Diels-Alder反应的理论研究新进展

Diels-Alder反应已经成为合成六元环加成化合物、天然萜类化合物和药物中间体、哌啶衍生物的一个关键步骤,随着在合成领域取得令人瞩目的成果,Diels-Alder反应的机理研究也取得了一定的进展.该文综述了国内外Diels-Alder反应最新的理论研究,在催化剂lewis酸、噁唑硼烷、水溶剂、离子溶剂和超临界CO2...     

两峰之间“波谷”——剖析2011年中国车市

中国车市2011年1—5月出现大幅度回落,有专家误判＂车市进入本次波动收缩期＂,因此对完成＂十二五＂汽车规划信心动荡。文章为解决上述＂认识误区＂,采用＂车市波动分析法＂这一创新成果,分析研究了有关数据和波动图波形走势,判定当前车市处于两峰之间的＂波谷＂,处于本次波动＂扩张后期＂,还没有进入＂收缩期＂。2011年车市处于中下等市场,2011年下半年将有所回升,年增长率接近10%（与GDP基本同步或稍高）。对＂十二五＂期间车市发展持审慎乐观态度。     

超声波-铁氧体法处理含铬废水的实验研究

本实验使用超声波-铁氧体法对含铬废水进行处理,通过考察硫酸亚铁用量、pH值、H2O2用量、超声波的辐射时间和辐射功率对含铬废水铬去除率以及铁氧体磁性的影响,设计超声波-铁氧体法处理含铬废水的最佳操作条件.结果表明,随着硫酸亚铁用量的增加,Cr6 的去除率增大,最佳pH为9.0,当Fe2 :Cr6 =6∶1(mol∶mol)、超声波辐射时间和辐射功率分别是30 min和50 W/cm2时,去除率高达到99.9%以上,H2O2用量为1.0~2.0 mL,铁氧体的磁性最强.     

制冷剂/压缩机油与PA6的相容性研究

采用红外光谱分析和热重分析研究了不同规格PA6(聚酰胺6或尼龙6)的区别,不同规格PA6的红外谱图有细微区别,PA6在350℃之前的热失重量不同,可见其增塑剂等小分子的含量不同,这不但影响PA6的耐热老化性能,还会明显影响PA6的挤出工艺和使用性能.通过PA6在制冷剂、压缩机油、制冷剂/压缩机油等介质中的热老化测试和测...     

用新观点研究预测中国2010—2011年车市发展

为分析研究2011年及近期车市发展趋势,供汽车产销单位经营决策参考,采用"车市波动分析法",用车市季度主要参数表和年度车市波动图分析车市实际走势。肯定了汽车产销量超美的成绩。指出2010年车市逐季度大幅回落趋势,分析了罕见的"波形异常"问题的影响及原因。对2011年面临形势进行了分析和预测:车市处于扩张后期,中下等市场,2011年后车市仍有可能小幅回升,对"十二五"期间车市发展持审慎乐观态度。     

复杂城市场地下大跨度桥梁总体设计关键技术研究

以常德沅江六桥总体设计为例，分析了基于复杂城市场地下大跨度桥梁设计特点及需考虑的各方面因素，阐述沅江六桥方案的设计思路。综合考虑规划路网、沿线高压电走廊、沅江水文条件、地震断裂带等因素，对大桥的规划桥位进行优化调整，提出推荐桥位方案。根据通航要求和规划码头等条件，确定推荐方案的桥梁跨径和桥型。简要介绍桥梁结构设计，并验证主要结构的科学合理性。     

Mechanical model and characteristics of deep-water drilling riser-wellhead system under internal solitary waves

Internal solitary waves with a huge amount of energy easily trigger the large dynamic responses of riser-wellhead system and threaten its structural safety. However, previous studies have only focused on the dynamic response of the riser under internal solitary waves. The riser may experience excessive traction from the platform, especially from the mooring platform, in response to the arrival of internal solitary waves. The bottom of the riser connects to the wellhead system, which in turn exerts a reaction force on the riser. To address this problem, a coupled dynamic model of deep-water drilling mooring platform-riser-wellhead system under internal solitary waves is developed in this paper. A dynamic response analysis method based on the fourth-order Runge-Kutta method and finite element method is also proposed for the mooring platform-riser-wellhead system. A dynamical solver for the coupled system is then developed using MATLAB. The dynamic response characteristics of the riser-wellhead system under internal solitary waves are calculated. Results show that the displacement and bending moment of the system initially increases and then decreases along with the propagation of internal solitary waves, and finally reach equilibrium position. The displacement and bending moment reach their peak before the trough of internal solitary waves passes through the riser-wellhead system. The dynamic responses of the riser-wellhead system under the influence of internal solitary wave loads are much larger than those without the effect of internal solitary wave loads. The riser system experiences shearing loads at the interface of internal solitary waves, which trigger a step-like bending moment variation. The bending moment of the conductor under the mudline is greatly increased by the internal solitary waves.