高纯NF3气体管路系统的预处理

高纯三氟化氮气体在电子工业中有着广阔的应用前景,在生产过程中常存在微粒子的污染问题,本文介绍了目前工业化生产三氟化氮(NF3)过程中微粒子产生的原因及几种不锈钢管路和阀门、附件的处理方法。     

液氮远洋渔业综合体--浅谈液氮在远洋渔业中的应用

本文从国内远洋渔业现状出发，大胆地提出一个不同于国内外现有远洋渔业捕捞的技术体系想法---液氮远洋渔业综合体，详细介绍了其构成、存在问题及解决方案等技术要点，为国内远洋渔业的发展提供了重要的价值取向。     

氮对奥氏体不锈钢氢脆敏感性的影响

本文研究了气相充氢条件下,氮对２１—６—９奥氏体不锈钢力学性能的影响,以及不同牌号的Ｃｒ─Ｎｉ—Ｍｎ系奥氏体不锈钢充氢后力学性能的变化。结果表明,不同牌号奥氏体不锈钢的抗氢脆能力随其层错能的增加而提高,氮含量的增加则使２１—６—９钢的抗氢脆能力下降。由此推论氮可能具有降低奥氏体钢层错能的作用。     

二氧化氮芯片式检定管胶体的研制

选用淀粉-碘化钾法研制二氧化氮芯片式检定管胶体,研究了载体和胶体配比等对胶体性能的影响,并绘制了定量曲线。二氧化氮芯片式检定管的检测下限是0.27mg/m3。芯片式检定管无需手工切割,采用光电识别,读数误差小,可在光线昏暗的环境中使用。     

Modelling of high speed gas quenching

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Nitrogenous discharges to the eastern Gulf of Finland, the Baltic Sea: Elemental flows, stable isotope signatures, and their estuarine modification

We studied the nutrient input to the Gulf of Finland via River Neva, the largest river discharging freshwater to the Baltic Sea, and characterised the isotopic signatures (¹⁵N, ¹⁸O, ¹³C) in dissolved and particulate substances (NO₃⁻, PON, POC, DIC) in the River Neva over two seasonal cycles, as well as in samples from St. Petersburg wastewater treatment plants (NO₃⁻, NH₄⁺, PON, POC). These riverine and municipal discharges account for 40% of terrestrial inorganic N loading to the Gulf of Finland, representing annually 7% of the total nitrogen pool in the water mass of the whole Gulf. To describe and evaluate the modification of these isotopic signals along a Gulf of Finland transect towards the Baltic Proper, two cruises were arranged, one in late spring after the annual maximum in River Neva runoff, and one in autumn, in the late phase of the annual growth season.River Neva nitrate signatures of ¹⁵N and ¹⁸O indicated major agricultural fertilizer origin of nitrogen, and the isotopic composition was clearly lighter (δ¹⁵N-NO₃⁻ mean of 2.4‰ air) than previously measured from more southern rivers discharging into the Baltic Sea. Because of the light composition of the River Neva N source, close to the ¹⁵N signatures of the open Gulf, as well as of the efficient depletion of the inorganic load already in the innermost estuary, straightforward end-member tracer analysis of the transport of N in the basin is problematic. St. Petersburg wastewater ammonium showed, however, high δ¹⁵N values (ca. 13‰), which gives a first estimate of 5.8‰ for δ¹⁵N of the easternmost estuarine total inorganic N source. The available sediment data from the basin (δ¹⁵N 6 to 8‰) somewhat exceeds the average source signature. This emphasizes the significance of biological transformation processes, most importantly assimilation of inorganic nitrogen, food web interactions and denitrification, which all involve isotopic fractionation, for the mass balance models describing the dynamics of the sources and sinks of the N cycle of the basin.     

Estimation of nitrogen oxides emissions from petrol and diesel passenger cars by means of on-board monitoring: Effect of vehicle speed,vehicle technology,engine type on emission rates

NO_X emission rates of 13 petrol and 3 diesel passenger cars as a function of average speed from 10 to 120 km/h, emission class (pre-Euro 1 – Euro 5), engine type were investigated by on-board monitoring on roads and highways of St. Petersburg using a portative Testo XXL 300 gas analyzer. The highest level of NO_X emission 0.5–2.5 g/km was inherent to old pre-Euro 1 petrol cars without a catalytic converter. NO_X emissions rates of Euro 1 and Euro 2 petrol cars changed within 0.15–0.9 g/km, Euro 3 – 0.015–0.27 g/km, Euro 4 – 0.013–0.1 g/km, Euro 5 – 0.002–0.043 g/km. Euro 3 – Euro 4 petrol cars generally satisfied corresponding NO_X Emission Standards (ES), except cold-start period, Euro 5 petrol cars did not exceed ES. Warmed, stabilized engines of Euro 3 – Euro 5 petrol cars showed 5–10 times lower NO_X emission rates than corresponding ES in the range of speed from 20 to 90 km/h. NO_X emission rates of diesel Euro 3 and Euro 4 cars varied from 0.45 to 1.1 g/km and from 0.31 to 1.1 g/km, respectively. Two examined diesel Euro 3 and one Euro 4 passenger vehicles did not satisfy NO_X ES at real use. Euro 3 diesel cars showed 28.9 times higher NO_X emissions than Euro 3 petrol cars and Euro 4 diesel car demonstrated 17.6 times higher NO_X emissions than Euro 4 petrol cars at warmed and stabilized engine at a cruise speed ranging from 30 to 60 km/h.     

Real-world gaseous and particle emissions of a Bi-fuel gasoline/CNG Euro 6 passenger car

The objective of the present study is the assessment of the environmental impact of a bivalent (bi-fuel) vehicle, running either on gasoline or compressed natural gas (CNG). To that aim, a Euro 6 passenger car was tested under various real-world driving conditions. In order to cover the full range of conventional powertrains currently in the market, the tests were also repeated on a Euro 6 diesel passenger car. Both cars were driven in two routes, the first complying with the regulation limits and the second going beyond them. Carbon monoxide (CO), nitrogen oxides (NO_x) and particle number (PN) emissions were recorded using a Portable Emissions Measurement System (PEMS). Apart from the aggregated emission levels, in g/km, the exact emission location along the route was also assessed. Natural gas proved beneficial for CO and PN emissions, the level of which always remained below the respective legislation limits. On the other hand, under the dynamic driving conditions with gasoline, the relevant limits were exceeded. Cold start, occurring at the beginning of the urban part, and motorway driving were identified as major contributors to total emissions, especially in gasoline mode. However, the application of natural gas was associated with a penalty in NO_x emissions, which were significantly increased as compared to gasoline. Local peaks within the urban part were identified in CNG mode. In any case, the diesel vehicle was by far the highest NO_x emitter.     

Mathematical Models and Computer Simulation of Nitrogen Concentration Profiles in Pulse Ion Nitrided Layers

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减压速度对低温流体闪蒸现象的影响

本实验钍对贮藏容器及输送管道的安全问题，以液化氮为一质，模仿在实际中可能遇到的容器及管道裂缝而引起的容器内压力变化，利用实验棒作为加热面，以不同的减压速度进行了实验，对减压速度对低温流体闪蒸现象的影响的一般规律及津腾样态了作了一定的研究。