钢板桩围堰在双层软土地质条件下的应用

板桩支撑系统在江浙沿海地区的双层软土地质条件下的深基坑工程中具有较广阔的运用前景。以嘉绍北岸接线高速公路的长山河大桥围堰为工程背景,利用有限元法模拟了板桩施工过程及支撑受力,保证了结构的安全,优化了钢材用量,为此类地质条件下的钢板桩围堰施工积累了经验。     

A study of single-walled carbon nanotubes modified by organics of the phthalocyanine category

Organics of the phthalocyanine category have very good nonlinear optical properties. The single-walled carbon nanotubes were modified by using the phenoxy phthalocyanine. Characterization analysis was made by means of the transmission electron microscope (TEM), ultraviolet visible absorptive spectra, fluorescent spectra and Raman spectra. Under the TEM, it was observed that the composite looked like sugarcoated haws. By comparing the ultraviolet visible absorptive spectra before and after absorption, it was disclosed that the spectral intensity and the intensity of the peaks in the fluorescent spectra dropped remarkably. This shows that the single-walled carbon nanotubes have absorbed a large number of phenoxy phthalocyanines. Raman analysis revealed that in the Raman spectra, the position of the main peaks of the single-walled carbon nanotubes after absorption moved in the direction of long waves. The analysis suggests that the movement of the Raman spectra results from the change in the state of the single-walled carbon nanotubes before and after absorption.