双层Ni-P合金镀层制备及耐蚀性

为研究双层Ni-P合金镀层的高耐蚀性,通过改变络合剂组分和控制化学镀工艺条件,制备了3种不同磷含量的镀层.用XRD,EDS和SEM方法,对镀层的成分、结构和形貌进行表征,并用电化学方法和腐蚀膏法,分别测定了镀层的腐蚀电位和耐蚀性.结果表明:不同的镀液成分和化学镀工艺使镀层的磷含量和组织结构发生变化.随镀层中磷含量上升,镀层组织的变化从晶态到晶态+非晶态,最后到非晶态,使镀层的自腐蚀电位及自腐蚀电流分别增加和下降.在外层为低电位层(-550 mV),内层为高电位层(-295 mV),内外层厚度比为2∶1时,镀层的耐腐蚀性最好.     

Fe-Mn-Al-Cr合金双极板在模拟PEMFC环境中的电化学性能

采用电化学方法测定一种Fe-Mn-Al-Cr合金在模拟PEMFC环境中的极化曲线以及在PEMFC工作电位下的电流密度随时间变化的曲线.结果表明,Fe-Mn-Al-Cr合金在0.05 mol/L H2SO4＋2 mg/L F-溶液中呈现明显的活化-钝化转变.在恒电位极化过程中,阴极一侧表面能够形成稳定的钝化膜,钝化电流密度低于l6μA.cm-2.而在阳极一侧则产生了大量溶解的金属离子.     

Recycling of aluminum from fibre metal laminates

Recycling of aluminum alloy scrap obtained from delaminated fibre metal laminates (FMLs) was studied through high temperature refining in the presence of a salt flux. The aluminum alloy scrap contains approximately mass fraction w(Cu) = 4.4%, w(Mg) = 1.1% and w(Mn) = 0.6% (2024 aluminum alloy). The main objective of this research is to obtain a high metal yield, while maintaining its original alloy compositions. The work focuses on the metal yield and quality of recycled Al alloy under different refining conditions. The NaCl-KCl salt system was selected as the major components of flux in the Al alloy recycling. Two different flux compositions were employed at NaCl to KCl mass ratios of 44:56 and 70:30 respectively, based on either the eutectic composition, or the European preference. Different additives were introduced into the NaCl-KCl system to study the effect of flux component on recycling result. Although burning and oxidation loss of the alloying elements during re-melting and refining take place as the drawbacks of conventional refining process, the problems can be solved to a large extent by using an appropriate salt flux. Experimental results indicate that Mg in the alloy gets lost when adding cryolite in the NaCl-KCl salt system, though the metal yield can reach as high as 98%. However, by adding w(MgF₂) = 5% into the NaCl-KCl salt system (instead of using cryolite) all alloying elements were well controlled to its original composition with a metal yield of almost 98%.     

Formation of nanometer coherent structures during spinodal decomposition and ordering coexistence phase transformation in Fe-24Al alloys

The nanometer coherent structure evolution of spinodal decomposition and ordering coexistence phase transformation in Fe-24Al alloys is investigated by the microscopic phase field kinetic model. The results show that the concentration and long-range order parameters all continuously change towards to their equilibrium values during phase transformation. With the increase of elastic interaction energy, the anisotropy along [01] or [10] elastic soft direction is more obvious and the time reaching equilibrium state is also shortened. According to the results, the formation of nanometer coherent structures during phase transformation is composed of the initial decreasing stage of order degree stage, the incubation stage, the continuous increasing stage of concentration order parameter and long-range order parameter, and the later stable stage. The spinodal decomposition and ordering is interaction; the initial ordering stage is a necessary condition of the coexistence phase transformation. The nanometer coherent structures are not found to grow during the whole phase transformation. The simulation results are in accordance with the results in experiment obtained by the aging treatment in Fe-24Al alloys.     

Ni-Mn合金的去合金化

在氩气保护下,应用真空熔炼炉分别制备了Ni30Mn70与Ni55Mn45合金.测定了这两种合金在(NH4)2SO4溶液中的圾化曲线,然后对其进行去合金化实验.结果显示,Ni30Mn70合金在1M(NH4)2S04溶液中去合金化后,试样表面呈现“泥裂”结构.Ni55Mn45在1M(NH4)2S04溶液中不同电位下去合金化...     

增功利器DIY精品 MSC标识部件变形金刚系列之黑白双雄

为了适应当前市场个别车友对爱骑动力性快速提升的需求,MSC标识部件研发部在成熟的白金系列套缸的基础上,重新修改技术参数,将全新的改装套缸奉献给大家,使在不改动发动机其他部件的基础上让发动机的动力得到了明显提升。该套件采用新配方的磷矾铸铁缸体,其优良的物理稳定性保证了工作受热时最小的膨胀系数,优异的储油性使搭配特种活塞环后实现了超长的耐磨性;高硅铝基材的活塞重量更轻,膨胀系数更小,在降低粘缸几率的同时,产生更大的功率;采用特种材质、冷镦精磨工艺生产的活塞销,由于加工过程中金属材料流线(纤维组织)不会被切断,从而大幅度提高了抗剪切力和抗揉断力,杜绝了断裂现象的产生,     

车用尼龙及其复合材料的性能与应用

尼龙及其复合材料是汽车常用的塑料材料之一,研究其结构与性能有助于扩大其在汽车上的应用.文章以汽车上应用最广泛的尼龙、玻璃纤维增强尼龙、尼龙聚丙烯合金和尼龙丁腈橡胶合金材料为例,分析它们内部结构的不同以及在力学性能上的区别.针对不同材料的不同性能,列举了这些材料制造的具体零部件和使用现状.由于尼龙及其复合材料具有很高的性价比,其应用范围必将不断扩大.今后对尼龙及其复合材料缺陷的优化和改进,将成为这种材料的研究方向.     

合金电缆在污水处理行业的应用前景

通过对比新型合金电缆与传统铜芯电缆的各项技术参数,并结合水处理行业的电缆应用现状,论证了合金电缆在以水处理行业为代表的市政基础设施工程中具有较好的应用前景,并提出了其在实际应用中的设计要点。     

Au40 Pd20合金原子团簇惰性气体氛围凝聚动力学行为研究

采用蒙特卡洛方法,结合Tight-binding和Lennard-Jones作用势,对Ar原子氛围中初始随机分布的40个Au原子和20个Pd原子体系的凝聚动力学行为进行了研究．Ar原子氛围对合金团簇的形成过程及其形貌尺寸有重要影响,计算表明：不同的Ar原子氛围得到的Au40 Pd20合金原子团簇凝聚结构形貌不同;在降温退火过程中, Ar原子密度大时,得到的Au40 Pd20合金原子团簇结构更加紧凑,且Au40 Pd20合金团簇凝聚相变温度更高;而恒温退火过程中,则发现较高温度时能得到较为紧凑的合金团簇结构,Ar原子密度越大,系统到达平衡的动力学时间更短．模拟结果能为惰性气体冷凝方法中实现合金团簇结构与形貌可控制备提供参考．     

汽车用铝锡铜轴瓦合金热膨胀性能研究

对3种常见的AlSn6Cu、AlSn20Cu、AlSn30Cu铝锡铜合金的热膨胀性能进行了研究。结果表明，随着合金中Sn含量的增加，组织中B(Sn)相增加，膨胀系数减小；高熔点的Cu元素固溶于α(Al)相中，使α(Al)晶格常数下降，能有效抑制合金膨胀系数随温度的急剧变化。