键合纤维素衍生物手性固定相的合成及手性拆分

采用包夹聚合法,将纤维素(10-十一烯酸酯/3,5-二甲基苯基氨基甲酸酯)键合于乙烯基硅胶上,制备了键合纤维素(10-十一酸酯/3,5-二甲基苯基氨基甲酸酯)手性固定相(简称为键合纤维素(3,5-二甲基苯基氨基甲酸酯)(键合(CDMPC-CSP)),并对其进行了表征.分别以正己烷/异丙醇、正己烷/四氢呋喃、正己烷/三氯甲烷为流动相,对键合CDMPC-CSP的手性识别能力进行了评价.实验结果表明,键合CDMPC-CSP具有一定的手性识别能力,可以拆分所研究的8种手性化合物中的4种.     

高速电气化铁路的接触网电分相型式探讨

根据目前关节式电分相存在问题，提出一种新型的3个绝缘锚段关节双中性段关节式电分相型式，有效地克服了目前双锚段关节单中性段关节式电分相存在的问题，可较好解决关节式电分相对电力机车受电弓多弓运行条件的限制。     

Spatial distribution of cadmium over a cyclonic eddy in the southern East China Sea

Eddy systems are a unique ecosystem, usually having high biological masses and primary production in the sea. In this study, both particulate and dissolved phases of cadmium in the water column of 15 stations over a cyclonic eddy in the southern East China Sea were determined to obtain their spatial distributions. This allows us to confirm that cyclonic eddy systems play the role of a Cd pump in the sea.Results showed that particulate Cd (PCd) and dissolved Cd (DCd) concentrations in water varied greatly, ranging over two orders and one order of magnitude, respectively. Large spatial variability was found not only for PCd but also for DCd in the upper water, apparently due to the effects of the cyclonic eddy system on the Cd distributions over the study area. DCd accounts for about 99% of the total Cd. For the surface water, DCd concentration at the eddy center was about five times the average of the water surrounding the eddy center. The depth distributions of DCd exhibited a typical surface depletion and a subsequent increase with depth; however, the PCd distribution showed the opposite, i.e. a surface maximum and a subsequent decline with depth. In general, the DCd maxima were found at depths of 600–1000 m, agreeing well with the literature. It reflected the internal biogeochemical cycling of Cd in the water column, which was driven by the utilization of Cd by plankton in the euphotic zone and by the regeneration of Cd at depth. In addition, a remarkably high DCd concentration existed in near-bottom water around the cyclonic eddy center.The horizontal distributions of both PCd and DCd in the upper water shared a common feature with elevated concentrations centering around the eddy center and a decline in concentration with distance from the eddy center. This shows that the cyclonic eddy could bring up the Cd-rich deep water to the surface water around the eddy center and could then expand toward eddy's vicinity via advection–diffusion. It is thus likely that it produces ample biological masses over the eddy system. Hence, this work can demonstrate that the ascending nutrient-rich water driven by the cyclonic eddies can serve as an important source not only for many nutrients but also for Cd in the sea.     

绍兴市梅龙湖人行桥总体与景观设计

钢拱桥由于自重轻、水平推力相对较小、结构表现力丰富而被广泛采用。绍兴市梅龙湖人行桥设计为70 m+35 m全焊接钢结构桁架拱桥,介绍该桥主要设计技术标准、结构总体设计及桥梁的景观设计。     

无灯控行人过街元胞自动机交通模型研究

以无灯控行人过街对交通流影响为分析目标,在综合考虑行人穿越行为及车辆行为的基础上,建立了相应的行人及车辆元胞自动机模型规则,尤其是在模型中提出了行人等待区的概念及基于等待区内有无行人的车辆行为规则。以上述模型为基础,通过对不同行人产生概率及速度快的行人比例情况时路段交通流演化趋势进行了仿真。     

基于交通冲突技术的行人安全分析与改善

从研究行人安全的角度出发,简要介绍了行人交通冲突技术及冲突成因,通过实例调查分析,探讨了交叉口信号配时对行人安全的影响以及闯红灯人数与行人冲突的关系,建立了行人绿信比与闯红灯比例、行人绿灯时转弯车与行人冲突数的关系模型,分析了行人冲突特性,用一种潜在事故指标表征行人安全.最后,针对存在的问题提出了相应的行人安全改善措施,并对3种冲突改善措施的效果进行了对比,得出相关结论.     

连续相位调制信号的检测

本文主要介绍了CPM信号的解调方法,研究了基于最大似然接收原理的网格搜索最优算法—维特比（viterbi）算法,并且通过Matlab计算机仿真,给出了一定信噪比条件下影响CPM调制体系误码率性能的因素。     

舰船惯导航行数据的重构及混沌特性分析

针对现有舰船航行数据处理研究中,对数据内在属性及不同数据间相关性研究不够深入的问题,应用不同方法对舰船惯导航行数据进行了相空间重构及比较分析。分析结果表明,C-C方法对船舶惯导航行数据的重构效果较好。在此基础上,进行了惯导数据的混沌特性定性分析,并计算了惯导数据的最大Lyapunov指数,对舰船惯导数据进行了混沌动力学特性研究。分析结果证实了舰船航行数据具有较为典型的混沌特性,为进一步研究采用混沌控制等方法对舰船航行中的混沌状态进行控制提供必要的数据基础和比较依据。