键合纤维素衍生物手性固定相的合成及手性拆分

采用包夹聚合法,将纤维素(10-十一烯酸酯/3,5-二甲基苯基氨基甲酸酯)键合于乙烯基硅胶上,制备了键合纤维素(10-十一酸酯/3,5-二甲基苯基氨基甲酸酯)手性固定相(简称为键合纤维素(3,5-二甲基苯基氨基甲酸酯)(键合(CDMPC-CSP)),并对其进行了表征.分别以正己烷/异丙醇、正己烷/四氢呋喃、正己烷/三氯甲烷为流动相,对键合CDMPC-CSP的手性识别能力进行了评价.实验结果表明,键合CDMPC-CSP具有一定的手性识别能力,可以拆分所研究的8种手性化合物中的4种.     

高速电气化铁路的接触网电分相型式探讨

根据目前关节式电分相存在问题，提出一种新型的3个绝缘锚段关节双中性段关节式电分相型式，有效地克服了目前双锚段关节单中性段关节式电分相存在的问题，可较好解决关节式电分相对电力机车受电弓多弓运行条件的限制。     

Spatial distribution of cadmium over a cyclonic eddy in the southern East China Sea

Eddy systems are a unique ecosystem, usually having high biological masses and primary production in the sea. In this study, both particulate and dissolved phases of cadmium in the water column of 15 stations over a cyclonic eddy in the southern East China Sea were determined to obtain their spatial distributions. This allows us to confirm that cyclonic eddy systems play the role of a Cd pump in the sea.Results showed that particulate Cd (PCd) and dissolved Cd (DCd) concentrations in water varied greatly, ranging over two orders and one order of magnitude, respectively. Large spatial variability was found not only for PCd but also for DCd in the upper water, apparently due to the effects of the cyclonic eddy system on the Cd distributions over the study area. DCd accounts for about 99% of the total Cd. For the surface water, DCd concentration at the eddy center was about five times the average of the water surrounding the eddy center. The depth distributions of DCd exhibited a typical surface depletion and a subsequent increase with depth; however, the PCd distribution showed the opposite, i.e. a surface maximum and a subsequent decline with depth. In general, the DCd maxima were found at depths of 600–1000 m, agreeing well with the literature. It reflected the internal biogeochemical cycling of Cd in the water column, which was driven by the utilization of Cd by plankton in the euphotic zone and by the regeneration of Cd at depth. In addition, a remarkably high DCd concentration existed in near-bottom water around the cyclonic eddy center.The horizontal distributions of both PCd and DCd in the upper water shared a common feature with elevated concentrations centering around the eddy center and a decline in concentration with distance from the eddy center. This shows that the cyclonic eddy could bring up the Cd-rich deep water to the surface water around the eddy center and could then expand toward eddy's vicinity via advection–diffusion. It is thus likely that it produces ample biological masses over the eddy system. Hence, this work can demonstrate that the ascending nutrient-rich water driven by the cyclonic eddies can serve as an important source not only for many nutrients but also for Cd in the sea.     

DVVT对缸内直喷增压发动机性能影响的试验研究

通过对GDI增压发动机进行DVVT扫点试验,研究了DVVT对GDI增压发动机外特性性能、部分负荷燃油经济性和怠速稳定性的影响。试验结果表明:对于试验发动机的凸轮轴型线而言,排气VVT的开启对发动机性能起到负面影响;外特性方面,中等转速工况采用较大的气门重叠角可提高体积效率;高转速采用较小的气门重叠角可提高充量系数;怠速和部分负荷工况下,较小的气门重叠角对改善发动机稳定性有一定帮助。     

列车振动荷载作用下交叠隧道衬砌结构响应特性分析

以某交叠隧道为背景,通过有限元分析理论与数值计算方法建立三维模型,研究了双向列车通过时其振动对隧道结构的影响。分析表明：拱底中央受列车振动荷载影响最大,结构满足安全性要求;土压静载仍为结构设计的控制因素。     

连续相位调制信号的检测

本文主要介绍了CPM信号的解调方法,研究了基于最大似然接收原理的网格搜索最优算法—维特比（viterbi）算法,并且通过Matlab计算机仿真,给出了一定信噪比条件下影响CPM调制体系误码率性能的因素。     

舰船惯导航行数据的重构及混沌特性分析

针对现有舰船航行数据处理研究中,对数据内在属性及不同数据间相关性研究不够深入的问题,应用不同方法对舰船惯导航行数据进行了相空间重构及比较分析。分析结果表明,C-C方法对船舶惯导航行数据的重构效果较好。在此基础上,进行了惯导数据的混沌特性定性分析,并计算了惯导数据的最大Lyapunov指数,对舰船惯导数据进行了混沌动力学特性研究。分析结果证实了舰船航行数据具有较为典型的混沌特性,为进一步研究采用混沌控制等方法对舰船航行中的混沌状态进行控制提供必要的数据基础和比较依据。     

二相流模式下JDC4-55可调桨粘性流场分析

运用CFD方法中的汽-液混合二相流模型模拟JDC4-55可调桨的水动力性能和空泡性能。通过改变进速和调节桨叶角度得到相应的水动力性能参数。分析空泡对螺旋桨水动力性能的影响,进行JDC4-55可调桨桨流场模拟分析。相对于单相流模型而言,JDC4-55可调桨汽-液混合二相流模型性能计算结果与实验值吻合得更好。