排序方式: 共有14条查询结果,搜索用时 15 毫秒
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针对掺混甲烷的乙烯层流火焰中的炭烟颗粒从形貌角度进行了研究,构建了具有相同当量比(2.07)、火焰温度、气体流速的层流预混乙烯火焰和掺混甲烷的乙烯火焰,并各自选取了3个高度进行热泳探针取样,采用TEM和AFM方法对各个工况的炭烟颗粒粒径分布、平均粒径、平均体积当量球径进行了对比。发现少量的甲烷掺混会令乙烯火焰中炭烟颗粒的尺寸变大,而当甲烷掺混量变多时该现象消失。而通过对颗粒的圆度、球度和分形维数计算和分析,发现即使是很小的颗粒也具有相似的不规则形状,这一现象广泛存在于各种火焰和各种大小的颗粒中,不受掺混比的影响,并且越大的颗粒结构越松散。 相似文献
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A series of Pd/Co3O4 catalysts were prepared by Self-Propagating High-Temperature Synthesis (SHS) method in this study, and electric field was applied for catalytic combustion of lean methane over Pd/Co3O4 catalysts at low temperature. When electric field was applied, the catalytic combustion performance of Pd/Co3O4 catalysts was greatly improved, and the application of electric field could reduce the load of active element Pd to some extent while maintaining the same efficiency. Based on experimental tests and the analysis results of X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), H2-temperature-programmed reduction (H2-TPR) and in-situ diffuse reflectance infrared Fourier transform spectroscopy (in-situ DRIFTS), the mechanism of catalytic oxidation of CH4 over Pd/Co3O4 catalysts in electric field was proposed. The catalytic combustion of CH4 occurs only when the temperature is higher than 250 °C normally, but when electric field was applied, the whole process of CH4 oxidation was promoted significantly and the reaction temperature was reduced. Electric field could promote the reduction of the support Co3O4 to release the lattice oxygen, resulting in the increase of PdOx and the surface chemisorbed oxygen, which could provide more active sites for the low-temperature oxidation of CH4. Furthermore, electric field could accelerate the dehydroxylation of CoOOH to further enhance the activity of the catalysts. 相似文献
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当前低浓度甲烷催化氧化存在起燃温度高、贵金属用量大等问题,为探索低成本、清洁高效的甲烷去除技术,基于臭氧的强氧化性和Fe/SSZ-13分子筛优异的吸附性,探究了在臭氧(O3)气氛下Fe负载量、n(CH4)∶n(O3)以及空速对甲烷催化氧化性能的影响。研究结果表明,在Fe负载量为1%,n(CH4)∶n(O3)为1∶6,温度为200℃的条件下,甲烷的转化率可达80.8%。通过BET,XRD,NH3-TPD,H2-TPR,UV-Vis以及XPS表征手段,证明了适量的Fe负载可以提高催化剂比表面积,促进更多酸性位点的形成,调节催化剂表面铁元素的价态分布和种类,从而促进甲烷催化臭氧化反应。基于原位红外试验发现O3可以活化活性位点,进而促进甲烷吸附和催化氧化反应。 相似文献
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CuCeZrOx and KCuCeZrOx catalysts were synthesized and coated on the blank diesel particulate filter (DPF) substrate and a particulate matter (PM) loading apparatus was used for soot loading. The catalytic performances of soot oxidation were evaluated by temperature programmed combustion (TPC) test and characterization tests were conducted to investigate the physicochemical properties of the catalysts. The reaction mechanism in the oxidation process was analyzed with diffuse reflectance infrared Fourier transform spectroscopy. The results demonstrated that CuCeZrOx catalyst exhibited high activities of soot oxidation at low temperature and the best results have been attained with Cu0.9Ce0.05Zr0.05Ox over which the maximum soot oxidation rate decreased to 410 °C. Characterization tests have shown that catalysts containing 90% Cu have uniformly distributed grains and small particle sizes, which provide excellent oxidation activity by providing more active sites and forming a good bond between the catalyst and the soot. The low-temperature oxidation activity of soot could be further optimized due to the excellent elevated NO’s conversion rate by partially substituting Cu with K. The maximum particle oxidation rate can be easily realized at such a low temperature as 347°C. 相似文献
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为了拓宽选择性催化还原NO_x钒基催化剂的活性温度窗口,采用溶液燃烧合成法制备了TiV_(0.1)O_x催化剂,依次加入Mn元素与Er元素形成新的催化剂,分别对它们进行了SCR活性及选择性测试,发现负载Mn元素可以提高钒基催化剂的低温活性,同时也会降低钒基催化剂的高温活性,负载适量的Er元素可以提高钒基催化剂的高温活性和N_2选择性。利用N2吸附脱附法进行BET比表面积和孔容孔径分析,发现负载Er元素增大了比表面积,进而提升了催化剂活性。利用X射线衍射(XRD)图谱进行晶体结构分析,所有催化剂样品均没有发现VO_x,MnO_x或ErO_x的衍射峰,说明溶液燃烧法制备的催化剂活性组分在TiO2颗粒上呈无定型态分布,分散度高。最终优选出最佳Mn和Er比例的TiV_(0.1)Mn_(0.1)Er_(0.01)O_x催化剂,在160~470℃之间保持80%以上的NO_x去除率。 相似文献
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选择性催化还原过滤器(Selective Catalytic Reduction Filter, SCRF)是具有很大发展潜力的发动机污染物处理手段,作为兼具SCR和DPF两部分功能的后处理装置,能够帮助减小后处理装置体积和费用,或者在不缩减体积的情况下获得更好的污染物处理效果。但SCRF内部多种组分构成的复杂的反应体系和较宽的工作温度窗口导致对系统污染物处理效果的预测难度提高很多。全面梳理了近年来SCRF在以下两个方面的研究成果:一是影响DeNOx效率和被动再生效率的表观因素,一是SCRF微观化学反应与传质机制,有利于研究者开展微观机理和SCRF配套优化研究。 相似文献
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