Mechanical properties and residue stress of four kinds of ZrC coatings prepared by chemical vapor deposition

Four kinds of ZrC coatings with nearly the same thickness have been successfully prepared on graphite substrate by chemical vapor deposition (CVD) through controlling the ratio of inlet reacting gases. From backscattered electron images, it can be inferred that ZrCIII coating has the best tightness of all coatings. Meanwhile, line energy spectrum curve shows that zirconium and carbon elements distribute uniformly along the normal direction of the ZrCIII coating. As for varied microstructures, the coatings show different mechanical properties and residue stress. The strength and elastic modulus of ZrCIII coating were up to 89.57 and 1 192.5GPa, respectively. Those make it near the level of diamond. Value of residue tensile stress of ZrC+C composite coating was only 7.729MPa and that of ZrCIII coatings was 349.632 MPa. The strong combination of small-size grains in ZrCIII coating plays a decisive role to the best mechanical properties. However, strong misfit of lattice between ZrCIII coating and substrate can induce high residue stress.     

Microstructure of hot-dip galvanized Zn-Al-Mg alloy coating

The microstructure of hot-dip galvanized Zn-11%Al-3%Mg-0.2%Si alloy coating was studied in this article. X-ray diffraction analysis revealed the coating is composed by Zn, Al and MgZn₂ phase. Optical microscope (OM) and scanning electron microscope (SEM) observations showed the coating is occupied by snowflake-like dendrite, double hexagonal organization and eutectic. The coating backbone was the dendrite considered to be a phase of hexagonal close-packed (HCP) structure judging form its morphology according to the crystal growth way in the coating. Transmission electron microscopy (TEM) and energy dispersive spectroscopy (EDS) researches on the dendrite suggested that an intermediate Zn-Al phase was formed at high temperature, then decomposed into a type of Zn-Al granular eutectoid after cooling down to room temperature, while the eutectoid Zn and Al had a certain crystallographic relationship. The coating solidification process and the grain crystal structure were discussed.     

磷酸盐皮膜结晶结构与其各种物性的关系

为研究磷酸盐皮膜结晶结构与其各种物性之间的关系,对磷酸锌皮膜主要成分(磷酸锌和磷酸铁锌)的结晶结构进行了分析。结果表明:两者晶体结构基本相似;结晶水是与6配位的锌结合在一起,如果此部位的锌被其他金属置换后,结晶水的结合状态将发生变化,从而引起结晶水脱离温度以及耐碱性也发生变化;皮膜从4水盐脱水变成2水盐时,在厚度方向上将产生收缩等。     

哈萨克斯坦第三油气处理厂厂外管道防腐设计

介绍了哈萨克斯坦第三油气处理厂厂外管道防腐工艺的选择,根据管线穿越土壤的介质和管线规格数量,选择了3PE外防腐层加阴极保护的联合保护方案,并提出了施工要求.投入运行后,效果良好.     

船舶上层建筑涂料消耗控制方法

为控制船舶上层建筑建造成本,减少上层建筑建造中的涂料消耗,以某海洋工程上层建筑的涂装项目为例,对油漆用量进行统计,分析影响上层建筑涂料消耗偏高的因素,针对主要影响因素提出改进方案,实现船舶上层建筑建造成本的控制.     

雪灾对接触网覆冰及其影响的探讨

2008年初的严重冻雨气候使得接触网和电力架空线路覆冰严重,给正常运行造成极大困难,个别地方出现了独立锚柱拉断的现象.如何提高接触网抗击雪灾能力,确保电气化铁道在恶劣气候条件下正常运行是设计人员今后必须面对的问题.     

特种功能涂料在轨道交通车辆上的应用

介绍了阻尼涂料、防滑涂料、防火涂料、抗结冰涂料等特种功能涂料在轨道交通车辆上的应用,同时总结了各特种功能涂料的特点及技术要求。结合涂料行业的环保发展趋势,讨论了特种功能涂料的环保发展方向。     

跨海桥梁混凝土结构耐久性设计

近年来的桥梁设计十分重视提高结构物的耐久性并将其作为重要的设计原则,统一考虑合理的结构布局和构造细节。海南清澜大桥是较长的跨海桥梁,该桥梁结构的耐久性设计成为设计中的难点和重点。结合工程实践阐述结构耐久性设计的具体措施和设计要点。     

无溶剂超厚膜环氧涂层海洋腐蚀模拟试验研究

超厚膜重防腐涂料具有优异的防腐性能以及环境友好的特点,是海洋环境防腐涂料的重要发展方向。文中介绍了一种新型的无溶剂超厚膜环氧重防腐涂料,测试了涂层的物理性能,并采用海洋腐蚀模拟试验装置对该涂料以及常用的三种重防腐涂料在海水浪花飞溅区、潮差区和全浸区的耐久性进行了对比研究。结果表明:该涂料具有优异的物理性能,VOC含量极低,是环境友好型无溶剂涂料;模拟试验表明浪花飞溅区是海洋腐蚀最严酷的区域,各涂料在该区域腐蚀最严重,超厚膜环氧重防腐涂料的防腐效果最优,是环氧沥青涂料的理想替代品。     

秦巴山区中草药治疗非特异性溃疡性结肠炎的实验研究及临床观察

作者以秦巴山区中草药为主组方,制成多种剂型,应用于不同病变部位,20年来治疗慢性非特异性溃疡性结肠炎359例,总有效率:灌肠加栓剂组96%;单纯灌肠组94.1%;口服溃结灵肠溶胶囊组87.5%;外用栓剂组89%,对照组(补脾益肠丸)65%,实验组与对照组有明显差异(P<0.005),治疗前后经结肠粘膜活检材料电镜观察病变明显改善。药物抑菌实验证明对多种细菌有中度抑菌作用;药理证明对离体家兔、豚鼠肠管收缩有缓慢抑制作用,因而这一方药具有止痛、止泻及消炎作用。