Pb and Pu in the Northeast Water Polynya, Greenland: particle dynamics and sediment mixing rates

Distributions of the radionuclides ²¹⁰Pb and ^239,240Pu in sediment cores from the Northeast Water Polynya, Greenland, showed that these nuclides reached depths of 5–15 cm by particle mixing and sediment accumulation. End-member average values of the particle mixing coefficient and sediment accumulation rate were 0.13 cm² y⁻¹ and 0.06 cm y⁻¹, obtained from the ²¹⁰Pb profiles by assuming that each process is dominant relative to the other. Both ²¹⁰Pb and ^239,240Pu were measured on four cores; using the Pu data to constrain mixing rates produced corrected sediment accumulation rates that were 20–80% of the values calculated by neglecting mixing. Organic carbon burial in the polynya sediments was ≤0.4 mmol m⁻² d⁻¹, based on measured POC values at depth in the sediments and sediment accumulation rates corrected for mixing. This value is about 1% of the independently measured POC flux leaving the euphotic zone and compares with benthic carbon remineralization rates of 7% calculated by others from O₂ uptake in the sediments.The inventories of excess ²¹⁰Pb in the sediments ranged from 6 to 28 dpm cm⁻². Relative to the atmospheric input of ²¹⁰Pb and in situ production from decay of ²²⁶Ra, approximately 5 dpm cm⁻² of ²¹⁰Pb was being removed from the water column. The difference between the removal from the water column and sediment inventories suggests a net import of ²¹⁰Pb to the polynya. This may occur by input of dissolved ²¹⁰Pb from offshore waters or by input of ²¹⁰Pb carried by sea ice. Particulate matter in land-derived fast ice adjacent to the polynya contained 330 ± 14 dpm of excess ²¹⁰Pb g⁻¹. If particles transported in sea ice are comparable to those extracted from fast ice, then sea ice transport into the polynya followed by melting may be an important source of excess ²¹⁰Pb to the area. Fast ice also may contribute ²¹⁰Pb if portions break off and melt within the polynya, as occurred in 1993.     

Examining the influence of firm performance on business risk-taking and the mediation effect of scale of operations in the container terminal industry

Container shipping and its related service sectors help accelerate globalization of the world economy. This industry has been experiencing rapid growth, prompting container terminal operators to increase their handling capacity in response. Providing container terminal services requires substantial capital investment in physical assets such as cargo handling facilities and information systems. On the other hand, operating container terminals is a long-term investment that typically spans several business cycles. Hence prudent asset management using appropriate tools is critical for container terminal operators to sustain their businesses. Generally, due to risk-adverseness, investors are unwilling to take more risk in their investment unless they can reap a higher return. Contrary to this argument, this study finds no direct influence of better firm performance as a proxy of higher return on business risk-taking by container terminal operators. Instead, scale of operations is positively associated with business risk-taking, suggesting that container terminal operators with a larger scale of operations are willing to take more business risk.     

Calculation of external costs for freight transport

Abstract

The negative impacts of transport are in general associated with costs. These costs are usually denoted as ‘external costs’ or ‘externalities’. This paper presents a tool for calculating external costs for freight transport together with its application to a number of case studies. The categories considered include: air pollution, greenhouse gases, noise, accidents and congestion. Results are presented for a number of different transport alternatives as total costs and divided into categories. The uncertainties in the results are discussed. The assessment of these costs is essential for predicting future transport costs.     

Coupled lateral-longitudinal vehicle dynamics and control design with three-dimensional state portraits

The dynamics of vehicles with pneumatic tyres are well-known to be non-holonomic, nonlinear, and subject to state bounds in order to remain on defined roadways. As such, it can be challenging to apply many of the tools typically used to analyse nonlinear dynamics and synthesise control strategies. Furthermore, the use of traditional stability analyses is often insufficient for vehicle control design since adherence to the roadway geometry implies a constrained space that dictates stricter conditions on the states than provable stability. A two-state phase portrait approach has been used to analyse vehicle dynamics and provides an illustrative view of the state trajectories at constant speed. This paper extends the phase portrait to three states to represent the nonlinear vehicle dynamics with steering and longitudinal tyre force inputs and consideration of the longitudinal vehicle dynamics. The concept of a fixed point in the phase plane is extended to a stable curve and example controllers are examined and synthesised using the three-dimensional vector space.     

