潜艇液体除湿空调系统探讨

液体除湿空调克服了传统空调除湿与制冷能力不匹配的问题,因而受到广泛关注。针对潜艇舱内的热湿环境,分析了液体除湿空调系统应用于潜艇的可行性,在综合考虑潜艇舱室空间布局和系统节能性要求的基础上,提出为目前的空调系统增加除湿剂循环系统,并根据系统的要求分析工作原理,改进空调器的设计,甄选除湿剂类型,解决除湿剂再生的难题,设计出一种满足潜艇舱室环境要求的液体除湿空调系统,实现潜艇舱室低耗安静除湿功能。     

高液限红黏土CBR试验

加州承载比CBR(California Bearing Ratio)是国际上普遍认同的在公路工程中广泛使用的一个性能指标,是评价路基土和路面材料强度特性的主要依据。采用路面材料强度仪做了未泡水的CBR试验、泡水1昼夜、2昼夜和4昼夜的CBR试验。结果表明,随着土样含水率的增大,高液限红黏土未泡水CBR值先增大后减小,在最佳含水率CBR值达到最大。未泡水CBR值与压实度有着良好的相关关系,即CBR=-0.969 2x2+190x-8 932.7,R2=0.999 9;无论是泡水1昼夜、2昼夜还是4昼夜,CBR值与含水率关系曲线平缓,试样初始含水率对CBR值影响较小;随着泡水时间的增长CBR值降低幅度较大,泡水1昼夜、2昼夜CBR值能满足规范要求,泡水4昼夜CBR值不能满足规范中各等级公路对CBR值的要求。     

高液限粘土路用填料的改良研究

为了对高液限粘土进行路用填料改良研究,分别对其进行了石灰、粉煤灰、水泥、石灰加粉煤灰以及砂砾的改良试验。试验结果表明,高液限粘土采用4％,5％的石灰改良后,CBR值分别为原土的12.5,14.3,14.7和16.1,15.6,16.0倍;经粉煤灰改良后的高液限粘土CBR强度改善不明显;采用3％,4％的水泥改良后,高液限粘土CBR值分别为原土的9.0,9.0,9.2和12.3,12.8,13.8倍;石灰和粉煤灰联合改良后,高液限粘土CBR值分别为原土的6.5,7.1,8.1和15.0,15.8,16.8倍。     

绍兴地区软土工程特性研究

软土具有特殊的物理力学性质。通过对绍兴地区的地层分布调查和现场勘查测试,研究了该区软土的物理力学特性。运用回归分析手段研究了各物理力学指标之间的相关关系。     

高液限红粘土变形特性研究

为了研究红粘土路基的沉降特性,基于一维室内固结试验,分析了高液限红粘土变形特性。引入压缩变形系数,分析了高液限红粘土的物理指标对变形指标的影响,采用应变法来表达压缩变形曲线结果。引入非线性应力、应变关系的割线模量,研究了高液限红粘土的加荷本构模型和增(减)湿本构模型。结果表明:压缩变形系数随含水量的增大而增加,当含水量大于最佳含水量2%~3%后,压缩变形系数随含水量的增加增长幅度迅速变大;压实度越大,压缩变形系数越小,低压实度高含水量的情况下,压缩变形系数显著增大;压缩系数随含水量的增加而增大,压缩系数随压实度的增大而减小;高液限红粘土的应力-应变关系可以用幂函数的形式来表达。提出了高液限红粘土加荷本构模型和增(减)湿本构模型,该模型具有较高的可靠性,为研究红粘土路基沉降特性提供了有力依据。     

Electrocatalytic oxidation and determination of dopamine at a carbon ionic liquid electrode modified with nafion-L-aspartic acid composite film

The electrocatalytic oxidation of dopamine (DA) was studied by electrochemical approaches at a carbon ionic liquid electrode (CILE) modified with the composite film of nafion and L-aspartic acid (NL-CILE). The CILE was fabricated by replacing non-conductive organic binders with a room-temperature hydrophobic ionic liquid, 1-butyl-3-methyl-imidazolium hexafluorophosphate. The composite film of NL was used as matrix to adsorb DA and catalyze the oxidation of DA in phosphate buffer solution (PBS). The electrochemical response of DA was investigated at the NL-CILE, the traditional carbon paste electrode (TCPE), CILE and the nafion modified CILE (N-CILE) in 0.1M PBS (pH 7.4), respectively. The results showed the superiority of NL-CILE to N-CILE, CILE and TCPE in terms of provision of higher sensitivity, faster electron transfer and better reversibility. Under optimum condition, the oxidation peak current was rectilinear with DA concentration range from 0.1μM to 0.1mM, with a detection limit of 0.03μM (S/N=3) by differential pulse voltammetry. The proposed method was applied to determine DA in samples successfully.     

Analysis of ganciclovir and its related substances using high performance liquid chromatography and liquid chromatography-mass spectrometry methods

Objective High performance liquid chromatography (HPLC) and liquid chromatography-mass spectrometry (LC/MS) methods were developed for the determination of ganciclovir and its related substances. Methods A Hypersil ODS2 column (4.6mm×250mm, 5μm) was used with a mobile phase of 0.02M potassium 1.0mL/min, and UV detector set at 254nm was used for monitoring the eluents. Results The method was simple, rapid, selective and capable of separating all related substances at trace level with a detection limit of 0.04μg/mL. It has been validated with respect to accuracy, precision, linearity, and limits of detection and quantification. The linearity range was 10.2-153.0μg/mL with r=0.9998. The percentage recoveries ranged from 96.7% to 101.6%, and RSD was 1.24%-1.96% (n=5). Conclusion The method was found to be suitable not only for monitoring the reactions during the process development but also for quality control of ganciclovir. For identification of related substances, LC/MS was used. The mainly related substances of ganciclovir active pharmaceutical ingredients (API) were determined as guanine, (1, 3-dioxolan-4-yl) methyl acetate, and diacetyl guanine.     

高液限土路堤病害机理分析及处治措施

高液限土土性较差,用于修筑路堤容易产生失稳、沉陷等破坏。本着安全有效地利用该类资源,节约换填好土所带来的经济损耗的目的,对高液限土路堤病害机理进行分析,提出利用高液限土修筑路堤的处治建议,以保证高液限土路堤的稳定性,并改善其变形特性。     

重复荷载作用下高液限粘土路基永久变形特性分析

重复荷载作用下高液限粘土路基的永久变形对道路正常运行有较大影响。结合FALC3D软件,建立高液限粘土（路堤）及其水泥改良土（路床）的路基弹塑性本构模型,分析路基在不连续半正弦波荷载下产生的动力响应。分析结果表明：在重复荷载作用下土体的永久变形逐渐累积,随着加载次数增加,初始屈服面不断增大,最后趋近于最大加载面;在重复荷载作用下,土体变形在荷载作用初期变形较大,随着荷载重复次数的增加,变形速率逐渐减小;水泥改良后的高液限粘土路床具有抵抗变形能力。该研究对于高液限粘土地区的高速公路建设具有重要的理论意义和实际价值。     

低液限土的冲击压实特性分析

针对高速公路低液限土的特点,采用不同冲击振动压路机组合工况进行试验,碾压后测量压实度评价低液限土的压实效果.研究表明:采用冲击压实技术能够达到低液限土的压实需求,比普通压路机的组合压实效果提高了5％左右,为工程应用提供了可靠依据.