在中草药微量元素及重金属分析中的应用

文中对近十年来原子吸收光谱法在中草药微量元素和重金属中的分析应用进行了综述,对原子吸收光谱法测定中草药中微量元素的应用实例进行了归类和总结.同时,对当前应用原子吸收光谱技术测定中草药微量元素常用的样品前处理方法也进行了归纳,并分析了它们的优点与不足.此外,还着重介绍了中草药中微量元素形态分析的方法和意义,并针对目前原子吸收光谱法的某些不足,阐述了该方法未来的发展方向.     

发Zn、发Cu与克汀病区不明原因儿童智能低下的关系初探

本文应用原子吸收光谱法及荧光法测定了安康克汀病区不明原因智能低下儿童与西安市正常儿童头发中7种微量元素(Zn、Cu、Mn、Pb、Fe、Cr、Se)的含量.结果发现,发Zn、发Cu 受地域及环境因素影响甚大;低Zn、低Cu 可能是致病的重要因子;Cu/Zn 比值显著升高可能是患儿的重要征兆。     

THE STUDY ON THE CHANGES OF ZINC, COPPER, CALCIUM AND MAGNESIUM IN PLASMA AND ERYTHROCYTES DURING CARDIOPULMONARY BYPASS

Objective To study the changes and their influence factors involved of zinc, copper, calcium and magnesium in plasma and erythrocytes during cardiopulmonary hypass(CPB). Methods Zinc, copper, calcium and magnesium values in plasma and erythrocytes were measured by atomic absorption spectrophotometer during CPB. Results Zinc and copper levels in plasma were significantly elevated above preinduction level before perfusion, hut calcium and magnesium levels did not change significantly; zinc, copper and calcium levels in plasma were significantly below preoperation level during CPB, hut magnesium level in plasma was significantly increased above preoperation; zinc level in plasma was increased to preoperation level after CPB and began to decrease again at 8 hours after CPB,copper level in plasma was increased to preoperation level at 20 hours after CPB, calcium in plasma was increased significantly from beginning to 8 hours after CPB, magnesium level in plasma was decreased to preoperation level at 8 hours afterCPB. Concentration of zinc , copper, calcium and magnesium in erythrocytes did not change significantly. Conclusion During CPB, the changes of zinc, copper, calcium and magnesium had relation to hemodilution, operative wound, carrier protein, stress and component of priming Solution and cardioplegic solution, hut no relation to transferfrom plasma erythrocytes. The results indicate that it is beneficial to patient‘s recovery to supplement zinc, copper, calcium and magnesium properly by different ways during cardiac perioperation.     

一种无需化学前处理的固体分析技术

1 辉光放电技术的原理 辉光放电技术是基于惰性气体在低气压下的放电原理而发展起来的分析技术.     

NMR Structural Studies on Alamethicin Dimers

IntroductionAlamethicinisanantibioticmembrane active peptide producedbythesoilfungusTrichodermaviride .Thepeptideisrichinα aminoisobutyricacid (Aib) ,hasanalcoholicC terminus ,andissometimecalledapeptaibol[1] .Theprimarysequenceofthealamethicinmoleculeus…     

微波场驱动的近简併Λ型三能级原子的发射谱

用时间演化算符方法研究了理想腔中近简併Λ型三能级原子在微波驱动场作用下的发射谱.讨论了增大或减弱驱动微波场对原子发光谱的影响,及谱对Λ型三能级原子两个下能级裂距的依赖关系.     

小型液货船惰性气体系统最新动向

防止油船和化学品船火灾及爆炸事故一直是IMO关注的问题,同时也是油轮公司和化学品船公司日常安全管理的重点之一。液货船(包括油船、化学品船和液化气体船)在海上航行或在货物操作期间,可能发生各种不可预测的因素,存在着很多巨大的火灾或爆炸危险性。为确保安全,避免航行及货物操作期间各种不可预测因素的影响,只有在液货船,如油船上安装惰性气体系统,并对船员作全面培训,才能减少甚至防止事故的发生。