用锌(II)-5-Br-PADAP-SDBS-Tween80配合物测定土壤和植物中的微量锌

研究了高灵敏的Zn(Ⅱ)-5-Br-PADAP-SDBS(十二烷基苯磺酸钠)-Tween80(吐温80)配位体系。该本系的适宜酸度为pH6.5～7.0范围内,最大吸收峰在565nm波长处,摩尔吸光系数为ε_=1.7×10~5L·mol~(-1)·cm~(-1)。在565nm处,空白值几乎为零。在SDBS和Tween80存在下配合物的组成比为Zn(Ⅱ):5-Br-PADAP=1:2。其表观稳定常数为1.6×10~(-11)。在0～0.5μgZn~(2+)/ml范围内,符合比尔定律。此法一般金属离子和阴离子均不干扰。该法已用于直接测定土壤和植物体由微量锌,测定结果相当满意。     

稀土对锌电极在碱性溶液中耐蚀性能的影响

本文通过动力学参数测试,析气实验研究了添加稀土金属对锌电极在碱性溶液中耐蚀性能的影响,结果表明添加少量稀土元素可以显著提高锌电极在碱性溶液中的耐蚀性.     

易格斯DryLin直线滑动轴承

为实现直线驱动,Conergy公司将直线轴承用于调整系统,它采用了易格斯高性能工程塑料滑动轴承:DryLin直线滑动轴承确保轴精确运行。DryLin直线系统轴承基座由坚固的铸造锌制成,滑动原件则包括阳极硬化铝(导轨)和iglidur滑动膜,其具有低摩擦系     

新型锌铝合金在阀门生产中的应用

在分析阀杆螺母服役条件的基础上，对用价格低廉的锌铝合金生产阀杆螺母进行了成分设计，确定了新型的锌铝合金－ZA33－3，并对其了力学性能及耐磨性能试验，结果表明，新型ZA33－3合金的各项性能指标全面超过铜合金，是替代铜合金生产阈杆螺母的理想材料，而其价格仅为铜合金的1／3。     

泰州大桥环氧富锌漆及防水粘结层耐高温性能研究

根据泰州大桥钢桥面铺装特点和技术要求,对美国环氧沥青和日本环氧沥青2种材料作为防水粘结层的耐高温性能进行了研究。通过4种温度(23℃、60℃、220℃、250℃)的拉拔试验,得到了防水粘结层的不同温度下的敏感性。试验结果表明:环氧富锌漆经过220℃老化后,与钢板间粘结强度损失不大,只是颜色出现明显变化;而防水粘结层随着温度的升高,其拉拔强度下降很快,且美国环氧沥青防水粘结层高温老化后的拉拔强度与日本环氧沥青防水粘结层高温老化后的性能相差不大。本研究可为环氧沥青钢桥面防水粘结层施工提供参考。     

THE STUDY ON THE CHANGES OF ZINC, COPPER, CALCIUM AND MAGNESIUM IN PLASMA AND ERYTHROCYTES DURING CARDIOPULMONARY BYPASS

Objective To study the changes and their influence factors involved of zinc, copper, calcium and magnesium in plasma and erythrocytes during cardiopulmonary hypass(CPB). Methods Zinc, copper, calcium and magnesium values in plasma and erythrocytes were measured by atomic absorption spectrophotometer during CPB. Results Zinc and copper levels in plasma were significantly elevated above preinduction level before perfusion, hut calcium and magnesium levels did not change significantly; zinc, copper and calcium levels in plasma were significantly below preoperation level during CPB, hut magnesium level in plasma was significantly increased above preoperation; zinc level in plasma was increased to preoperation level after CPB and began to decrease again at 8 hours after CPB,copper level in plasma was increased to preoperation level at 20 hours after CPB, calcium in plasma was increased significantly from beginning to 8 hours after CPB, magnesium level in plasma was decreased to preoperation level at 8 hours afterCPB. Concentration of zinc , copper, calcium and magnesium in erythrocytes did not change significantly. Conclusion During CPB, the changes of zinc, copper, calcium and magnesium had relation to hemodilution, operative wound, carrier protein, stress and component of priming Solution and cardioplegic solution, hut no relation to transferfrom plasma erythrocytes. The results indicate that it is beneficial to patient‘s recovery to supplement zinc, copper, calcium and magnesium properly by different ways during cardiac perioperation.     

锌银蓄电池负极化成的研究进展

本文叙述了锌银蓄电池试制过程中负极化成的研究进展情况,并提出一些优化改进该工艺流程的措施,进一步保证了由小批量试制到大批量试制工艺的顺利过渡,并提出一些有利于大量试制的合理化建议。     

锆系薄膜前处理工艺在汽车涂装中的应用

涂装前处理的作用是清洁白车身,提高电泳漆膜的附着力、耐蚀性能和全涂层的装饰性。三元锌系磷化体系作为汽车涂装前处理的标准工艺已经应用40多年,其主要缺点是磷化沉渣量大、需对设备进行定期酸洗;为了保证磷化膜良好的成膜性,需设置表调、钝化等工序,使前处理工艺中的化学过程多,相应的化学品用量也大;磷化废水中含重金属镍和锰,对环境造成污染。为了满足整车厂的涂装规范,并最大程度地降低前处理的成本和对环境的影响,必须以环保型的前处理工艺取代之。回顾了汽车涂装前处理的发展历程,着重介绍了新型锆系薄膜前处理工艺的有关情况。