催化分解二茂铁制备碳纳米片及其结构表征

以二茂铁为催化剂和碳源,硫粉为辅助剂,采用催化分解技术,在500°C时制备碳纳米片,成炭率高达95％左右．结构测试结果表明：酸处理后的主要产物为非晶碳纳米片,其厚度约为40 nm．氮气吸附脱附结果表明：合成的碳纳米片为介孔材料的特征吸附脱附等温线,比表面积为41.1 m2/g,孔径主要集中在3.5～5 nm．     

纳米水化硅酸钙在免蒸养轨道板中的应用研究北大核心

采用水化微量热仪等测试手段研究了纳米水化硅酸钙(N‑C‑S‑H)对水泥水化及砂浆抗压强度的影响,并开展了基于N‑C‑S‑H的免蒸养轨道板的试应用。结果表明:掺加N‑C‑S‑H能提高水泥的水化放热速率和总水化放热量,且当N‑C‑S‑H掺量超过6.0%后,水泥水化放热第二峰值不再继续提高;掺加N‑C‑S‑H能显著提高砂浆8 h和12 h抗压强度,且随着N‑C‑S‑H掺量的增加,砂浆抗压强度先提高后降低;在25℃养护条件下,掺加1%N‑C‑S‑H可达到轨道板混凝土免蒸养强度要求。     

An ionic liquid supported CeO2 nanoparticles-carbon nanotubes composite-enhanced electrochemical DNA-based sensor for the detection of Pb2＋

An electrochemical sensor incorporating a signal enhancement for the determination of lead （II） ions （Pb2＋） was designed on the basis of the thrombin-binding aptamer （TBA） as a molecular recog- nition ...     

纳米TiO2改性沥青抗光老化性能研究

选用纳米TiO2对沥青进行改性.采用自制紫外光源环境箱对基质沥青和改性沥青进行紫外线光老化试验,根据光老化前后沥青性能指标的变化,研究纳米TiO2对提高沥青抗光老化性能的作用.结果表明,紫外光照射后,改性沥青的低温延度明显高于基质沥青,且光照前后软化点的变化率也低于基质沥青,说明掺入纳米TiO2能明显提高沥青的抗光老化...     

舰船舱室环境对分子筛负载纳米TiO2分解甲醛性能的影响

采用密闭实验舱模拟舰艇舱室环境。以分子筛负载纳米TiO2的分解效率为依据,考察了其对甲醛的催化分解性能。结果表明,纳米TiO2的分解效率随着温度的上升而显著提高,随湿度的升高而降低,光照强度对纳米TiO2的催化效能影响不大,而过高的甲醛初始浓度也会降低纳米TiO2的分解效率。     

纳米二氧化钛改性沥青混合料路用性能研究

为了解纳米二氧化钛改性沥青混合料的路用性能,通过纳米二氧化钛改性沥青混合料的残留稳定度试验、高温车辙试验和低温弯曲试验,分析了纳米二氧化钛改性沥青混合料的综合路用性能。结果表明:纳米二氧化钛粉粒可以全面改善沥青混合料的路用性能。     

Oleanolic acid-induced apoptosis and its relation with intracellular calcium in human lung adenocarcinoma A549 cells

Objective To investigate the effect of oleanolic acid (OA) on apoptosis, correlation between apoptosis and intracellular calcium, and its mechanism in human lung adenocarcinoma cell line A549. Methods Human lung adenocarcinoma A549 cells were incubated in vitro and assigned with OA concentrations of 0, 10, 20 and 40μg/mL. The apoptosis status of A549 cell line was detected with Annexin V-FITC/PI by flow cytometry (FCM); fluorescence intensity (FI) of A549 cells was assessed and the level of intracellular calcium was calculated at 24 hour of OA intervention. The relation between apoptosis and calcium FI was illustrated by curve fitting. Results FCM showed that 10, 20 and 40μg/mL of OA could induce A549 cell apoptosis, which followed a concentration-effect pattern; 24-hour intervention with 20μg/mL and 40μg/mL OA showed increased A549 cell apoptosis, and was significantly different from that with 0μg/mL OA (P<0.01). The FI of intracellular calcium concentration in 10, 20 and 40μg/mL OA groups was significantly higher than that in 0μg/mL group after 24 hours' intervention, and the FI showed a trend of increase with increased OA concentration (P<0.01). Curve fitting showed a significant correlation between apoptosis rate and intracellular calcium concentration in A549 cells (r=0.981, P<0.01). Regression equation was Y=0.508X-1.627. Conclusion OA plays a role in inducing apoptosis of human lung adenocarcinoma cells in a concentration-dependent manner. The OA-induced apoptosis is responsible for intracellular calcium overload of the tumor.     

Eu(DBM)3Phen/PS复合纤维的制备与发光性能

采用静电纺丝法与无皂乳液法相结合制备了稀土配合物/聚合物复合纳米纤维Eu(DBM)3Phen/PS.采用扫描电镜(SEM)、红外光谱(FT-IR)和荧光光谱(FS)等,对纤维的形貌和发光性质进行了表征.实验结果表明,随着PS浓度的增加,所制备的纤维直径逐渐增大,纤维的发光强度也逐渐递增,荧光寿命逐渐增长.     

复合纳米二氧化钛的制备及光催化降解罗丹明B

以Ti(OC4H9)4和Si(OC2H5)4为原料,采用溶胶-凝胶法制备纳米TiO2-SiO2复合材料.通过光催化降解罗丹明B实验,确定制备纳米TiO2-SiO2复合材料的最佳条件,即Ti:Si=1:0.5,煅烧温度为500℃,制备溶胶pH取5～6.通过SEM测试,发现纳米复合材料的基本粒子为分散均匀的球形颗粒状结构;XRD分析结果表明,复合材料中TiO2主要以锐钛矿晶型存在,颗粒粒径在10～30 nm.光催化降解实验表明,按照最佳条件制备纳米TiO2-SiO2复合材料的光催化降解效果较好,在日光照射90min后,对罗丹明B的降解率可以达到100%.