Green shipping practices and firm performance

Global economic development is facilitated by the commercial shipping industry. Shipping operations contribute to the growth of international trade activities, which heavily count on ships to carry cargoes from places of production to places of consumption. Despite its importance, there have been growing concerns about the environmental impacts caused by shipping activities in international trade. To balance environmental protection and productivity, many shipping firms have begun to adopt green shipping practices (GSPs) to improve their operations in a more environmentally friendly manner. GSP consists of six dimensions, namely, company policy and procedure (CPP), shipping documentation (SD), shipping equipment (SE), shipper cooperation (SC), shipping materials (SM), and shipping design and compliance (SDC). GSP is becoming an important aspect of shipping operations. It is timely for the shipping industry to evaluate firm capability in carrying out greening operations, that is, firms’ “greening” capability. Firm capability comprises two key elements: one is embedded in firms’ business routines or activities, and the other concerns firms’ ability in transforming inputs into outputs. GSPs can be considered as inputs while firm performance measures as outputs. This study uses an input/output approach to examine the greening capability (GC) of shipping firms. The results indicate that shipping firms are relatively weak in the practices of SC and SE, while the capability scores of SM, CPP, SDC, and SD are all close to 1, with an average score of 0.927, 0.920, 0.924, and 0.978, respectively. Academic and managerial significance of the findings are highlighted.     

Estimates of Southern Ocean primary production—constraints from predator carbon demand and nutrient drawdown

In view of the wide range of estimates for the total primary production for the Southern Ocean south of the Subantarctic Front—current estimates range from 1.2 to 3.5 Gtonne C year⁻¹—we have examined two indirect methods for assessing primary production. First, we have estimated the primary production needed to sustain the carbon requirements of the endotherm top predators in the ecosystem. Estimation of the carbon requirements for crabeater seals of about 7 Mtonne C year⁻¹ is extrapolated to a value for all endotherm predators of 15–30 Mtonne C year⁻¹. Current data indicate that 70–80% of the diet of this suite of predators is zooplankton (predominantly the euphausiid krill), making for highly efficient transfer from primary production to top predators. Our best estimate of Southern Ocean primary production by this method is of the order of 1.7 Gtonne C year⁻¹, or an averaged areal primary production of about 30–40 g C m⁻² year⁻¹. Our second approach is to estimate primary production from the drawdown of inorganic nutrients, based on the limited suite of studies from which an annual nutrient deficit can be calculated. Again, this indicates annual primary production of the order of 1.5 Gtonne. Although both methods have inherent uncertainties, taken together they provide a relatively robust constraint on annual primary production. For both methods to underestimate primary production by the 1–1.5 Gtonne C implied by the higher current estimates, carbon export from the Southern Ocean pelagic ecosystem would need to be much higher than is normally found in other oceans.     

Lights, camera and acoustics: Assessing macrobenthic communities at a dredged material disposal site off the North East coast of the UK

This study presents the results of a trial assessment based on a combination of sampling techniques at a dredged material disposal site located off the North East coast of the UK, over 2001 to 2004. The site was surveyed with a high-resolution sidescan sonar system producing a mosaic with 100% coverage of the survey area. Benthic communities and sediments were ground-truthed using a Hamon grab with a video camera. Additionally, the area was also sampled in 2003 with a Sediment Profile Imaging (SPI) camera, which complemented other techniques by providing in situ information on sediment quality, and biogenic activities. An assessment is made of the benefits of combining the results from conventional methods, principally using grab samples, with those from acoustic techniques and optical imaging devices to determine seafloor and macrobenthic conditions. This information has the potential to contribute to the enhancement of routine monitoring programmes within UK waters.     

