新型固态胺二氧化碳吸收剂的制备及性能

采用丙烯酸酯类为单体,二乙烯苯为交联剂,悬浮聚合制备大孔交联共聚物基质,胺解制备了一种新型固态胺二氧化碳吸收剂一聚丙烯酰多乙烯多胺型树脂,研究了单体种类、功能基结构和含量、胺解条件等对树脂吸收二氧化碳性能的影响.模拟条件试验表明,该树脂吸收二氧化碳活性高,寿命长.     

A multi-class model-based control scheme for reducing congestion and emissions in freeway networks by combining ramp metering and route guidance

The paper proposes a multi-class control scheme for freeway traffic networks. This control scheme combines two control strategies, i.e. ramp metering and route guidance, in order to reduce the total time spent and the total emissions in a balanced way. In particular, the ramp metering and route guidance controllers are feedback predictive controllers, i.e. they compute the control actions not only on the basis of the measured system state, but also on the basis of the prediction of the system evolution, in terms of traffic conditions and traffic emissions. Another important feature of the controllers is that they have a multi-class nature: different classes of vehicles are considered and specific control actions are computed for each class. Since the controllers are based on a set of parameters that need to be tuned, the overall control framework also includes a module to properly determine the gains of the controllers. The simulation analysis reported in the paper shows the effectiveness of the proposed control framework and, in particular, the possibility of implementing control policies that are specific for each vehicle type.     

Annual uptake of atmospheric CO2 by the Weddell Sea derived from a surface layer balance, including estimations of entrainment and new production

Data from two cruises, one in April/May 1996 and one in December/January 1993, covering the same wide area in the offshore Weddell Sea, were used to derive the annual extent of entrainment and the capacity of the biological pump. The former property was obtained with the help of dissolved oxygen data, whereas the latter was approximated with nutrients. Especially the data from April/May, representing the initial state of the winter surface layer, were crucial to assess the annual extent of these processes. The results were applied to our carbon dioxide data. The annual increase of the Total CO₂ (TCO₂) concentration in the surface layer due to vertical transport amounts to 16.3 μmol kg⁻¹. An entrainment rate of deep water in the surface layer amounting to 35±10 m yr⁻¹ was deduced. The compensating, biologically mediated TCO₂ reduction was calculated to be larger than the TCO₂ increase due to vertical transport. Since the balance of these two processes determines whether the Weddell Sea is a source or a sink of CO₂, this indicates that the Weddell Sea, albeit upwelling area, is definitely a sink for atmospheric CO₂ on an annual basis. This conclusion is further supported by contemplations that the biological drawdown of CO₂ in the Weddell Sea as a whole is probably underestimated by our calculations. The new production for the Weddell Sea on a per unit area basis was found to be much higher than that for the Antarctic Ocean, when the latter value is being obtained by traditional biological methods. On the other hand, the CO₂ uptake by the Weddell Sea on a per unit area basis is somewhat smaller than the CO₂ uptake by the world ocean.     

Regulating transport’s environmental impacts in a deregulating world

In recent years, a growing awareness of the environmental impacts of transport has played a major part in the shift towards policies to manage the demand for travel. As a result, a substantial increase in the role of public transport has been identified as necessary in any strategy towards more environmentally sustainable transport patterns. At the same time there has been a quite separate process of deregulation and the withdrawal of the state from the transport market. These two trends appear to represent potentially contradictory processes. This article draws upon two major studies that explore the relationship between increasing needs for environmental regulation and the privatisation of bus and rail services. It is shown that, as currently organised in Britain, the development of bus and rail services are inadequately linked to strategic environmental policymaking and, rather than being part of the solution to transport’s environmental impacts, there is a real danger that these ‘green’ methods of transport could slide into simply being part of the problem itself. It is concluded that privatisation and deregulation does not mean the end of the need for policy mechanisms, but they do mean that policy has to be implemented in a very different way.     

Temporal disaggregation of travel demand for high resolution emissions inventories

The commonly used photochemical air quality model, the Urban Airshed Model (UAM), requires emission estimates with grid-based, hourly resolution. In contrast, travel demand models, used to simulate the travel activity model inputs for the transportation-related emissions estimation, typically only provide traffic volumes for a specific travel period (e.g. the a.m. and p.m. peak periods). A few transportation agencies have developed procedures to allocate period-based travel demand data into hourly emission inventories for regional grid cells. Because there was no theoretical framework for disaggregating period-based volumes to hourly volumes, application of these procedures frequently relied upon a single hypothetical hourly distribution of travel volumes. This study presents a new theoretical modeling framework that integrates traffic count data and travel demand model link volume estimates to derive intra-period hourly volume estimates by trip purpose. We propose a new interpretation of the model coefficients and define hourly allocation factors by trip purpose. These allocation factors can be used to disaggregate the travel demand model ‘period-based’ simulation volumes into hourly resolution, thereby improving grid-based, hourly emission estimates in the UAM.     

火灾受损桥梁检测评估与加固处理

介绍回弹 超声综合法在检测评定桥梁结构遭受火灾损伤中的应用。结合实例,给出应用碳纤维布补强技术对其加固处理的方法,并通过桥梁静载试验证实加固取得了很好的效果,其思路可为处理同类病害的桥梁提供有益的参考。     

JS250沙滩车的排放治理

对于JS250沙滩车采用新型号化油器优化 催化剂 二次补气的排放治理方案后和原车相比,可使CO降幅62％;HC降幅61％,基本满足了欧标法规要求,此方法是国内外应用研究的少有案例。     

复叠式CO2/NH3低温制冷系统热力学分析

复叠式制冷系统具有良好的应用前景,利用自然工质CO_2、NH_3做制冷剂使系统有着很大的优势;对影响复叠制冷循环性能系数的几个因素进行热力学分析,并指出此系统的特点。     

碳纤维加固混凝土梁抗弯性能的非线性有限元分析

对经碳纤维加固后的钢筋混凝土梁进行有限元非线性全过程数值模拟分析。成功地解决了有限元求解碳纤维加固混凝土梁非线性数值的收敛问题,阐述了非线性的行为。有限元计算的结果与试验结果具有较好的一致性,并对两者之间的误差所产生的原因进行了分析。结果表明,建立合理的有限元数值模型,并采用合理的求解策略,能很好的准确预测并模拟碳纤维布加固混凝土梁的抗弯性能,同时也为以后的数值研究工作奠定了基础。     

2007-2017年西安市机动车排放特征研究

西安市机动车保有量的大量增长带来了交通尾气污染物和CO2的高强度、集中性排放,严重影响空气质量以及碳排放治理工作。因此,详细的机动车排放特征研究可以为减排措施的设定提供依据。本文研究了2007-2017年西安市不同车型、不同排放标准的车辆排放特征。研究发现:各种污染物中,CO2排放量增长最快,年均增长率为15.1%。大型客车和大型货车是NOx、PM2.5的主要来源,小型客车和大型货车是CO2的主要来源。随着排放标准的不断提高,2017年国0排放标准的车型对VOCS和CO的贡献率仅为2.7%和1.9%。对各种污染物进行归一化处理后发现,CO和NOx在机动车污染物中占比最高。