Monitoring trace elements (Al, As, Cr, Cu, Fe, Mn, Ni and Zn) in deep and surface waters of the estuary of the Nerbioi-Ibaizabal River (Bay of Biscay, Basque Country)

Deep water samples (in contact with the sediment) were collected at eight different points of the estuary of the Nerbioi-Ibaizabal River (Bay of Biscay, Basque Country), both at low and high tides, during four sampling campaigns (May, September and December 2005 and March 2006). Superficial water was also sampled in March 2006. Temperature, pH, redox potential, dissolved oxygen and electrical conductivity corresponding to each sample were measured in situ at each sampling point using a multiparametric probe. The physico-chemical parameters found are typical of highly stratified estuaries, with an acceptable oxygenation level. After filtering and acidifying the samples, they were analysed by inductively coupled plasma/mass spectrometry (ICP/MS) to simultaneously determine the total concentration of Al, As, Cr, Cu, Fe, Mn, Ni and Zn. Concentrations in the μg kg^− 1 level were found in all cases (c_Cr and c_Ni, 1–10; c_Al, c_As and c_Zn, 10–50; c_Cu and c_Mn, 10–100 and c_Fe, 100–400 μg kg^− 1). A probable net input of Al, Cr, Mn and Zn via the main (Nerbioi-Ibaizabal) and some of the tributary rivers (Galindo, Asua and Gobela) was identified. Evidence of a common source of Al and Zn to the estuary was found. Correlation analysis of data revealed connections between variables (concentration of Cu, Fe and As with salinity, as well as c_Al with c_Zn, c_Cu with c_Fe, c_As with c_Fe, and c_As with c_Cu). Principal Component Analysis (PCA) of data allowed the samples to be grouped according to sampling campaign, with two principal components accounting for 62% of the total variance. In addition, plots of element concentration against salinity suggested a conservative behaviour for As, Cu and Fe and a non-conservative one for Cr. Not clear mixing behaviour was observed for the rest of elements.     

轨枕间距对钢轨波磨的影响

主要研究轨枕间距对钢轨波磨发展的影响。研究小半径曲线内轨的小矢跨比波磨。这些出现问题的曲线段属于西班牙毕尔巴鄂区域的地铁轨道,铺设着混凝土道床和两层STEDEF型支承垫层。当初始轨枕间距为1000mm时,仅有92万组轮对通过后所测得的波磨深度峰-峰值已经达到0.42mm。随后更换产生波磨的钢轨,比较列车通过时轨枕上方和轨间中部的内轨垂向、横向加速度。当轨枕间距为1000mm时,轨间中部出现频率为204和244Hz的强烈响应,在轨枕上方却未出现。在相邻轨枕中间铺设一个轨枕,使轨枕间距变为500mm,钢轨波磨停止发展。该结论是根据2年的观测结果得到的。