Measurement of ocean temperatures using instruments carried by Antarctic fur seals

The study aimed to test the utility of instruments deployed on marine mammals for measuring physical oceanographic variation and, using this method, to examine temperature variation in the coastal waters around South Georgia. There was a significant correlation between temperature measurements made using a towed undulating oceanographic recorder (UOR) and concurrent measurements from time-depth recorders (TDRs) fitted to lactating Antarctic fur seals foraging from the coast of South Georgia. Congruence was found at horizontal spatial scales from 0.01°×0.01° to 0.5°×0.5° (degrees of latitude and longitude), and at a vertical scale of 10 m. However, there was no significant correlation between temperature measured by TDRs in the top 5 m and sea surface temperature (SST) measured by satellite remote sensing. TDR data provided information about temperature variation vertically through the water column, and through time. The UOR data were used to recalibrate the TDR data in order to correct for the slow response time of the TDR thermistor relative to the speed of seal movements through the water column. Seasonal temperature variation was apparent, and temperatures also varied between regions, and with bathymetry. These results were consistent with the current interpretation of the coastal oceanography around South Georgia. In particular, the relationship between on- and off-shelf waters showed larger amounts of warmer surface water in a region in which more run-off was to be expected. The study also showed that Antarctic fur seals concentrate their activity in regions of colder, and presumably oceanic, water. Such instrumented animals could provide near real time data for assimilation into ocean models.     

Applying a Mediated Negotiation Framework to Integrated Coastal Zone Management

Conflict is intrinsic to coastal zone management, yet relatively few peer-reviewed studies have examined how coastal managers might apply conflict resolution processes in the coastal zone management (CZM) context. The authors believe that many of these disputes can be addressed by using a structured mediation model that involves face-to-face negotiation with a broad range of stakeholders to build consensus-based agreements for integrated coastal zone management (ICZM). To explore this further, the article examines four questions. First, it examines how CZM literature characterizes conflict and conflict resolution. Second, it looks at how essential principles from the field of alternative dispute resolution and environmental mediation can be best employed in the ICZM context. In particular, it explores the various elements of a stepwise agreement building model, a mediated negotiation process model the authors use in practice that bases its success on a foundation of four principles: representation, participation, legitimacy, and accountability. Next, it details three essential tools used in this process, stakeholder analysis, joint factfinding, and single-text negotiation, that the authors believe to be promising for developing and adopting stable, well-informed, and implementable agreements for ICZM. Finally, the article examines how these structuring principles and process strategies have been used in two recent case studies regarding the management of the San Francisco estuary and its tributaries.     

Distribution of total dissolved and C18 extractable copper and nickel in relation to dissolved organic matter sources, in the Thermaikos Gulf (eastern Mediterranean)

Organically complexed and total dissolved copper and nickel were measured in the Thermaikos Gulf waters during winter 1998. Total concentrations ranged from 1.13 nmol/L to 7.02 nmol/L for copper and from 3.04 nmol/L to 9.50 nmol/L for nickel. The C18 Sep-Pak solid phase extraction technique was used in order to determine the amount of copper and nickel complexed with the hydrophobic component of the dissolved organic matter (DOM). Up to 32.4% of total copper and 4.57% of total nickel were complexed with the DOM extracted by C18. By applying HPLC analysis it was shown that the majority of the organic compounds retained by C18 had intermediate to low polarity. Using the absorbance ratio a₂₅₄/a₄₃₆ it was possible to unravel that humic substances of both terrestrial and marine origin were present in the Thermaikos Gulf and their distribution followed the dilution of riverine waters. Moreover our results indicated that organic binding of both Cu and Ni was stronger with the hydrophobic compounds of terrestrial origin than with those of marine origin.